Plant for producing 2,3,3,3-tetrafluoropropene

Patent metadata

Field	Value
Publication number	US-9776938-B2
Application number	US-201615139662-A
Country	US
Kind code	B2
Filing date	Apr 27, 2016
Priority date	Feb 3, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

The invention concerns a method for producing 2,3,3,3-tetrafluoropropene comprising: a fluoridation reaction of a halopropane and/or halopropene into 2,3,3,3-tetrafluoropropene by means of hydrogen fluoride; the recovery of a gas stream resulting from the reaction; the cooling and partial condensation of the gas stream resulting from the reaction into a partially condensed stream; the separation of the partially condensed stream into a gas fraction and a liquid fraction; the compression of the gas fraction into a compressed gas fraction; the compression of the liquid fraction into a compressed liquid fraction; the distillation of the compressed gas fraction and compressed liquid fraction in order to provide a stream of 2,3,3,3-tetrafluoropropene, a stream of hydrochloric acid, and a stream of unreacted hydrogen fluoride. The invention also concerns an installation suitable for implementing said method.

First claim

The invention claimed is:

1. A plant for producing 2,3,3,3-tetrafluoropropene, comprising:
at least one fluorination reactor having an outlet, the reactor being supplied with halopropane and/or halopropene and hydrogen fluoride;
a first line for reaction gases, which is connected at the outlet of the fluorination reactor;
at least one cooling and partial condensation vessel having an outlet, the at least one cooling and partial condensation vessel being supplied by the first line for reaction gases;
a second line for transporting a partially condensed stream, which is connected at the outlet of the cooling and partial condensation vessel;
a separating flask having an outlet, the separating flask being supplied by the second line for transporting the partially condensed stream;
a third line for withdrawing a gaseous fraction and a fourth line for withdrawing a liquid fraction, which lines are connected at the outlet of the separating flask;
a compressor having an outlet, the compressor being supplied by the third line for withdrawing the gaseous fraction;
a fifth line for supplying a compressed gaseous fraction, which is connected at the outlet of the compressor;
a pump having an outlet, the pump being supplied by the fourth line for the withdrawn liquid fraction;
a sixth line for supplying a compressed liquid fraction, which is connected at the outlet of the pump;
at least one distillation vessel having an outlet, the distillation vessel being supplied by the fifth line for supplying the compressed gaseous fraction and by the sixth line for supplying the compressed liquid fraction; and
a seventh line for withdrawing 2,3,3,3-tetrafluoropropene, an eighth line for withdrawing hydrochloric acid, and a ninth line for withdrawing unreacted hydrogen fluoride, wherein said lines are connected at the outlet of the at least one distillation vessel.

2. The plant as claimed in claim 1 , wherein the ninth line for withdrawing unreacted hydrogen fluoride supplies the fluorination reactor.

3. The plant as claimed in claim 1 , further comprising a heating device on the third line for withdrawing gaseous fraction.

4. The plant as claimed in claim 1 , wherein the at least one distillation vessel comprise a first distillation column and a second distillation column, the fifth line for supplying the compressed gaseous fraction and the sixth line for supplying the compressed liquid fraction supplying the first distillation column.

5. The plant as claimed in claim 4 , wherein:
the ninth line for withdrawing unreacted hydrogen fluoride is connected at the bottom of the first distillation column;
a tenth line for withdrawing an intermediate stream is connected at the top of the first distillation column, the tenth line supplying the second distillation column;
the eighth line for withdrawing hydrochloric acid is connected at the top of the second distillation column; and
the seventh line for withdrawing 2,3,3,3-tetrafluoropropene is connected at the bottom of the second distillation column.

6. The plant as claimed in claim 4 , wherein:
the eighth line for withdrawing hydrochloric acid is connected at the top of the first distillation column;
a tenth line for withdrawing an intermediate stream is connected at the bottom of the first distillation column, the tenth line supplying the second distillation column;
the seventh line for withdrawing 2,3,3,3-tetrafluoropropene is connected at the top of the second distillation column; and
the ninth line for withdrawing unreacted hydrogen fluoride is connected at the bottom of the second distillation column.

7. The plant as claimed in claim 4 , wherein the fifth line for supplying the compressed gaseous fraction and the sixth line for supplying the compressed liquid fraction supplies the first distillation column at different stages of said column.

8. The plant as claimed in claim 1 , wherein the seventh line for withdrawing 2,3,3,3-tetrafluoropropene supplies further purification vessels.

Assignees

• Arkema France

Inventors

• Deur-Bert Dominique
• Collier Bertrand
• Wendlinger Laurent

Classifications

• C07C17/25

  by splitting-off hydrogen halides from halogenated hydrocarbons · CPC title

• C07C17/206 Primary

  the other compound being HX · CPC title

• F25J1/0022

  Hydrocarbons, e.g. natural gas · CPC title

• C07C17/20 Primary

  of halogen atoms by other halogen atoms · CPC title

• F25J3/04412

  in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title