Polymeric powder composition and a method of producing same

Patent metadata

Field	Value
Publication number	US-9765211-B2
Application number	US-201414782359-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Apr 23, 2013
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

A polymeric powder composition prepared from an emulsion blend comprising from 95 to less than 100 percent by weight latex based substrate polymer, wherein the latex based substrate polymer comprises units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylates, functionalized alkyl(meth)acrylates styrene, acrylonitrile, butadiene, chloroprene, vinyl chloride, (meth)acrylates, vinyl acetate, and combinations of two or more thereof and wherein the latex based substrate polymer has a Tg equal to or greater than 60° C. and an average particle size between 100 nm and 10 μm; and from greater than 0 to 5 percent by weight binder latex polymer, wherein the binder has a Tg of equal to or less than 10° C. and has units derived from one or more (meth)acrylic monomers, and wherein the binder polymer has an average particle size from 50 to 250 nm is provided.

First claim

We claim:

1. A polymeric powder composition prepared from an emulsion blend comprising:
from 95 to less than 100 percent by weight latex based substrate polymer, wherein the latex based substrate polymer comprises units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylates, functionalized alkyl(meth)acrylates styrene, acrylonitrile, butadiene, chloroprene, vinyl chloride, (meth)acrylates, vinyl acetate, and combinations of two or more thereof and wherein the latex based substrate polymer has a Tg equal to or greater than 60° C. and an average particle size between 100 nm and 10 μm; and
from greater than 0 to 5 percent by weight binder latex polymer, wherein the binder has a Tg of equal to or less than 10° C. and has units derived from one or more (meth)acrylic monomers, and wherein the binder polymer has an average particle size from 50 to 250 nm;
wherein a dry powder prepared from the emulsion blend by spray drying or fluidized spray drying exhibits no more than a 25% decrease in median particle size after attrition testing and no more than a 50% increase in the fraction of particles <45 μm after the attrition testing.

2. The polymeric powder composition according to claim 1 , wherein the latex based substrate polymer has a core/shell structure.

3. The polymeric powder composition according to claim 1 , wherein the binder latex polymer does not have a core/shell structure.

4. The polymeric powder composition according to claim 1 , wherein the binder polymer has an average particle size of less than 150 nm.

5. The polymeric powder composition according to claim 1 , where the binder latex polymer has a Tg of less than −30° C.

6. The polymeric powder composition according to claim 1 , wherein the substrate polymer has a core/shell structure having more than one shell layer and wherein an outermost layer has a Tg of greater than 70° C.

7. The polymeric powder composition according to claim 1 , wherein the binder polymer is present in an amount of from 1 to 5% by weight based on the weight of the dry powder.

8. The polymeric powder composition according to claim 1 , wherein the substrate polymer comprises units derived from one or more monomers selected from the group of styrene, methyl methacrylate, vinyl choride, acrylonitrile, alkyl (meth)acrylates, and methacrylic acid.

9. The polymeric powder composition according to claim 1 , wherein the binder polymer comprises greater than 98% by weight units derived from butyl acrylate, ethyl acrylate, and/or ethylhexyl acrylate, 0.1 to 2% by weight (meth)acrylic acid.

10. A method for making a polymeric powder composition comprising:
preparing by emulsion polymerization a latex based substrate polymer comprising units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylates, functionalized alkyl(meth)acrylates styrene, acrylonitrile, butadiene, chloroprene, vinyl chloride, (meth)acrylates, vinyl acetate, and combinations of two or more thereof and wherein the latex based substrate polymer has a Tg equal to or greater than 60° C. and an average particle size between 100 nm and 10 μm;
preparing by emulsion polymerization a binder polymer comprising units derived from one or more (meth)acrylic monomers, having a Tg of equal to or less than or equal to −10° C. and an average particle size from 50 to 250 nm; and
blending the substrate and binder polymers by spray drying or fluidized spray drying to produce a dry powder exhibiting no more than a 25% decrease in median particle size after attrition testing and no more than a 50% increase in the fraction of particles <45 μm after the attrition testing.

11. The method according to claim 10 , wherein the blending is by batch or in-line continuous blending.

12. The method according to claim 10 , wherein the latex based substrate polymer is prepared by emulsion polymerization such as to impart to the substrate polymer a core/shell structure.

13. The method according to claim 10 , wherein the binder latex polymer is prepared such as to impart a non-core/shell structure to the binder latex polymer.

14. The method according to claim 10 , wherein the binder polymer has an average particle size of less than 150 nm.

15. The method according to claim 10 , where the binder latex polymer has a Tg of less than −30° C.

16. The method according to claim 10 , wherein the substrate polymer has a Tg greater than 70° C.

17. The method according to claim 10 , wherein the substrate polymer has a core/shell structure having more than one shell layer and wherein an outermost layer has a Tg of greater than 70° C.

18. The method according to claim 10 , wherein the binder polymer is present in an amount of from 1 to 5% by weight, based on the weight of the dry powder.

19. The method according to claim 10 , wherein the substrate polymer comprises units derived from one or more monomers selected from the group of styrene, methyl methacrylate, vinyl choride, acrylonitrile, alkyl (meth)acrylates, and methacrylic acid.

20. The method according to claim 10 , wherein the binder polymer comprises from greater than 98% by weight units derived from butyl acrylate, ethyl acrylate, and/or ethylhexyl acrylate, 0.1 to 2% by weight (meth)acrylic acid.

Assignees

• Rohm & Haas

Inventors

• Nelliappan Veera G
• Lundquist Eric G
• Adamo Joseph R

Classifications

• C08L33/14 Primary

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

• C08J2327/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08J2309/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J2331/04

  Homopolymers or copolymers of vinyl acetate · CPC title

• C08J2333/08

  Homopolymers or copolymers of acrylic acid esters · CPC title