Method of preparing polycrystalline diamond from derivatized nanodiamond

Patent metadata

Field	Value
Publication number	US-9776151-B2
Application number	US-201113077426-A
Country	US
Kind code	B2
Filing date	Mar 31, 2011
Priority date	Apr 14, 2010
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A method of forming a polycrystalline diamond comprises derivatizing a nanodiamond to form functional groups, and combining the derivatized nanodiamond with a microdiamond having an average particle size greater than that of the derivatized nanodiamond, and a metal solvent-catalyst. A polycrystalline diamond compact is prepared by adhering the polycrystalline diamond to a support, and an article such as a cutting tool may be prepared from the polycrystalline diamond compact.

First claim

The invention claimed is:

1. A method of forming a polycrystalline diamond, comprising:
disposing a first functional group on a plurality of nanodiamonds by a chemical reaction to form derivatized nanodiamonds that contain functional groups comprising alkyl, alkenyl, alkynyl, amido, epoxy, keto, alkoxy, ether, ester, or lactones, metallic groups, organometallic groups, or a combination comprising at least one of the foregoing, the derivatized nanodiamonds derivatized without direct halogenation;
combining the derivatized nanodiamonds with a plurality of microdiamonds having an average particle size greater than that of the derivatized nanodiamonds, and a metal solvent-catalyst; and
forming a polycrystalline diamond from the derivatized nanodiamonds, the microdiamonds and the metal solvent catalyst.

2. The method of claim 1 wherein the derivatized nanodiamonds include a first functional group comprising alkyl, alkenyl, alkynyl, carboxyl, hydroxyl, amino, amido, epoxy, keto, alkoxy, ether, ester, lactones, metallic groups, organometallic groups, polymeric groups, ionic groups, or a combination comprising at least one of the foregoing.

3. The method of claim 1 wherein the nanodiamonds have an average particle size of 1 nm to less than 1 μm.

4. The method of claim 1 , wherein the microdiamonds have an average particle size of greater than or equal to 1 μm.

5. The method of claim 1 , wherein the average particle size of the microdiamonds is at least about 10 times greater than the average particle size of the derivatized nanodiamonds.

6. The method of claim 1 , wherein the polycrystalline diamond comprises 0.001 to 90 wt% of derivatized nanodiamonds based on the total weight of the derivatized nanodiamonds, microdiamonds, and metal solvent-catalyst.

7. The method of claim 1 , wherein the microdiamonds are derivatized to include a second functional group comprising alkyl, alkenyl, alkynyl, carboxyl, hydroxyl, amino, amido, epoxy, keto, alkoxy, ether, ester, lactones, metallic groups, organometallic groups, polymeric groups, ionic groups, or a combination comprising at least one of the foregoing.

8. The method of claim 1 , further comprising a plurality of nanoparticles not identical to the derivatized nanodiamonds, a plurality of microparticles not identical to the microdiamonds, or a combination comprising at least one of the foregoing.

9. The method of claim 8 , wherein the nanoparticles comprise fullerene, nanographite, nanographene, graphene oxide, nanotube, adamantane, diamondoid, nanodiamond, polysilsesquioxane, nanoclay, or inorganic nanoparticles, or combinations comprising at least one of the foregoing.

10. The method of claim 9 , wherein the nanoparticles comprise single-wall carbon nanotube, multi-walled carbon nanotube, metal, metal or metalloid carbide, metal or metalloid nitride, metal carbonate, or metal bicarbonate nanoparticles, or a combination comprising at least one of the foregoing.

11. The method of claim 8 wherein the nanoparticles are derivatized nanoparticles not identical to the derivatized nanodiamonds.

12. The method of claim 8 , wherein the microparticles comprise micrographite, carbon fiber, boron nitride, microdiamond, silicon carbide, or tungsten carbide microparticles, or a combination comprising at least one of the foregoing.

13. The method of claim 12 , wherein the microparticles are derivatized microparticle.

14. The method of claim 1 , wherein combining comprises:
mixing the derivatized nanodiamonds, microdiamonds, and metal solvent-catalyst in a solvent to form a suspended mixture,
forming a polycrystalline diamond precursor by removing the solvent, and
forming the polycrystalline diamond from the polycrystalline diamond precursor by processing the polycrystalline diamond precursor under conditions of heating and pressure.

15. The method of claim 14 , where combining further comprises mixing nanoparticles not identical to the derivatized nanodiamonds, microparticles not identical to the microdiamonds, or a combination comprising at least one of the foregoing.

16. The method of claim 14 , wherein the suspension has a homogeneity greater than a suspension in which a non-derivatized nanodiamond is included in place of the derivatized nanodiamond.

17. The method of claim 16 , where mixing further comprises slurrying a nanoparticle not identical to the derivatized nanodiamond, a microparticle not identical to the microdiamond, or a combination comprising at least one of the foregoing.

18. The method of claim 14 , wherein heating is at a temperature of greater than or equal to about 1,000° C., the pressure is greater than or equal to about 5 gigapascals (GPa), and processing is carried out for 1 second to 1 hour.

19. The method of claim 1 , where in the metal solvent-catalyst comprises a metal comprising Ni, Fe, Co, Cr, Ru, Os, Mn, V, alloys thereof, or a combination comprising at least one of the foregoing; magnesium carbonate, calcium carbonate, strontium carbonate, barium carbonate, or a combination comprising at least one of the foregoing; or a combination comprising at least one of the foregoing metals and carbonates.

20. The method of claim 1 , wherein the polycrystalline diamond comprises a superabrasive.

21. The method of claim 1 , wherein the polycrystalline diamond comprises an article.

22. The method of claim 21 , wherein the article is a cutting tool.

23. The method of claim 1 wherein the derivatized nanodiamonds include a first functional group comprising an alkyl group.

24. A method of making an article, comprising
forming a superabrasive polycrystalline diamond compact by combining:
a plurality of nanodiamonds derivatized by disposing a first functional group on the plurality of nanodiamonds by a chemical reaction to form derivatized nanodiamonds comprising functional groups containing alkyl, alkenyl, alkynyl, amido, epoxy, keto, alkoxy, ether, ester, or lactones, metallic groups, organometallic groups, or a combination comprising at least one of the foregoing, the derivatized nanodiamonds derivatized without direct halogenation,
a plurality of microdiamonds having an average particle size greater than that of the derivatized nanodiamonds, and
a metal solvent-catalyst;

combining the polycrystalline diamond with a substrate comprising a ceramic; and
removing a portion of the metal solvent-catalyst from the polycrystalline diamond compact by leaching.

25. The method of claim 24 , where leaching comprises immersing the polycrystalline diamond compact in hydrochloric acid, hydrofluoric acid, nitric acid, or a combination comprising at least one of the foregoing, at a temperature of greater than 100° C.

26. The method of claim 25 , wherein the article is a cutting tool.

27. A method of forming a polycrystalline diamond comprising:
processing a suspension under heat and pressure, the suspension comprising as components:
a plurality of nanodiamonds having an average particle size of 1 to 500 nm and derivatized by a chemical reaction to include functional organic groups comprising alkyl, alkenyl, alkynyl, amido, epoxy, keto, alkoxy, ether, ester, or lactones, metallic groups, organometallic groups, or a combination comprising at least one of the foregoing, wherein the nanodiamonds are derivatized without direct halogenation,
a plurality of microdiamond having an average particle size greater than that of the derivatized nanodiamond,

Assignees

• Chakraborty Soma
• Agrawal Gaurav
• Richard Bennett
• Digiovanni Anthony A
• Baker Hughes Inc

Inventors

• Chakraborty Soma
• Agrawal Gaurav
• Richard Bennett
• Digiovanni Anthony A

Classifications

• C04B2235/422

  Carbon · CPC title

• C04B2237/401

  Cermets · CPC title

• B01J2203/0655

  Diamond · CPC title

• C04B2235/5288

  Carbon nanotubes · CPC title

• C04B2235/427

  Diamond · CPC title