Method to provide pipeline quality natural gas

Patent metadata

Field	Value
Publication number	US-9771522-B2
Application number	US-201415107636-A
Country	US
Kind code	B2
Filing date	Aug 5, 2014
Priority date	Jan 23, 2014
Publication date	Sep 26, 2017
Grant date	Sep 26, 2017

Abstract

The present invention relates to a method of separating and recovering NGLs from a natural gas feedstream. Specifically, the present method allows for the separation of ethane and heavier hydrocarbons and/or propane and heavier hydrocarbons from a raw natural gas feedstream to provide pipeline quality natural gas. One embodiment of this method provides for the use of a regenerable adsorbent media which is regenerated by a microwave heating system. Said regeneration step may be operated as a batch process, a semi-continuous process, or a continuous process.

First claim

What is claimed is:

1. A method to remove and recover some or all of the natural gas liquids (NGLs): ethane, propane, butane, pentane, or heavier hydrocarbons, from a natural gas feedstream to provide a methane-rich natural gas supply wherein the NGLs are separated from the natural gas feedstream by means of a NGLs separation unit comprising:
(i) an adsorption unit comprising an adsorption bed comprising an adsorbent media which adsorbs NGLs to form a loaded adsorbent media and
(ii) a regeneration unit comprising a means to regenerate loaded adsorbent media by causing the release of adsorbed NGLs from the loaded adsorbing media and forming regenerated adsorbent media
wherein the method comprises the steps of:
(a) passing the natural gas feedstream through the adsorption unit generating the adsorbent loaded with NGLs and a methane-rich natural gas supply,
(b) transporting the adsorbent loaded with NGLs from the adsorption unit to the regeneration unit,
(c) regenerating the adsorbent loaded with NGLs by releasing the adsorbed NGLs from the loaded adsorbing media and forming regenerated adsorbent media
(d) transporting the regenerated adsorbent media back to the adsorption unit for reuse,
(e) recovering the released NGLs,
and
(f) providing the methane-rich natural gas supply to a natural gas pipeline for transportation and/or for use as fuel for a combustion process,

wherein the adsorption media is a porous cross-linked polymeric adsorbent, a partially pyrolized macroporous polymer, or mixtures thereof.

2. The method of claim 1 wherein the source of the natural gas feedstream is from an oil well, a gas well, a condensate well, or a pipeline natural gas containing NGLs.

3. The method of claim 1 wherein the methane-rich natural gas supply has a BTU value equal to or less than 1073.

4. The method of claim 1 wherein the loaded adsorption media is regenerated by means of reduced pressure over the media, heating the media, or a combination of reduced pressure and heating.

5. The method of claim 1 wherein the loaded adsorption media is regenerated by a microwave heating system.

6. The method of claim 1 wherein the regeneration step is operated as a batch process, a semi-continuous process, or as a continuous process.

7. The method of claim 1 further comprising the step
(g) transporting the recovered NGLs by pipeline, truck, rail, or ship to a chemical processing facility where one or more of the NGLs is used as a chemical feedstock in the chemical processing facility.

Assignees

• Dow Global Technologies Llc

Inventors

• Matteucci Scott T
• Badhwar Ajay N
• Shurgott Nicholas J
• Goltz H Robert

Classifications

• C10G5/02 Primary

  with solid adsorbents · CPC title

• B01J20/28066

  being more than 1000 m2/g · CPC title

• B01J20/3441

  Regeneration or reactivation by electric current, ultrasound or irradiation, e.g. electromagnetic radiation such as X-rays, UV, light, microwaves · CPC title

• B01D2253/102

  Carbon · CPC title

• B01D2253/306

  Surface area, e.g. BET-specific surface · CPC title