Organic electroluminescent element and organic electroluminescent display panel

Patent metadata

Field	Value
Publication number	US-9768403-B2
Application number	US-201415026663-A
Country	US
Kind code	B2
Filing date	Oct 22, 2014
Priority date	Oct 30, 2013
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

The organic electroluminescent element of the present invention includes, in the given order: an anode; a light-emitting layer; and a cathode, the light-emitting layer including a luminescent dopant layer and a luminescent host layer, the luminescent dopant layer containing a luminescent dopant material and substantially no luminescent host material, the luminescent host layer containing a luminescent host material and substantially no luminescent dopant material.

First claim

The invention claimed is:

1. An organic electroluminescent display panel comprising:
a substrate; and
an organic electroluminescent element disposed on the substrate; wherein
the organic electroluminescent element includes, in the following order:
an anode;
a light-emitting layer; and
a cathode,

the light-emitting layer includes a luminescent dopant layer and a luminescent host layer,
the luminescent dopant layer contains a luminescent dopant material and 3 wt % or lower of a luminescent host material,
the luminescent host layer contains a luminescent host material and 20 wt % or lower of a luminescent dopant material,
the organic electroluminescent display panel is a top side emission organic electroluminescent display panel which emits light from the cathode side,
the organic electroluminescent element includes the anode, a hole transport layer, the luminescent dopant layer, the luminescent host layer, a doped electron transport layer, and the cathode in this order from the substrate side,
the doped electron transport layer is made of a material obtained by doping a substance having electron transport ability with a dopant, and
the lowest triplet state energy level of a material constituting the hole transport layer is higher than the lowest triplet state energy level of the luminescent dopant material.

2. The organic electroluminescent display panel according to claim 1 ,
wherein the luminescent host material has bipolarity, and
the hole mobility of the luminescent host material is lower than the electron mobility thereof.

3. The organic electroluminescent display panel according to claim 1 ,
wherein the luminescent dopant layer has a thickness of 5 nm or smaller.

4. The organic electroluminescent display panel according to claim 1 ,
wherein the luminescent dopant layer has a concentration of the luminescent dopant material of 90 wt % or higher.

5. The organic electroluminescent display panel according to claim 1 ,
wherein the dopant is an n-type impurity.

6. The organic electroluminescent display panel according to claim 1 ,
wherein the luminescent dopant material is a blue fluorescent material exhibiting delayed fluorescence.

7. An organic electroluminescent display panel comprising:
a substrate; and
an organic electroluminescent element disposed on the substrate, wherein
the organic electroluminescent element includes, in the following order:
an anode;
a light-emitting layer; and
a cathode,

the light-emitting layer includes a luminescent dopant layer and a luminescent host layer,
the luminescent dopant layer contains a luminescent dopant material and 3 wt % or lower of a luminescent host material,
the luminescent host layer contains at least two luminescent host materials and 20 wt % or lower of a luminescent dopant material,
the organic electroluminescent display panel is a top side emission organic electroluminescent display panel which emits light from the cathode side,
the organic electroluminescent element includes the anode, a hole transport layer, the luminescent dopant layer, the luminescent host layer, a doped electron transport layer, and the cathode in the order from the substrate side,
the doped electron transport layer is made of a material obtained by doping a substance having electron transport ability with a dopant,
the at least two luminescent host materials include a material having electron transport ability and a material having hole transport ability, and
the highest occupied molecular orbital level of the material having hole transport ability is higher than the highest occupied molecular orbital level of the material having electron transport ability.

8. The organic electroluminescent display panel according to claim 7 ,
wherein the at least two luminescent host materials include a material having bipolarity, and
the hole mobility of the material having bipolarity is lower than the electron mobility thereof.

9. The organic electroluminescent display panel according to claim 7 ,
wherein the luminescent dopant layer has a thickness of 5 nm or smaller.

10. The organic electroluminescent display panel according to claim 7 ,
wherein the luminescent dopant layer has a concentration of the luminescent dopant material of 90 wt % or higher.

11. The organic electroluminescent display panel according to claim 7 ,
wherein the dopant is an n-type impurity.

12. The organic electroluminescent display panel according to claim 7 ,
wherein the luminescent dopant material is a blue fluorescent material exhibiting delayed fluorescence.

13. An organic electroluminescent display panel comprising:
a substrate; and
an organic electroluminescent element disposed on the substrate, wherein
the organic electroluminescent element includes, in the following order:
an anode;
a light-emitting layer; and
a cathode,

the light-emitting layer including a luminescent dopant layer and a luminescent host layer,
the luminescent dopant layer containing a luminescent dopant material and 3 wt % or lower of a luminescent host material,
the luminescent host layer containing at least two luminescent host materials and 20 wt % or lower of a luminescent dopant material,
wherein the organic electroluminescent display panel is a top side emission organic electroluminescent display panel which emits light from the cathode side,
the organic electroluminescent element includes the anode, a hole transport layer, the luminescent dopant layer, the luminescent host layer, a doped electron transport layer, and the cathode in the order from the substrate side,
the doped electron transport layer is made of a material obtained by doping a substance having electron transport ability with a dopant,
the at least two luminescent host materials include a material having electron transport ability and a material having hole transport ability, and
the lowest unoccupied molecular orbital level of the material having hole transport ability is higher than the lowest unoccupied molecular orbital level of the material having electron transport ability.

14. The organic electroluminescent display panel according to claim 13 ,
wherein the at least two luminescent host materials include a material having bipolarity, and
the hole mobility of the material having bipolarity is lower than the electron mobility thereof.

15. The organic electroluminescent display panel according to claim 13 ,
wherein the luminescent dopant layer has a thickness of 5 nm or smaller.

16. The organic electroluminescent display panel according to claim 13 ,
wherein the luminescent dopant layer has a concentration of the luminescent dopant material of 90 wt % or higher.

17. The organic electroluminescent display panel according to claim 13 ,
wherein the dopant is an n-type impurity.

18. The organic electroluminescent display panel according to claim 13 ,
wherein the luminescent dopant material is a blue fluorescent material exhibiting delayed fluorescence.

Assignees

• Sharp Kk

Inventors

• Tsukamoto Yuto
• Kikuchi Katsuhiro
• Niboshi Manabu
• Isomura Yoshiyuki
• Uchida Hideki
• Endo Ayataka
• ITO Asae

Classifications

• H01L2251/558

  Electricity · mapped topic

• H01L51/5056

  Electricity · mapped topic

• H01L51/0061

  Electricity · mapped topic

• H01L51/5076

  Electricity · mapped topic

• H01L2251/552

  Electricity · mapped topic