Method for producing hematite for ironmaking

Patent metadata

Field	Value
Publication number	US-9776885-B2
Application number	US-201314386445-A
Country	US
Kind code	B2
Filing date	Feb 13, 2013
Priority date	Mar 21, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

Provided is a production method for refining iron oxide (hematite), which has such a low sulfur content as to be used as an iron-making raw material, from a leach residue containing iron oxide produced by a high pressure acid leach (HPAL) process. In the method for refining iron oxide for ironmaking by a process of adding sulfuric acid to nickel oxide ore and then leaching nickel from the nickel oxide ore using a pressure vessel, an amount of the sulfuric acid added is 150 kg or more and 220 kg or less per ton of nickel oxide ore.

First claim

The invention claimed is:

1. A method of refining iron oxide for ironmaking from a leach residue, the method comprising:
adding sulfuric acid to nickel oxide ore that includes iron;
leaching nickel from the nickel oxide ore using a pressure vessel and forming a leach slurry, and then
solid-liquid separating the leach slurry to provide the leach residue that includes hematite and a nickel containing leachate,
wherein an amount of the sulfuric acid added is 150 kg to 205 kg per ton of the nickel oxide ore wherein the addition provides 96 kg to 131.2 kg H 2 SO 4 per ton of the nickel oxide ore, and
wherein a sulfur grade of the leach residue is 1 wt.% or less.

2. The method of claim 1 further comprising:
adding a chloride to the nickel oxide ore along with the sulfuric acid.

3. The method of claim 2 , further comprising washing the leach residue with an alkali solution having a concentration of 20% by weight or more.

4. The method of claim 1 , further comprising washing the leach residue with an alkali solution having a concentration of 20% by weight or more.

5. The method of claim 2 , wherein the chloride is selected from calcium chloride, sodium chloride, potassium chloride, and magnesium chloride.

6. The method of claim 5 , wherein the chloride is magnesium chloride.

7. The method of claim 2 , wherein the chloride is added in an amount corresponding to a molar ratio of about 4 times the sulfur contained in the leach residue.

8. A method of refining iron oxide for ironmaking from a leach residue, the method comprising:
adding sulfuric acid to nickel oxide ore which includes iron;
leaching nickel from the nickel oxide ore using a pressure vessel and forming a leach slurry, and then
solid-liquid separating the leach slurry to provide the leach residue which includes hematite and a nickel containing leachate,
wherein an amount of the sulfuric acid added is 150 kg to 205 kg per ton of the nickel oxide ore wherein the addition provides 979 to 1338 moles H 2 SO 4 per ton of the nickel oxide ore, and
wherein a sulfur grade of the leach residue is 1 wt.% or less.

9. A method of refining iron oxide for ironmaking from a leach residue, the method comprising:
adding 64% sulfuric acid to nickel oxide ore which includes iron;
leaching nickel from the nickel oxide ore using a pressure vessel and forming a leach slurry, and then
solid-liquid separating the leach slurry to provide the leach residue which includes hematite and a nickel containing leachate,
wherein an amount of the sulfuric acid added is 150 kg to 205 kg per ton of the nickel oxide ore, and wherein a sulfur grade of the leach residue is 1 wt.% or less.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ozaki Yoshitomo
• Enomoto Manabu
• Shouji Hirofumi
• Higaki Tatsuya

Classifications

• B09B3/70

  Chemical treatment, e.g. pH adjustment or oxidation (involving an extraction step B09B3/80) · CPC title

• C22B23/0415 Primary

  with acids or salt solutions except ammonium salts solutions · CPC title

• Y02P10/20

  Recycling · CPC title

• B09B3/00

  Destroying solid waste or transforming solid waste into something useful or harmless · CPC title

• B09B3/0083

  Operations & Transport · mapped topic