Fuel cell device having a liquid soak up region

Patent metadata

Field	Value
Publication number	US-9768455-B2
Application number	US-200813003775-A
Country	US
Kind code	B2
Filing date	Sep 12, 2008
Priority date	Sep 12, 2008
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

The fuel cell device includes an electrode assembly. A gas diffusion layer is on each side of the electrode assembly. A solid, non-porous plate is adjacent each of the gas diffusion layers. A hydrophilic soak up region is near an inlet portion of at least one of the gas diffusion layers. The hydrophilic soak up region is configured to absorb liquid water from the electrode assembly when the fuel cell device is shutdown.

First claim

We claim:

1. A fuel cell device, comprising:
an electrode assembly;
a first gas diffusion layer on a first side of the electrode assembly;
a second gas diffusion layer on a second side of the electrode assembly;
a first solid, non-porous plate adjacent the first gas diffusion layer;
a second solid, non-porous plate adjacent the second gas diffusion layer; and
a hydrophilic soak up region located within the first gas diffusion layer and within the first solid, non-porous plate, the hydrophilic soak up region near an inlet portion of the first gas diffusion layer, the hydrophilic soak up region contacting the electrode assembly and configured to absorb liquid water directly from the electrode assembly when the fuel cell device is shut down.

2. The fuel cell device of claim 1 , wherein the hydrophilic soak up region is on an anode side of the electrode assembly.

3. The fuel cell device of claim 2 , including the hydrophilic soak up region near an inlet portion of the first solid, non-porous plate on the anode side of the electrode assembly.

4. The fuel cell device of claim 1 , wherein the hydrophilic soak up region is at least partially within an electrochemically inactive area of the first gas diffusion layer.

5. The fuel cell device of claim 1 , wherein the hydrophilic soak up region has pores of a first size and the electrode assembly includes a catalyst layer immediately adjacent the first gas diffusion layer, the catalyst layer is porous having pores of a second size that is at least as large as the first size.

6. The fuel cell device of claim 5 , wherein the second size is larger than the first size.

7. The fuel cell device of claim 1 , wherein the hydrophilic soak up region comprises a hydrophilic material associated with the first gas diffusion layer, the hydrophilic material comprising at least one of carbon or a wettable polymer, wherein the first gas diffusion layer is porous and the hydrophilic material at least partially fills at least some pores of the inlet portion of the first gas diffusion layer.

8. The fuel cell device of claim 7 , wherein the hydrophilic material is applied to at least some of the inlet portion of the first gas diffusion layer.

9. The fuel cell device of claim 1 , wherein the hydrophilic soak up region remains essentially dry during operation of the fuel cell device.

10. The fuel cell device of claim 1 , wherein the hydrophilic soak up region has pores of a first size, and regions of the gas diffusion layer outside the hydrophilic soak up region have pores of a second size that is at least as large as the first size.

11. The fuel cell device of claim 1 wherein the hydrophilic soak up region extends through an entire thickness of the solid, non-porous plate.

12. A method of managing fluid in a fuel cell including a solid, non-porous plate and a gas diffusion layer associated with an electrode assembly, the method comprising:
providing a hydrophilic soak up region within the gas diffusion layer, within the solid, non-porous plate, and near an inlet portion of the gas diffusion layer;
contacting the electrode assembly with the hydrophilic soak up region; and
absorbing water directly from the electrode assembly into the hydrophilic soak up region when the fuel cell is shut down.

13. The method of claim 12 , wherein the hydrophilic soak up region remains essentially dry during operation of the fuel cell.

14. The method of claim 12 , wherein liquid water in the electrode assembly moves into the hydrophilic soak up region when the fuel cell is shut down.

15. The method of claim 12 , comprising introducing dry air into at least flow field channels of the non-porous plates when the fuel cell is shut down.

16. The method of claim 12 , comprising providing the hydrophilic soak up region on an anode side of the electrode assembly.

17. The method of claim 16 , comprising providing the hydrophilic soak up region near an inlet portion of the solid, non-porous plate on the anode side of the electrode assembly.

18. The method of claim 12 , comprising providing the hydrophilic soak up region at least partially within an electrochemically inactive area of the gas diffusion layer.

19. The method of claim 12 , comprising providing pores in the hydrophilic soak up region having a first size and providing pores on a catalyst layer of the electrode assembly having a second size that is at least as large as the first size.

20. The method of claim 19 , wherein the second size is larger than the first size.

21. The method of claim 12 , wherein the providing comprises at least one of:
treating a material of the gas diffusion layer with a hydrophilic material comprising at least one of carbon or a wettable polymer; or
at least partially filling pores of the gas diffusion layer with a hydrophilic material comprising at least one of carbon or a wettable polymer.

22. The method of claim 12 wherein providing the hydrophilic soak up region comprises providing the hydrophilic soak up region through an entire thickness of the solid, non-porous plate.

Assignees

• Badrinarayanan Paravastu
• Patterson Timothy W
• Audi Ag

Inventors

• Badrinarayanan Paravastu
• Patterson Timothy W

Classifications

• H01M8/04223 Primary

  during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells · CPC title

• H01M8/04179

  by purging or increasing flow or pressure of reactants · CPC title

• H01M8/0241 Primary

  Composites · CPC title

• H01M8/04171

  using adsorbents, wicks or hydrophilic material · CPC title

• H01M8/0239

  Organic resins; Organic polymers · CPC title