Liquid crystal polyester composition, method for producing liquid crystal polyester composition, and molded article

Patent metadata

Field	Value
Publication number	US-9771475-B2
Application number	US-201314386570-A
Country	US
Kind code	B2
Filing date	Mar 18, 2013
Priority date	Mar 21, 2012
Publication date	Sep 26, 2017
Grant date	Sep 26, 2017

Abstract

A liquid crystal polyester composition contains: a liquid crystal polyester in an amount of 100 parts by mass as well as a fibrous filler and a plate-like filler in an amount of not less than 65 parts by mass and not more than 100 parts by mass in total. The fibrous filler in the composition has a number average fiber diameter of not less than 5 μm and not more than 15 μm and a number average fiber length of more than 200 μm and less than 400 μm. The mass ratio of the fibrous filler to the plate-like filler in the composition is not less than 3 and not more than 15. The flow starting temperature of the composition is not lower than 250° C. and lower than 314° C.

First claim

The invention claimed is:

1. A liquid crystal polyester composition comprising: a liquid crystal polyester in an amount of 100 parts by mass as well as a fibrous filler and a plate filler in a total filler amount of not less than 65 parts by mass and not more than 100 parts by mass,
said fibrous filler having a number average fiber diameter of not less than 5 μm and not more than 15 μm, and a number average fiber length of more than 200 μm and less than 400 μm,
the mass ratio of the fibrous filler to the plate filler being not less than 3 and not more than 15, and
wherein the composition has a flow starting temperature of not lower than 250° C. and lower than 314° C.

2. The liquid crystal polyester composition according to claim 1 wherein the liquid crystal polyester has a repeating unit represented by the following formula (1), a repeating unit represented by the following formula (2) and a repeating unit represented by the following formula (3):
—O—Ar 1 —CO—  (1)

—CO—Ar 2 —CO—  (2)

—X—Ar 3 —Y—  (3)

where Ar 1 represents a phenylene group, a naphthylene group or a biphenylene group, Ar 2 and Ar 3 each independently represent a phenylene group, a naphthylene group, a biphenylene group or a group represented by the following formula (4), X and Y each independently represent an oxygen atom or an imino group, the hydrogen atoms present in the group represented by Ar 1 , Ar 2 or Ar 3 may each independently be replaced by a halogen atom, an alkyl group or an aryl group;
—Ar 4 —Z—Ar 5 —  (4)

where Ar 4 and Ar 5 each independently a phenylene group or a naphthylene group, and
Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group or an alkylidene group.

3. The liquid crystal polyester composition according to claim 2 wherein
the liquid crystal polyester is a mixture of
a liquid crystal polyester (A) comprising the repeating unit represented by the formula (1), the repeating unit represented by the formula (2) and the repeating unit represented by the formula (3), where Ar 1 is a p-phenylene group, and
a liquid crystal polyester (B) including the repeating unit represented by the formula (1), the repeating unit represented by the formula (2) and the repeating unit represented by the formula (3), wherein Ar 1 is a 2,6-naphthylene group.

4. The liquid crystal polyester composition according to claim 3 which comprises the liquid crystal polyester (A) in an amount of 20 parts by mass or more based on 100 parts by mass of the liquid crystal polyester.

5. The liquid crystal polyester composition according to claim 1
wherein the fibrous filler is at least one selected from the group consisting of a glass fiber, a wollastonite whisker, an aluminum borate whisker and a potassium titanate whisker.

6. The liquid crystal polyester composition according to claim 1
wherein the plate filler is one or both of mica and talc.

7. The liquid crystal polyester composition according to claim 1
wherein the plate filler has a volume average particle size of not less than 10 μm and not more than 30 μm.

8. A method for producing a liquid crystal polyester composition, including
a step of melting and kneading a liquid crystal polyester in an amount of 100 parts by mass as well as a mixture which contains a fibrous filler raw material and a plate filler in an amount of not less than 65 parts by mass and not more than 100 parts by mass in total,
wherein the fibrous filler raw material has a number average fiber diameter of not less than 5 μm and not more than 15 μm and a number average aspect ratio of 100 or more,
an extruder used in the melting and kneading step has a cylinder and a screw installed in the cylinder,
the cylinder has a first supply port, and a second supply port set on the downstream side in the extrusion direction with respect to the first supply port,
the screw has a ratio (L/D) of not less than 15 and not more than 65 where L is an effective length of the screw and D is a diameter of the screw, and
for melting and kneading, the liquid crystal polyester in an amount of 50% by mass or more based on the total supply amount and the filler raw material in an amount of 50% by mass or less based on the total supply amount are supplied from the first supply port, and the residual amount of the liquid crystal polyester, the residual amount of the filler raw material and the total amount of the plate filler are supplied from the second supply port.

9. A molded article comprising the liquid crystal polyester composition according to claim 1 .

10. The molded article according to claim 9 which is a connector.

11. The molded article according to claim 10 wherein the connector is a CPU socket.

Assignees

• Sumitomo Chemical Co

Inventors

• Komatsu Shintaro
• Harada Hiroshi

Classifications

• C08K2201/016

  Additives defined by their aspect ratio · CPC title

• B29C48/54

  with additional forward-feeding elements · CPC title

• B29B7/726

  Measuring properties of mixture, e.g. temperature or density (B29B7/724 takes precedence) · CPC title

• C08K7/14 Primary

  Glass · CPC title

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title