Olefin polymerization process with continuous discharging

Patent metadata

Field	Value
Publication number	US-9765165-B2
Application number	US-201414762288-A
Country	US
Kind code	B2
Filing date	Jan 21, 2014
Priority date	Jan 22, 2013
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

A process for the preparation of a polyolefin in a slurry loop reactor provided with settling legs may include introducing olefin reactants, diluents, and polymerization catalyst into the reactor while circulating. The process may include polymerizing the olefin reactants to produce a slurry, continuously withdrawing the slurry, via the settling legs, and transferring withdrawn solid olefin polymer particles to a recovery section. Each settling leg may have an inlet connected to the reactor and an outlet connected to the recovery section. At least one settling leg is continuously open, allowing continuous withdrawal of slurry. Each outlet of the settling legs may be connected to the recovery section by a conduit provided with a pressure control device. The pressure in the reactor may be controlled by operating the pressure control device.

First claim

The invention claimed is:

1. A process for the preparation of a polyolefin in at least one slurry loop reactor provided with one or more settling legs, comprising the steps of:
introducing into said at least one slurry loop reactor one or more olefin reactants, diluents, polymerization catalyst while circulating said olefin reactants, diluents and polymerization catalyst in said slurry loop reactor;
polymerizing said one or more olefin reactants to produce a polyolefin slurry comprising liquid diluent and solid polyolefin particles;
continuously withdrawing polyolefin slurry comprising solid polyolefin particles and diluent from said at least one slurry loop reactor, via said one or more settling legs and transferring said withdrawn solid polyolefin particles from said at least one slurry loop reactor to a recovery section;
wherein each settling leg has an inlet connected to the at least one slurry loop reactor and an outlet connected to the recovery section, and wherein at least one settling leg is continuously open allowing continuous withdrawal of said polyolefin slurry from said at least one slurry loop reactor, and
wherein each outlet of said one or more settling legs is connected to the recovery section by means of at least one conduit provided with a pressure control device, and wherein the pressure in said at least one slurry loop reactor is controlled by operating said pressure control device.

2. The process according to claim 1 , characterized in that each inlet of said settling legs is connected to said at least one slurry loop reactor by means of one discharge conduit connected to said at least one slurry loop reactor.

3. The process according to claim 2 , wherein at least one flushing system is provided in each settling leg and/or in each discharge conduit.

4. The process according to claim 1 , comprising periodically increasing an opening of the pressure control device.

5. The process according to claim 1 , characterized in that each inlet of said settling legs is connected to said slurry loop reactor by means of one discharge conduit provided with a bulk valve and in that a continuously open settling leg is a settling leg having its inlet bulk valve opened.

6. The process according to claim 1 , wherein said slurry loop reactor is provided with two or more settling legs.

7. The process according to claim 6 , wherein at least two settling legs are continuously open allowing continuous withdrawal of said polyolefin slurry from said slurry loop reactor.

8. The process according to claim 1 , wherein said process further comprises the step of continuously monitoring flow from said one or more settling legs, wherein said monitored flow is selected from the flow of reactants into the recovery section, flow of diluent into the recovery section, the flow of polymer solids into the recovery section, the total flow transferred into the recovery section, and combinations thereof.

9. The process according to claim 1 , wherein said process further comprises the step of controlling the number of continuously open settling legs.

10. The process according to claim 9 , wherein the step of controlling the number of continuously open settling legs comprises one or more of:
ii) raising the number of continuously open settling legs when:
the ratio between polymer solids and reactants transferred into the recovery section is lower than a first predetermined value; and/or
the ratio between polymer solids and diluent transferred into the recovery section is lower than a first predetermined value; and/or
the residence time of polymer solids in the settling legs is lower than a first predetermined value;

iii) lowering the number of continuously open settling legs when:
the ratio between polymer solids and reactants transferred into the recovery section is higher than a second predetermined value; and/or
the ratio between polymer solids and diluent transferred into the recovery section is higher than a second predetermined value; and/or
the residence time of polymer solids in the settling legs is higher than a second predetermined value.

11. The process according to claim 4 , characterized in that at least two settling legs are continuously open allowing continuous withdrawal of said polyolefin slurry from said slurry loop reactor, and in that said process further comprises the step of controlling flow distribution among the continuously open settling legs.

12. The process according to claim 11 , characterized in that the step of controlling flow distribution among the continuously open settling legs comprises:
i) monitoring flow from each settling leg, wherein said monitored flow is selected from flow of reactants into the recovery section, flow of diluent into the recovery section, flow of polymer solids into the recovery section, the total flow transferred into the recovery section from each settling legs and combination thereof; and
ii) adjusting the monitored flow of at least one settling leg, the outlet of said settling leg being provided with a valve which is continuously open and in that said valve is used to adjust the flow of said settling leg.

13. The process according to claim 1 , wherein said slurry loop reactor is single loop reactor.

14. The process according to claim 1 , wherein said slurry loop reactor is the last reactor of a loop reactor comprising at least two loop reactors connected in series.

15. The process according to claim 1 , wherein said olefin is ethylene.

16. The process according to claim 9 , wherein controlling the number of continuously open settling legs comprises monitoring one or more parameters selected from the ratio between polymer solids and reactants transferred into the recovery section, the ratio between polymer solids and diluent transferred into the recovery section, the residence time of polymer solids in each settling leg, and combinations thereof.

17. The process of claim 16 , wherein said monitoring one or more parameters is a continuous monitoring.

18. The process according to claim 12 , wherein monitoring flow from each settling leg is performed continuously.

Assignees

• Total Res & Technology Feluy

Inventors

• Fouarge Louis
• Horre Annelies
• Nauwelaerts Geert
• Tanghe Rudi
• Janssens Johan
• Beuckelaers Steven
• Richet Marc
• Wilderiane Pascal

Classifications

• C08F210/16 Primary

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F2/14

  Organic medium · CPC title