Bimetal catalysts

Patent metadata

Field	Value
Publication number	US-9776177-B2
Application number	US-201314388709-A
Country	US
Kind code	B2
Filing date	Mar 28, 2013
Priority date	Mar 29, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A catalyst comprises a carbide or nitride of a metal and a promoter element. The metal is selected from the group consisting of Mo, W, Co, Fe, Rh or Mn, and the promoter element is selected from the group consisting of Ni, Co, Al, Si, S or P, provided that the metal and the promoter element are different. The catalyst also comprises a mesoporous support having a surface area of at least about 170 m 2 g −1 , wherein the carbide or nitride of the metal and the promoter element is supported by the mesoporous support, and is in a non-sulfided form and in an amorphous form.

First claim

The invention claimed is:

1. A catalyst, comprising:
a carbide or nitride of a metal and a promoter element, the metal selected from the group consisting of Mo, W, Co, Fe, Rh or Mn, and the promoter element selected from the group consisting of Ni, Co, Al, Si, S or P, provided that the metal and the promoter element are different, and
a mesoporous support having a surface area of at least about 170 m 2 g −1 , wherein the carbide or nitride of the metal and the promoter element is supported by the mesoporous support, and is in a non-sulfided form and in an amorphous form.

2. The catalyst of claim 1 , wherein the support in the presence of the carbide or nitride has a surface area of at least about 450 m 2 g −1 .

3. The catalyst of claim 1 , wherein the support in the presence of the carbide or nitride has a surface area of at least about 700 m 2 g −1 .

4. The catalyst of claim 1 , wherein the support in the presence of the carbide or nitride has a pore volume of at least about 0.1 cm 3 g −1 .

5. The catalyst of claim 1 , wherein the support in the presence of the carbide or nitride has a pore volume of at least about 0.2 cm 3 g −1 .

6. The catalyst of claim 1 , wherein the support in the presence of the carbide or nitride has a pore volume of at least about 0.7 cm 3 g −1 .

7. The catalyst of claim 1 , wherein the metal is Mo.

8. The catalyst of claim 1 , wherein the metal is W.

9. The catalyst of claim 1 , wherein the promoter element is Ni.

10. The catalyst of claim 1 , wherein the promoter element is Co.

11. The catalyst of claim 1 , wherein the support is selected from the group consisting of Al 2 O 3 , SiO 2 , a zeolite, ZrO 2 , CeO 2 , a clay, and combinations thereof.

12. The catalyst of claims 11 , wherein the support is selected from the group consisting of ZSM-5, zeolite β, USY, γ-Al 2 O 3 , Al-SBA-15, MCM-14, diatomite and combinations thereof.

13. The catalyst of claims 11 , wherein the support is Al-SBA-15.

14. The catalyst of claims 1 , which is NiMoC supported on Al-SBA-15.

15. The catalyst of claims 1 , which is NiMoN supported on Al-SBA-15.

16. The catalyst of claims 1 , which is NiWC supported on Al-SBA-15.

17. The catalyst of claims 1 , which is NiWN supported on Al-SBA-15.

18. A process, comprising:
contacting the catalyst of claim 1 with a reaction, the catalyst catalyzing the reaction.

19. The process of claim 18 , wherein the reaction is a hydrodeoxygenation reaction.

20. The process of claim 18 , wherein the reaction is a hydrocracking reaction.

21. The process of claim 18 , wherein the reaction comprises both a hydrodeoxygenation reaction and a hydrocracking reaction, and the catalyst catalyzes both the hydrodeoxygenation reaction and the hydrocracking reaction.

22. A process, the process comprising:
contacting a material that comprises a glyceride with hydrogen in the presence of the catalyst of claim 1 such that at least some of the glyceride is converted into one or more gasoline to diesel range hydrocarbons, wherein the catalyst catalyzes the hydrocarbon formation.

23. The process of claim 22 , wherein the material further comprises a free fatty acid, and wherein at least some of the free fatty acid is converted into one or more gasoline to diesel range hydrocarbons in the presence of the catalyst, wherein the catalyst catalyzes the formation of hydrocarbon.

24. The process of claim 22 , wherein the glyceride comprises a triglyceride.

25. The process of claim 22 , wherein the glyceride comprises a diglyceride.

26. The process of claim 22 , wherein the material is a non-refined oil.

27. The process of claim 22 , wherein the material further comprises water, and wherein the water content in the material is more than about 5 weight %.

28. The process of claim 22 , wherein the material further comprises one or more free fatty acids, and wherein the free fatty acid content in the material is more than about 10 weight %.

29. A process, the process comprising:
contacting a material that comprises a free fatty acid with hydrogen in the presence of the catalyst of claim 1 such that at least some of the free fatty acid is converted into one or more gasoline to diesel range hydrocarbons, wherein the catalyst catalyzes the formation of hydrocarbon.

Assignees

• Univ Wayne State

Inventors

• Ng K Y Simon
• Salley Steve O
• Wang Huali

Classifications

• C10G3/49

  containing crystalline aluminosilicates, e.g. molecular sieves · CPC title

• B01J29/166

  Y-type faujasite · CPC title

• B01J27/24

  Nitrogen compounds · CPC title

• B01J29/0308

  Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 · CPC title

• B01J21/12

  Silica and alumina · CPC title