Process for producing acetic acid

Patent metadata

Field	Value
Publication number	US-9776941-B2
Application number	US-201314440545-A
Country	US
Kind code	B2
Filing date	Dec 2, 2013
Priority date	Dec 21, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A process for removing acetaldehyde efficiently and producing high-purity acetic acid stably is provided. Methanol is allowed to continuously react with carbon monoxide in a carbonylation reactor 1 in the presence of a catalyst system; the reaction mixture is continuously fed to a flasher 2 to form a volatile phase ( 2 A) containing acetic acid and methyl iodide; the volatile phase ( 2 A) is continuously fed to a splitter column 3 to form an overhead ( 3 A) containing methyl iodide and acetaldehyde and a stream ( 3 B) containing acetic acid; the volatile phase ( 2 A) and/or the overhead ( 3 A) is cooled by a first condenser C 1 , C 3 at a predetermined cooling temperature; and the noncondensed gaseous component is further cooled by a second condenser C 2 , C 4 to form a concentrate having a lower temperature and a higher acetaldehyde concentration. Acetaldehyde is efficiently removed by distilling the concentrate having a high acetaldehyde concentration.

First claim

The invention claimed is:

1. A process for producing acetic acid comprising:
a reaction step for allowing methanol to continuously react with carbon monoxide in the presence of a catalyst system containing a metal catalyst, a metal halide, and methyl iodide in a carbonylation reactor,
a flash evaporation step for separatin a reaction mixture into a volatile phase ( 2 A) containing produced acetic acid and methyl iodide and a less-volatile phase ( 2 B) containing the metal catalyst and the metal halide,
a distillation step for separating the volatile phase ( 2 A) into an overhead ( 3 A) containing methyl iodide and by-product acetaldehyde, and a stream ( 3 B) containing acetic acid, and
a condensing step for condensing a gaseous phase, containing at least acetaldehyde, resulting from at least one step selected from the group consisting of the reaction step, the flash evaporation step and the distillation step,
wherein the gaseous phase is condensed, in the condensing step, by a plurality of condensers to form a plurality of condensates sequentially lower in temperature, and acetaldehyde is separated from at least one of the condensates, enriched in acetaldehyde.

2. A process according to claim 1 , wherein the gaseous phase, containing at least methyl iodide and acetaldehyde, resulting from at least one step of the flash evaporation step and the distillation step is condensed by the plurality of condensers.

3. A process according to claim 1 , wherein at least one gaseous phase selected from the group consisting of the overhead ( 3 A) and the volatile phase ( 2 A) is subjected to the plurality of condensers and cooled to form condensates and noncondensed gaseous components, wherein the condensates have a lower temperature and a higher acetaldehyde concentration sequentially in the downstream direction, and acetaldehyde is separated from a condensate or condensates highly enriched in acetaldehyde.

4. A process according to claim 1 , wherein the gaseous phase is condensed by the plurality of condensers, and a condensate enriched in acetaldehyde from at least one of a second and subsequent condensers are stored in a hold tank, and acetaldehyde is separated from the stored condensate.

5. A process according to claim 1 , wherein the gaseous phase is condensed by the plurality of condensers, a condensate from at least a first condenser is stored in a decanter, a condensate enriched in acetaldehyde from at least one of a second and subsequent condensers is stored in a hold tank, the condensate in the decanter and the condensate in the hold tank are combined and distilled for separating an overhead containing acetaldehyde.

6. A process according to claim 1 , wherein the volatile phase ( 2 A) is distilled by a first distillation column to form a first overhead, the overhead as the gaseous phase is condensed by the plurality of condensers, and
(i) a condensate enriched in acetaldehyde from at least one of a second and subsequent condensers is distilled by a second distillation column,
(ii) a condensate from at least one of a second and subsequent condensers is stored in a hold tank, and the stored condensate is distilled by a second distillation column, or
(iii) a condensate from at least a first condenser is stored in a decanter, a condensate from at least one of a second and subsequent condensers is stored in a hold tank, the condensate in the decanter and the condensate in the hold tank are combined and distilled by a second distillation column,
for separating a second overhead enriched in acetaldehyde.

7. A process according to claim 5 , wherein the condensate in the decanter and the condensate in the hold tank are combined in a weight ratio of 0/100 to 95/5 as the former/the latter and distilled by a second distillation column.

8. A process according to claim 6 , wherein the second overhead is subjected to extraction with water to form an aqueous phase containing acetaldehyde and an organic phase containing methyl iodide, and the organic phase is recycled to the reactor.

9. A process according to claim 1 , wherein the volatile phase ( 2 A) as the gaseous phase is condensed by the plurality of condensers, a condensate from at least one of a second and subsequent condensers is distilled by a first distillation column and/or a second distillation column to form a first overhead and/or a second overhead.

10. A process according to claim 1 , wherein the gaseous phase is condensed by 2 to 5 condensers arranged in series.

11. A process according to claim 1 , wherein a condensate from at least one of a second and subsequent condensers among the plurality of condensers is distilled for separating an overhead containing acetaldehyde.

12. A process according to claim 1 , wherein the gaseous phase is cooled by a first condenser to form a first condensate and a first noncondensed gaseous component, the first noncondensed gaseous component is cooled by a second condenser of which a cooling temperature is lower than that of the first condenser to form a second condensate having a temperature lower than that of the first condensate and a second noncondensed gaseous component, and acetaldehyde is separated from at least the second condensate.

13. A process according to claim 1 , wherein, further, an offgas ( 5 A), containing at least methyl iodide and acetaldehyde, resulting from at least one step selected from the group consisting of the reaction step; the flash evaporation step; a storage step; and at least one distillation step, is allowed to contact with an absorption solvent, the resulting solvent is stripped to form a gaseous phase containing at least methyl iodide and acetaldehyde, and acetaldehyde is separated from the gaseous phase.

14. A process according to claim 1 , wherein a condensate in a first condenser has a temperature of not higher than 110° C., and a condensate in at least one of a second and subsequent condensers has a temperature of not higher than 45° C.

15. A method for separating or removing acetaldehyde, comprising:
distilling a mixture containing acetic acid, methyl acetate, methyl iodide, methanol, water and acetaldehyde to form a gaseous phase containing at least methyl iodide and acetaldehyde and a liquid phase containing at least water and methanol, and
condensing the gaseous phase to separate acetaldehyde from the gaseous phase,
wherein the gaseous phase is condensed, in the condensing step, by a plurality of condensers to form a plurality of condensates sequentially lower in temperature, and acetaldehyde is separated from at least one of the condensates, enriched in acetaldehyde.

16. A method according to claim 15 , wherein a condensate in a first condenser has a temperature of 20 to 110° C., and a condensate in at least one of a second and subsequent condensers has a temperature of −5° C. to 30° C.

17. A method according to claim 15 , wherein a condensate from at least one of a second and subsequent condensers is distilled to form an overhead containing acetaldehyde, and the overhead is subjected to extraction with water to form an aqueous phase containing acetaldehyde and an organic phase.

Assignees

• Daicel Corp

Inventors

• Shimizu Masahiko
• Saito Ryuji
• Miura Hiroyuki

Classifications

• B01J2231/321

  Hydroformylation, metalformylation, carbonylation or hydroaminomethylation · CPC title

• B01J2531/822

  Rhodium · CPC title

• B01J31/20

  Carbonyls · CPC title

• C07C51/44

  by distillation · CPC title

• B01J31/26

  containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 · CPC title