Components with environmental barrier coatings having improved surface roughness

Patent metadata

Field	Value
Publication number	US-9771826-B2
Application number	US-201414159759-A
Country	US
Kind code	B2
Filing date	Jan 21, 2014
Priority date	Jul 31, 2009
Publication date	Sep 26, 2017
Grant date	Sep 26, 2017

Abstract

Components having an environmental barrier coating and a sintered layer overlying the environmental barrier coating, the sintered layer defining an outer surface having a lower surface roughness than the environmental barrier coating. The sintered layer is formed from a slurry applied to and then sintered on the environmental barrier coating. The sintered layer comprises a primary material, at least one sintering aid dissolved in the primary material, and optionally a secondary material. The sintering aid contains at least one doping composition. The primary material is a rare earth disilicate or a rare earth monosilicate and is doped with the doping composition so as to be either a doped rare earth disilicate or a doped rare earth monosilicate. The optional secondary material is a reaction product of the primary material and any of the sintering aid not dissolved in the primary material.

First claim

What is claimed is:

1. A component comprising:
a plasma sprayed environmental barrier coating having a surface characterized by a surface roughness; and
a sintered layer is a transition layer on the plasma sprayed environmental barrier coating and defining an outer surface having a lower surface roughness than the surface of the environmental barrier coating, the sintered layer being formed from a slurry applied to and then sintered on the plasma sprayed environmental barrier coating, the sintered layer comprising a primary material, at least one sintering aid dissolved in the primary material, and optionally a secondary material, wherein:
the at least one sintering aid contains at least one doping composition chosen from the group consisting of iron, aluminum, titanium, gallium, nickel, boron, alkali metals, alkaline-earth metals, and Lnb rare earth metals, and the at least one sintering aid is selected from the group consisting of iron oxide, gallium oxide, aluminum oxide, nickel oxide, titanium oxide, boron oxide, alkaline earth oxides, carbonyl iron, iron metal, aluminum metal, boron, nickel metal, iron hydroxide, gallium hydroxide, aluminum hydroxide, nickel hydroxide, titanium hydroxide, alkaline earth hydroxides, iron carbonate, gallium carbonate, aluminum carbonate, nickel carbonate, boron carbonate, alkaline earth carbonates, iron oxalate, gallium oxalate, aluminum oxalate, nickel oxalate, titanium oxalate, water soluble iron salts, water soluble gallium salts, water soluble aluminum salts, water soluble nickel salts, water titanium salts, water soluble boron salts, water soluble alkaline earth salts, and combinations thereof;
the primary material is a rare earth disilicate and is doped with the at least one doping composition of the at least one sintering aid so as to be a doped rare earth disilicate containing the at least one doping composition; and
the secondary material optionally in the sintered layer is a reaction product of the primary material and any of the at least one sintering aid not dissolved in the primary material and
further comprising a second sintered layer on the plasma sprayed environmental barrier coating, the second sintered layer being an outer layer overlying the transition layer and defining an outermost surface of the component, the outer layer containing a rare earth monosilicate, the at least one sintering aid dissolved in the rare earth monosilicate, and optionally the secondary material, the rare earth monosilicate being doped with the at least one doping composition of the at least one sintering aid so as to be a doped rare earth monosilicate containing the at least one doping composition.

2. The component of claim 1 , wherein the at least one sintering aid consists of one or more of the iron oxide, gallium oxide, aluminum oxide, nickel oxide, titanium oxide, boron oxide, alkaline earth oxides, carbonyl iron, iron metal, aluminum metal, boron, nickel metal, iron hydroxide, gallium hydroxide, aluminum hydroxide, nickel hydroxide, titanium hydroxide, alkaline earth hydroxides, iron carbonate, gallium carbonate, aluminum carbonate, nickel carbonate, boron carbonate, alkaline earth carbonates, iron oxalate, gallium oxalate, aluminum oxalate, nickel oxalate, titanium oxalate, water soluble iron salts, water soluble gallium salts, water soluble aluminum salts, water soluble nickel salts, water titanium salts, water soluble boron salts, and water soluble alkaline earth salts.

3. The component of claim 1 , wherein the outer layer contains the secondary material, and the secondary material is at least one selected from the group consisting of Fe 2 O 3 , iron silicates, rare earth iron oxides, Al 2 O 3 , mullite, rare earth aluminates, rare earth aluminosilicates, TiO 2 , rare earth titanates, Ga 2 O 3 , rare earth gallates, NiO, nickel silicates, rare earth nickel oxides, Lnb metals, Lnb 2 O 3 , Lnb 2 Si 2 O 7 , Lnb 2 SiO 5 , borosilicate glass, alkaline earth silicates, alkaline earth rare earth oxides, alkaline earth rare earth silicates, and mixtures thereof.

4. The component of claim 1 , wherein the outer layer consists of about 85% to about 100% by volume of the rare earth monosilicate doped with the at least one doping composition and in which the at least one sintering aid is dissolved, and any balance is the secondary material.

5. The component of claim 1 , wherein the outer layer has a porosity of about 0% to about 30% by volume.

6. The component of claim 1 , wherein the transition layer contains the secondary material, and the secondary material is at least one selected from the group consisting of Fe 2 O 3 , iron silicates, rare earth iron oxides, Al 2 O 3 , mullite, rare earth aluminates, rare earth aluminosilicates, TiO 2 , rare earth titanates, Ga 2 O 3 , rare earth gallates, NiO, nickel silicates, rare earth nickel oxides, Lnb metals, Lnb 2 O 3 , Lnb 2 Si 2 O 7 , Lnb 2 SiO 5 , borosilicate glass, alkaline earth silicates, alkaline earth rare earth oxides, alkaline earth rare earth silicates, and mixtures thereof.

7. The component of claim 1 , wherein the transition layer consists of about 85% to about 100% by volume of the rare earth disilicate doped with the at least one doping composition and in which the at least one sintering aid is dissolved, and any balance is the secondary material.

8. The component of claim 1 , wherein the transition layer has a porosity of from 0% to about 15% by volume.

9. The component of claim 1 , further comprising a third sintered layer on the plasma sprayed environmental barrier coating, the third sintered layer being a compliant layer between the transition layer and the outer layer, the compliant layer containing BSAS, the at least one sintering aid dissolved in the BSAS, and optionally a secondary compliant material selected from the group consisting of Ln 2 O 3 , Ln 2 Si 2 O 7 , Ln 2 SiO 5 , Ln 3 Al 5 O 12 , Al 2 O 3 , mullite, and combinations thereof, the BSAS being doped with the at least one doping composition of the at least one sintering aid so as to be a doped BSAS containing the at least one doping composition.

10. The component of claim 9 , wherein the compliant layer contains the secondary compliant material.

11. The component of claim 9 , wherein the compliant layer consists of about 85% to about 99% by volume of the BSAS doped with the at least one doping composition and in which the at least one sintering aid is dissolved, and the balance is about 1% to about 15% by volume of the secondary compliant material.

12. The component of claim 9 , wherein the compliant layer has a porosity of about 0% to about 30% by volume.

13. The component of claim 1 , wherein the surface roughness of the environmental barrier coating is greater than 5 micrometers Ra and the lower surface roughness of the outer surface of the sintered layer is 1 to 5 micrometers Ra.

14. The component of claim 1 , wherein the component is a ceramic matrix composite or a monolithic ceramic turbine engine component selected from the group consisting of combustor components, turbine blades, shrouds, nozzles, heat shields, and vanes.

Assignees

• Gen Electric

Inventors

• Kirby Glen Harold
• Boutwell Brett Allen
• Subit Jessica Licardi

Classifications

• C04B41/89

  for obtaining at least two superposed coatings having different compositions · CPC title

• C04B2235/3225

  Yttrium oxide or oxide-forming salts thereof · CPC title

• F05D2300/516

  Surface roughness · CPC title

• C04B2235/3463

  Alumino-silicates other than clay, e.g. mullite · CPC title

• C04B2235/3232

  Titanium oxides or titanates, e.g. rutile or anatase · CPC title