Photoconductor, image forming apparatus, and process cartridge

Patent metadata

Field	Value
Publication number	US-9766562-B2
Application number	US-201615144199-A
Country	US
Kind code	B2
Filing date	May 2, 2016
Priority date	May 13, 2015
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

A photoconductor including: a conductive support; an undercoat layer; and a photoconductive layer, the undercoat layer being disposed over the conductive support, the photoconductive layer being disposed over the undercoat layer, wherein the undercoat layer includes zinc oxide particles, wherein when a film thickness of the undercoat layer is 20 μm, the undercoat layer has transmittance of 50% or more to light having a wavelength in a range of 500 nm or more but 800 nm or less, wherein a lowest transmittance of light is 85% or less in the range, and wherein when an electric field of 5 V/μm is applied to the undercoat layer, volume resistivity of the undercoat layer is 1.0×10 7 Ω·cm or more but 5.0×10 8 Ω·cm or less at an environment of 23° C. and 55% RH.

First claim

What is claimed is:

1. A photoconductor, comprising:
a conductive support;
an undercoat layer, and
a photoconductive layer,
wherein the undercoat layer is disposed over the conductive support and the photoconductive layer is disposed over the undercoat layer,
wherein the undercoat layer comprises zinc oxide particles and a salicylic acid derivative or a thiol compound,
wherein when a film thickness of the undercoat layer is 20 μm, the undercoat layer has transmittance of 50% or more to light having a wavelength in a range of 500 nm or more but 800 nm or less,
wherein a lowest transmittance of light is 50% or more but 85% or less in the range, and
wherein when an electric field of 5 V/μm is applied to the undercoat layer, volume resistivity of the undercoat layer is 1.0×10 7 Ω·cm or more but 5.0×10 8 Ω·cm or less at an environment of 23° C. and 55% RH.

2. The photoconductor according to claim 1 ,
wherein the zinc oxide particles are zinc oxide particles surface-treated with alkylalkoxysilane, and at least one alkyl group bound to Si in the alkylalkoxysilane comprises at least one alkyl group having 4 or less carbon atoms.

3. The photoconductor according to claim 2 ,
wherein an amount of a surface treating agent used for surface-treating the zinc oxide particles is 1.5% by mass or more but 4.0% by mass or less relative to an amount of the zinc oxide particles before surface treatment.

4. The photoconductor according to claim 1 ,
wherein an average film thickness of the undercoat layer is 7 μm or more but 30 μm or less.

5. The photoconductor according to claim 1 ,
wherein the undercoat layer satisfies a relational expression (1) below:
0.2< A/B< 5  (1),

where A is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 10° C. and a relative humidity of 15% RH, and B is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 30° C. and a relative humidity of 90% RH.

6. The photoconductor according to claim 1 ,
wherein a volume rate of the zinc oxide particles occupying the undercoat layer is 45% or more but 53% or less of the undercoat layer.

7. An image forming apparatus, comprising:
a photoconductor;
a charging unit configured to charge a surface of the photoconductor;
an exposing unit configured to expose the surface of the photoconductor charged to light to form an electrostatic latent image;
a developing unit configured to develop the electrostatic latent image with a toner to form a visible image; and
a transfer unit configured to transfer the visible image onto a recording medium,
wherein the photoconductor comprises:
a conductive support;
an undercoat layer; and
a photoconductive layer,

wherein the undercoat layer is disposed over the conductive support and the photoconductive layer is disposed over the undercoat layer,
wherein the undercoat layer contains zinc oxide particles and a salicylic acid derivative or a thiol compound,
wherein when a film thickness of the undercoat layer is 20 μm, the undercoat layer has transmittance of 50% or more to light having a wavelength in a range of 500 nm or more but 800 nm or less,
wherein a lowest transmittance of light is 50% or more but 85% or less in the range, and
wherein when an electric field of 5 V/μm is applied to the undercoat layer, volume resistivity of the undercoat layer is 1.0×10 7 Ω·cm or more but 5.0×10 8 Ω·cm or less at an environment of 23° C. and 55% RH.

8. The image forming apparatus according to claim 7 ,
wherein the zinc oxide particles are zinc oxide particles surface-treated with alkylalkoxysilane, and at least one alkyl group bound to Si in the alkylalkoxysilane comprises at least one alkyl group having 4 or less carbon atoms.

9. The image forming apparatus according to claim 8 ,
wherein an amount of a surface treating agent used for surface-treating the zinc oxide particles is 1.5% by mass or more but 4.0% by mass or less relative to an amount of the zinc oxide particles before surface treatment.

10. The image forming apparatus according to claim 7 ,
wherein an average film thickness of the undercoat layer is 7 μm or more but 30 μm or less.

11. The image forming apparatus according to claim 7 ,
wherein the undercoat layer satisfies a relational expression (1) below:
0.2< A/B< 5  (1),

where A is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 10° C. and a relative humidity of 15% RH, and B is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 30° C. and a relative humidity of 90% RH.

12. A process cartridge, comprising:
a photoconductor; and
at least one unit selected from the group consisting of a charging unit, an exposing unit, a developing unit, and a transfer unit,
wherein the charging unit is configured to charge a surface of the photoconductor, the exposing unit is configured to expose the surface of the photoconductor charged to form an electrostatic latent image, the developing unit is configured to develop the electrostatic latent image with a toner to form a visible image, and the transfer unit is configured to transfer the visible image onto a recording medium,
wherein the photoconductor comprises:
a conductive support;
an undercoat layer; and
a photoconductive layer,

wherein the undercoat layer is disposed over the conductive support and the photoconductive layer is disposed over the undercoat layer,
wherein the undercoat layer comprises zinc oxide particles and a salicylic acid derivative or a thiol compound,
wherein when a film thickness of the undercoat layer is 20 μm, the undercoat layer has transmittance of 50% or more to light having a wavelength in a range of 500 nm or more but 800 nm or less,
wherein a lowest transmittance of light is 50% or more but 85% or less in the range, and
wherein when an electric field of 5 V/μm is applied to the undercoat layer, volume resistivity of the undercoat layer is 1.0×10 7 Ω·cm or more but 5.0×10 8 Ω·cm or less at an environment of 23° C. and 55% RH.

13. The process cartridge according to claim 12 ,
wherein the zinc oxide particles are zinc oxide particles surface-treated with alkylalkoxysilane, and at least one alkyl group bound to Si in the alkylalkoxysilane comprises at least one alkyl group having 4 or less carbon atoms.

14. The process cartridge according to claim 13 ,
wherein an amount of a surface treating agent used for surface-treating the zinc oxide particles is 1.5% by mass or more but 4.0% by mass or less relative to an amount of the zinc oxide particles before surface treatment.

15. The process cartridge according to claim 12 ,
wherein an average film thickness of the undercoat layer is 7 μm or more but 30 μm or less.

16. The process cartridge according to claim 12 ,
wherein the undercoat layer satisfies a relational expression (1) below:
0.2< A/B< 5  (1),

where A is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 10° C. and a relative humidity of 15% RH, and B is volume resistivity of the undercoat layer when an electric field of 5 V/μm is applied to the undercoat layer at a temperature of 30° C. and a relative humidity of 90% RH.

Assignees

• Ishida Toshihiro
• Kurimoto Eiji
• Suzuki Tetsuro
• Asano Tomoharu
• Nii Daisuke
• Ricoh Co Ltd

Inventors

• Ishida Toshihiro
• Kurimoto Eiji
• Suzuki Tetsuro
• Asano Tomoharu
• Nii Daisuke

Classifications

• G03G21/18

  using a processing cartridge {, whereby the process cartridge comprises at least two image processing means in a single unit} · CPC title

• G03G5/1476

  Other polycondensates comprising oxygen atoms in the main chain; Phenol resins · CPC title

• G03G5/14765

  Polyamides; Polyimides · CPC title

• G03G5/144 Primary

  comprising inorganic material · CPC title

• G03G5/142

  Inert intermediate layers · CPC title