Method for making ceramic thin exterior part

Patent metadata

Field	Value
Publication number	US-9764535-B2
Application number	US-201514621387-A
Country	US
Kind code	B2
Filing date	Feb 13, 2015
Priority date	Feb 18, 2014
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

A method for making a thin ceramic part involves making a casting slurry including a ceramic powder, a solvent, a binder, a plasticizer, and a dispersant. The casting slurry is tape casted to achieve a single layer green tape. At least two single layer green tapes are laminated to form a green tape lamination. The green tape lamination is dry pressed, dried, shaped, degreased, and fired to achieve the exterior component required.

First claim

What is claimed is:

1. A method for making a ceramic exterior part, the method comprising:
preparing a casting slurry comprising a ceramic powder, a solvent, a binder, a plasticizer, and a dispersant;
defoaming the casting slurry in a closed container with a rotating speed in a range from about 1500 r/min to about 2500 r/min;
tape casting the casting slurry to achieve a single layer green tape;
laminating at least two single layer green tapes, to form a green tape lamination, comprising;
coating a layer of casting slurry on a surface of one single layer green tape; and
sandwiching the layer of casting slurry between two single layer green tapes to form the green tape lamination;
dry pressing the green tape lamination to form a dry pressed green tape lamination;
drying the dry pressed green tape lamination to remove the solvent in the green tape lamination and form a dried green tape lamination;
shaping the dried green tape lamination into a shaped green tape lamination;
degreasing the shaped green tape lamination by heating to achieve a degreased green tape lamination; and
firing the degreased green tape lamination.

2. The method of claim 1 , wherein based on a total weight of the casting slurry, the ceramic powder is in an amount of about 50% to about 60%, the solvent is in an amount of about 30% to about 60%, the binder is in an amount of about 3% to about 7%, the plasticizer is in an amount of about 3% to about 9%, and the dispersant is in an amount of about 0.5% to about 1.5%, all by weight.

3. The method of claim 1 , wherein the casting slurry is prepared by having steps of:
weighting the ceramic powder, the solvent, the binder, the plasticizer, and the dispersant;
mixing the ceramic powder, the dispersant and a portion of the solvent in a ball-milling device to have a first ball-milling to achieve a first slurry; and

adding the binder, the plasticizer, and remaining part of the solvent in the ball-milling device to mix with the first slurry and have a second ball-milling to achieve the casting slurry.

4. The method of claim 3 , wherein in the first slurry of the first ball-milling, the ceramic powder is in the amount of about 60% to about 80%, the solvent is in the amount of about 20% to about 30%, and the dispersant is in the amount of about 0.1% to about 0.3%, all by weights based on a total weight of the first slurry.

5. The method of claim 3 , wherein based on a total weight of the binder, the plasticizer, and the remaining part of the solvent in the second ball-milling, the plasticizer is in the amount of about 35% to about 45%, the binder is in the amount of about 25% to about 35%, and the rest part of the solvent is in the amount of about 25% to about 35%, all by weight.

6. The method of claim 3 , wherein the first ball-milling is carried out for about 12 hours to about 20 hours; and the second ball-milling is carried out for about 10 hours to about 20 hours.

7. The method of claim 1 , wherein the ceramic powder is selected from the group consisting of zirconium oxide, aluminum oxide, and combinations of zirconium oxide and aluminum oxide.

8. The method of claim 1 , wherein an average particle size of the ceramic powder is in a range from about 0.1 microns to about 1 micron.

9. The method of claim 1 , wherein the dispersant is selected from the group consisting of glyceryl trioleate, oleic acid, castor oil, fish oil, and combinations thereof.

10. The method of claim 1 , wherein the solvent is a mixture of a main solvent and an additional solvent, the main solvent is selected from the group consisting of ethanol, n-butanol, and a combination thereof; and the additional solvent is selected from the group consisting of acetone, ethylene glycol, and a combination thereof.

11. The method of claim 1 , wherein the binder is selected from the group consisting of polyvinyl butyral, poly methyl methacrylate, and a combination thereof.

12. The method of claim 1 , wherein the plasticizer is selected from the group consisting of poly(oxyethylene), dibutyl phthalate, and a combination thereof.

13. The method of claim 1 , wherein the casting slurry is prepared by using an energy ball-milling machine at a rotating speed from about 800 r/min to about 2200 r/min.

14. The method of claim 1 , wherein a viscosity of the casting slurry is in a range from about 5 Pa·s to about 30 Pa·s.

15. The method of claim 1 , wherein the drying the dry pressed green tape lamination is in a solvent-rich atmosphere formed by gasifying the solvent in the casting slurry.

16. The method of claim 1 , wherein the dry pressing applies a pressing force of about 6 MPa to about 10 MPa to the green tape lamination.

17. The method of claim 1 , wherein the degreasing the shaped green tape lamination is heating the shaped green tape lamination at a heating temperature increased at a rate of about 0.5° C./min to about 1.0° C./min to about 600° C., and kept at about 600° C. for about 0.5 hours to about 2 hours.

18. The method of claim 1 , wherein the firing the degreased green tape lamination is at a temperature of about 1400° C. to about 1600° C. for about 1 hour to about 3 hours.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Xie zhi-peng
• Yan hong-yan
• Liao Yu-Xi

Classifications

• C04B35/6263

  characterised by their solids loadings, i.e. the percentage of solids · CPC title

• C04B35/6261

  Milling · CPC title

• C04B35/109

  containing zirconium oxide or zircon (ZrSiO4) · CPC title

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title

• C04B35/634

  Polymers (C04B35/636 takes precedence) · CPC title