Halogen free high temperature polyamide compositions comprising phosphorus containing flame retardants

Patent metadata

Field	Value
Publication number	US-9765204-B2
Application number	US-201514792833-A
Country	US
Kind code	B2
Filing date	Jul 7, 2015
Priority date	Jul 24, 2013
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

Flame retardants produced by heating certain phosphonic acid salts at temperatures over 200° C. are readily compounded into high temperature polyamides that are processed at temperatures above 270° C. to provide flame retardant, high temperature polyamide compositions.

First claim

What is claimed:

1. A flame retardant, thermoplastic polymer composition comprising:
a) a high temperature, thermoplastic polyamide that melts above 270° C., into which high temperature, thermoplastic polyamide has been compounded

at temperatures above 270° C.
b) from 1% to 24%, by weight based on the total weight of the flame retardant polymer composition, of a flame retardant material obtained by transforming one or more than one compound of formula (I) into a different material via a process comprising heating in the absence of other materials at temperatures of about 200° C. or higher from about 0.01 hour to about 20 hours the one or more than one compound of formula (I)

wherein
R is C 1-12 alkyl, C 6-10 aryl, C 7-18 alkylaryl, or C 7-18 arylalkyl, wherein said alkyl, aryl,
alkylaryl, or arylalkyl are unsubstituted or are substituted by hydroxyl, amino, C 1-4 alkylamino, di-C 1-4 alkylamino, C 1-4 alkoxy, carboxy or C 2-5 alkoxycarbonyl;
M is a metal,
y is a number of from 1 to 4 so that M (+)y is a metal cation where (+)y represents the charge formally assigned to the cation, and p is a number of from 1 to 4, wherein the flame retardant, thermoplastic polymer composition is moldable.

2. The flame retardant, thermoplastic polymer composition according to claim 1 wherein M in formula (I) is Li, K, Na, Mg, Ca, Ba, Zn, Zr, B, Al, Si, Ti, Sn or Sb.

3. The flame retardant, thermoplastic polymer composition according to claim 1 wherein M in formula (I) is Al or Ca.

4. The flame retardant, thermoplastic polymer composition according to claim 1 wherein in formula (I) R is unsubstituted C 1-6 alkyl, C 6 aryl, C 7-10 alkylaryl, or C 7-12 arylalkyl.

5. The flame retardant, thermoplastic polymer composition according to claim 4 wherein R is methyl, ethyl, propyl, isopropyl, benzyl or phenyl.

6. The flame retardant, thermoplastic polymer composition according to claim 5 wherein M in formula (I) is Al or Ca.

7. The flame retardant, thermoplastic polymer composition according to claim 1 wherein the flame retardant material (b) is obtained by a process comprising:
i) preparing an intermediate salt complex by treating one or more phosphonic acid compound with one or more appropriate metal compound to give an intermediate salt complex corresponding to formula (I) comprising multiple values for R and/or M, and then heating in the absence of other materials the intermediate salt complex at temperatures of about 200° C. or higher for about 0.01 hour to about 20 hours;
or
ii) preparing an intimate salt mixture by combining two or more individual metal phosphonic acid salts of formula (I) which have differing values for R and/or M, and then heating in the absence of other materials the intimate salt mixture at temperatures of about 200° C. or higher for about 0.01 hour to about 20 hours;
or
(iii) heating in the absence of other materials at temperatures of about 200° C. or higher for about 0.01 hour to about 20 hours two or more separate metal phosphonic acid salts of formula (I), which differ by having different values for R and/or M to form individual flame retardant materials that are subsequently mixed together to form a blended flame retardant material.

8. The flame retardant, thermoplastic polymer composition according to claim 1 wherein the flame retardant material of b) is obtained by a process comprising heating in the absence of other materials one or more than one compound of formula (I) at temperatures about 220° C. or higher for from about 0.01 hour to about 20 hours.

9. The flame retardant, thermoplastic polymer composition according to claim 1 wherein the thermoplastic polyamide of a) melts at temperatures of 280° C. or higher.

10. The flame retardant, thermoplastic polymer composition according to claim 1 further comprising a reinforcing agent.

11. The flame retardant, thermoplastic polymer composition according to claim 1 wherein the thermoplastic polyamide of a) is a glass filled thermoplastic polyamide.

12. The flame retardant, thermoplastic polymer composition according to claim 1 , wherein the thermoplastic polyamide of a) comprises polyamide 46, polyamide 4T; polyamide MXD,6; polyamide 12,T; polyamide 10,T; polyamide 9,T; polyamide 6,T/6,6; polyamide 6,T/D,T; polyamide 6,6/6,T/6,I; polyamide 6/6,T; or polyamide 6,T/6,I.

13. The flame retardant, thermoplastic polymer composition according to claim 12 wherein the thermoplastic polyamide of a) is glass filled.

14. The flame retardant, thermoplastic polymer composition according to claim 1 further comprising (c) one or more compounds selected from the group consisting of additional flame retardants, synergists and flame retardant adjuvants.

15. The flame retardant, thermoplastic polymer composition according to claim 14 , wherein the one or more additional flame retardants comprise alkyl or aryl phosphine oxide flame retardants, or salts of alkyl or aryl phosphinic acid.

16. The flame retardant, thermoplastic polymer composition according to claim 15 wherein the one or more additional flame retardants comprise an aluminum tris(dialkylphosphinate).

17. The flame retardant, thermoplastic polymer composition according to claim 14 comprising one or more synergists or flame retardant adjuvants, wherein the one or more synergists or flame retardant adjuvants comprise thermally compatible melamine derivatives, melamine condensation products, melamine salts, phosphine oxides, polyphosphine oxides, or metal hydroxides, oxides, oxide hydrates, borates, phosphates, phosphites or silicates.

18. A flame retardant, thermoplastic composition according to claim 17 wherein the one or more synergists or flame retardant adjuvants comprise aluminum hydrogen phosphite, benzylic phosphine oxides, poly benzylic phosphine oxides, melam, melem or melamine metal phosphate wherein the metal comprises aluminum, zinc or magnesium.

19. The flame retardant, thermoplastic polymer composition according to claim 14 comprising (c) one or more additional flame retardant, synergist or flame retardant adjuvant, wherein the one or more additional flame retardant, synergist or flame retardant adjuvant comprises an aluminum tris(dialkylphosphinate), aluminum hydrogen phosphite, methylene-diphenylphosphine oxide-substituted polyaryl ether, xylylenebis(diphenylphosphine oxide), 1,2-bis-(9,10-dihydro-9-oxy-10-phosphaphenanthrene-10-oxide)ethane, a 4,4′-bis(diphenylphosphinylmethyl)-1,1′-biphenyl, melam, melem, or dimelamine zinc pyrophosphate.

20. The flame retardant, thermoplastic polymer composition according to claim 1 wherein the thermoplastic polyamide of a) comprises monomers containing aromatic groups.

Assignees

• Chemtura Corp
• Lanxess Solutions Us Inc

Inventors

• Timberlake Larry D
• Hanson Mark V
• Stockdale Zachary D

Classifications

• C08K7/14

  Glass · CPC title

• C08K5/5317

  Phosphonic compounds, e.g. R—P(:O)(OR')2 · CPC title

• C07F9/5333

  Arylalkane phosphine oxides or thioxides (C07F9/5329 takes precedence) · CPC title

• C07F9/3808

  Acyclic saturated acids which can have further substituents on alkyl · CPC title

• C08K5/34928

  Salts · CPC title