Front face side substrate for thermal transfer image-receiving sheet, and thermal transfer sheet

Patent metadata

Field	Value
Publication number	US-9776446-B2
Application number	US-201415105672-A
Country	US
Kind code	B2
Filing date	Dec 9, 2014
Priority date	Dec 18, 2013
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A front face side substrate provided between a supporting member and a receiving layer of a thermal transfer image-receiving sheet. The front face side substrate includes a front face side layer provided on one surface of a substrate layer and a rear face side layer provided on another surface of the substrate layer. The substrate layer includes (A) a propylene-based polymer, (B) calcium carbonate, and (C) titanium oxide, and the weight of (A) is 70% by weight to 94.5% by weight, the weight of (B) is 5% by weight to 28% by weight, and the weight of (C) is 0.5% by weight to 3% by weight, based on the assumption that the total weight of (A), (B) and (C) is 100% by weight. The front face side layer includes a modified propylene-based polymer, and the rear face side layer includes a propylene-based polymer.

First claim

The invention claimed is:

1. A front face side substrate for a thermal transfer image-receiving sheet,
comprising a layered structure of a front face side layer, a substrate layer and a rear face side layer in this order;
the substrate layer comprising (A) a propylene-based polymer, (B) calcium carbonate, and (C) titanium oxide, and the weight of (A) being in the range of from not less than 70% by weight to not more than 94.5% by weight, the weight of (B) being in the range of from not less than 5% by weight to not more than 28% by weight, and the weight of (C) being in the range of from not less than 0.5% by weight to not more than 3% by weight, based on the assumption that the total weight of (A), (B) and (C) is 100% by weight;
the front face side layer comprising a modified propylene-based polymer; and
the rear face side layer comprising a propylene-based polymer.

2. The front face side substrate for a thermal transfer image-receiving sheet according to claim 1 ,
wherein the front face side layer comprises (D) a propylene homopolymer,
as the modified propylene-based polymer; or
wherein the front face side layer comprises (D) a propylene homopolymer and (E) a propylene-α-olefin random copolymer, the weight of (E) is not more than 50% by weight, based on the assumption that the total weight of (D) and (E) is 100% by weight; and either or both of (D) and (E) is the modified propylene-based polymer.

3. The front face side substrate for a thermal transfer image-receiving sheet according to claim 2 ,
wherein the rear face side layer contains (F) a propylene homopolymer, and (G) a propylene-α-olefin random copolymer, and the weight of (F) is in the range of from not less than 40% by weight to not more than 90% by weight, based on the assumption that the total weight of (F) and (G) is 100% by weight.

4. The front face side substrate for a thermal transfer image-receiving sheet according to claim 3 , wherein an adhesive layer is further provided on the front face side layer.

5. The front face side substrate for a thermal transfer image-receiving sheet according to claim 2 , wherein the thickness of the front face side layer is in the range of from not less than 0.5 μm to not more than 10 μm.

6. The front face side substrate for a thermal transfer image-receiving sheet according to claim 5 , wherein an adhesive layer is further provided on the front face side layer.

7. The front face side substrate for a thermal transfer image-receiving sheet according to claim 2 , wherein an adhesive layer is further provided on the front face side layer.

8. The front face side substrate for a thermal transfer image-receiving sheet according to claim 1 ,
wherein the rear face side layer contains (F) a propylene homopolymer, and (G) a propylene-α-olefin random copolymer, and the weight of (F) is in the range of from not less than 40% by weight to not more than 90% by weight, based on the assumption that the total weight of (F) and (G) is 100% by weight.

9. The front face side substrate for a thermal transfer image-receiving sheet according to claim 8 , wherein the thickness of the front face side layer is in the range of from not less than 0.5 μm to not more than 10 μm.

10. The front face side substrate for a thermal transfer image-receiving sheet according to claim 9 , wherein an adhesive layer is further provided on the front face side layer.

11. The front face side substrate for a thermal transfer image-receiving sheet according to claim 8 , wherein an adhesive layer is further provided on the front face side layer.

12. The front face side substrate for a thermal transfer image-receiving sheet according to claim 1 , wherein the modified propylene-based polymer is a propylene-based polymer graft-modified with an unsaturated carboxylic acid or a derivative thereof.

13. The front face side substrate for a thermal transfer image-receiving sheet according to claim 12 , wherein the thickness of the front face side layer is in the range of from not less than 0.5 μm to not more than 10 μm.

14. The front face side substrate for a thermal transfer image-receiving sheet according to claim 13 , wherein an adhesive layer is further provided on the front face side layer.

15. The front face side substrate for a thermal transfer image-receiving sheet according to claim 12 , wherein an adhesive layer is further provided on the front face side layer.

16. The front face side substrate for a thermal transfer image-receiving sheet according to claim 1 , wherein the thickness of the front face side layer is in the range of from not less than 0.5 μM to not more than 10 μm.

17. The front face side substrate for a thermal transfer image-receiving sheet according to claim 16 , wherein an adhesive layer is further provided on the front face side layer.

18. The front face side substrate for a thermal transfer image-receiving sheet according to claim 1 , wherein an adhesive layer is further provided on the front face side layer.

19. A thermal transfer image-receiving sheet, comprising:
a supporting member
a receiving layer provided on one surface of the supporting member; and
a front face side substrate provided between the supporting member and the receiving member;
the front face side substrate comprising a layered structure of a rear face side layer, a substrate layer and a front face side layer, and being arranged in this order from the supporting member;
the substrate layer comprising (A) a propylene-based polymer, (B) calcium carbonate, and (C) titanium oxide, and the weight of (A) being in the range of from not less than 70% by weight to not more than 94.5% by weight, the weight of (B) being in the range of from not less than 5% by weight to not more than 28% by weight, and the weight of (C) being in the range of from not less than 0.5% by weight to not more than 3% by weight, based on the assumption that the total weight of (A), (B) and (C) is 100% by weight;
the front face side layer comprising a modified propylene-based polymer; and
the rear face side layer comprising a propylene-based polymer.

20. A thermal transfer image-receiving sheet according to claim 19 , wherein the thickness of the supporting member is in the range of from not less than 150 μm to not more than 300 μm.

Assignees

• Dainippon Printing Co Ltd
• Mitsui Chemicals Tohcello Inc

Inventors

• Takahashi Hirokazu
• OOMURA Junpei
• Matsuura Hiroshi
• Honda Hiroshi

Classifications

• B32B2250/24

  All layers being polymeric · CPC title

• B41M5/42

  Intermediate, {backcoat}, or covering layers {(B41M5/405 takes precedence; multilayer thermal transfer systems in general B41M5/38214)} · CPC title

• B32B2264/104

  Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles · CPC title

• B32B2264/102

  Oxide or hydroxide · CPC title

• B32B2250/242

  All polymers belonging to those covered by group B32B27/32 · CPC title