Methods and systems for treating a hydrocarbon feed

Patent metadata

Field	Value
Publication number	US-9765267-B2
Application number	US-201514945990-A
Country	US
Kind code	B2
Filing date	Nov 19, 2015
Priority date	Dec 17, 2014
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

The invention relates to methods and systems for treating heavy hydrocarbon by cavitation and hydroprocessing. The invention also relates to systems and methods for such treating, to equipment useful for such treating, and to cavitated, hydroprocessed products.

First claim

What is claimed is:

1. A heavy hydrocarbon treatment method, comprising:
(a) providing a heavy hydrocarbon having a mass density (measured at 15° C.) ≧1.0 g/cm 3 and a kinematic viscosity (measured at 50° C.) KV i ≧30 cSt;
(b) cavitating the heavy hydrocarbon to produce a cavitated heavy hydrocarbon having a kinematic viscosity (measured at 50° C.) of KV c , wherein (i) KV c is =(y*KV i ) and (ii) y is ≦0.95 and wherein cavitation is conducted at a temperature between 50° C. and 200° C.; and
(c) hydroprocessing at least a portion of the cavitated heavy hydrocarbon to produce a treated product.

2. The method of claim 1 , further comprising:
(d) providing a utility fluid which (i) comprises 1-ring and/or 2-ring aromatics in an amount ≧25.0 wt. % and (ii) has a final boiling point ≦430° C.; and
(e) combining the utility fluid with the heavy hydrocarbon and/or cavitated heavy hydrocarbon before the hydroprocessing.

3. The method of claim 1 , further comprising cavitating at least a portion of the hydroprocessed product.

4. The method of claim 1 , wherein the heavy hydrocarbon comprises ≧90.0 wt. % of steam cracker tar, the steam cracker tar having one or more of (i) an I N ≧85, (ii) a mass density (measured at 15° C.) ≧1.07 g/cm 3 , and (iii) a viscosity in the range of from 1000 cSt to 500,000 cSt.

5. The method of claim 1 , wherein y is ≦0.7.

6. The method of claim 1 , wherein y is ≦0.5.

7. The method of claim 1 , wherein the hydroprocessing is catalytic hydroprocessing and the hydroprocessing conditions include a temperature in the range of 300° C. to 500° C., a molecular hydrogen consumption rate ≦267 standard m 3 of molecular hydrogen per m 3 of the heavy hydrocarbon, and a molecular hydrogen partial pressure in the range of from 34 bar (abs) to 48 bar (abs).

8. The method of claim 1 , further comprising: producing a raffinate by separating from the hydroprocessed product one or more of (i) at least a portion of any vapor present in the hydroprocessed product and recycling at least a portion of the separated vapor to the hydroprocessing and (ii) separating from the hydroprocessed product at least a portion of those components having an atmospheric boiling point ≦430° C., wherein the utility fluid comprises at least a portion of the separated components of the hydroprocessed product.

9. The method of claim 8 wherein the raffinate comprises ≧90 wt. % of the hydroprocessed product's molecules having an atmospheric boiling point ≧290° C., and wherein the raffinate has one or more of (i) a kinematic viscosity (measured at 50° C.) <30 cSt, (ii) an I N ≦80, (iii) a sulfur content ≦1.0 wt. %, and (iv) a mass density (measured at 15° C.) ≦1.1 g/cm 3 .

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Evans Christopher M
• Abichandani Jeevan S

Classifications

• C10G9/36

  with heated gases or vapours · CPC title

• C10G2300/302

  Viscosity · CPC title

• C10G69/02 Primary

  plural serial stages only · CPC title

• C10G47/02

  characterised by the catalyst used · CPC title

• C10G2300/4056

  Retrofitting operations · CPC title