Process for treating water with a counter-current ion exchange unit including silica and boron concentatration monitoring and regeneration thereof

Patent metadata

Field	Value
Publication number	US-9776892-B2
Application number	US-201314083945-A
Country	US
Kind code	B2
Filing date	Nov 19, 2013
Priority date	Nov 21, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A process is described for treating water, in particular for obtaining ultrapure water, in which a decationized water stream is passed at least through a first strong base anion exchange bed and a second strong base anion exchange bed, which is arranged downstream, in particular directly downstream, of the first strong base anion exchange bed. Furthermore, a water treatment system and a counter-current ion exchange unit for carrying out such a process are described.

First claim

The invention claimed is:

1. A process for treating water comprising the steps of:
passing a decationized water stream through a counter-current ion exchange unit comprising:
a single column having
a separate first strong base anion exchange chamber, and
a separate second strong base anion exchange chamber,
the counter-current ion exchange unit further including:

a first strong base anion exchange bed in the first strong base anion exchange chamber, with a top liquid permeable base, and
a second strong base anion exchange bed in the second strong base anion exchange chamber, with another top liquid permeable base, the second strong base anion exchange bed being arranged downstream of the first strong base anion exchange bed, so that the decationized water stream passes through the first strong base anion exchange bed and then through the second strong base anion exchange bed,
monitoring silica concentration of the water stream at a location upstream of the second strong base anion exchange bed,
monitoring boron concentration of the water stream at a location downstream of the second strong base anion exchange bed, and

regenerating the counter-current ion exchange unit by passing a regeneration solution through the single column through the second strong base anion exchange bed and then through the first strong base anion exchange bed when one of the silica concentration and the boron concentration exceeds a defined threshold value.

2. The process according to claim 1 , wherein a sample of the water stream is passed through a strong acid cation exchange bed downstream of the second strong base anion exchange bed, with the strong acid cation exchange bed being arranged between the second strong base anion exchange bed and a boron analyzer.

3. The process according to claim 1 , wherein the anion exchange beds are regenerated when the silica concentration exceeds a defined threshold value of 20 ppb.

4. The process according to claim 1 , wherein the anion exchange beds are regenerated, when the boron concentration exceeds a defined threshold value of 100 ppt.

5. The process according to claim 1 , wherein there is an inert resin layer between the first strong base anion exchange bed and the top liquid permeable base, and wherein there is another inert resin layer between the second strong base anion exchange bed and the another top liquid permeable base.

6. The process according to claim 1 , wherein the regeneration solution is a sodium hydroxide solution.

7. A process for treating water comprising the steps of:
passing a decationized water stream through a counter-current ion exchange unit comprising:
a single column having
a weak base anion exchange bed chamber,
a separate first strong base anion exchange chamber, and
a separate second strong base anion exchange chamber,
the counter-current ion exchange unit further including:
a weak base anion exchange bed in the weak base anion exchange bed chamber, with a top liquid permeable base,
a first strong base anion exchange bed in the first strong base anion exchange chamber, with another top liquid permeable base, the first strong base anion exchange bed being arranged downstream of the weak base anion exchange bed, and
a second strong base anion exchange bed in the second strong base anion exchange chamber, with still another top liquid permeable base, the second strong base anion exchange bed being arranged downstream of the first strong base anion exchange bed so that the decationized water stream passes through the weak base anion exchange bed, then the first strong base anion exchange bed and then through the second strong base anion exchange bed,
monitoring silica concentration of the water stream at a location upstream of the second strong base anion exchange bed,
monitoring boron concentration of the water stream at a location downstream of the second strong base anion exchange bed, and
regenerating the counter-current ion exchange unit by passing a regeneration solution through the single column through the second strong base anion exchange bed, then through the first strong base anion exchange bed, and then through the weak base anion exchange bed when one of the silica concentration and the boron concentration exceeds a defined threshold value.

8. The process according to claim 7 , wherein there is an inert resin layer between the weak base anion exchange bed and the top liquid permeable base, and wherein there is another inert resin layer between the first strong base anion exchange bed and the another top liquid permeable base, and wherein there is still another inert resin layer between the second strong base anion exchange bed and the still another top liquid permeable base.

9. The process according to claim 7 , wherein the regeneration solution is a sodium hydroxide solution.

Assignees

• Ovivo Luxembourg S Å R L
• Ovivo Inc

Inventors

• Gensbittel Dominique

Classifications

• C02F2101/10

  Inorganic compounds · CPC title

• C02F2101/108

  Boron compounds · CPC title

• C02F2301/08

  Multistage treatments, e.g. repetition of the same process step under different conditions · CPC title

• B01D15/363

  Anion-exchange · CPC title

• C02F2001/422

  using anionic exchangers · CPC title