Scrubbing solution for absorption of carbon dioxide and method for accelerating the absorption by germanium dioxide

Patent metadata

Field	Value
Publication number	US-9764283-B2
Application number	US-201314414110-A
Country	US
Kind code	B2
Filing date	Jul 8, 2013
Priority date	Jul 17, 2012
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.

First claim

What is claimed is:

1. A carbon dioxide scrubbing solution consisting essentially of:
an absorbent for carbon dioxide comprising an amino acid salt, and
an absorption rate activator additive,
wherein the activator additive comprises germanium dioxide.

2. The scrubbing solution as claimed in claim 1 ,
wherein the proportion of germanium dioxide is between 0.01 and 10 weight percent.

3. The scrubbing solution as claimed in claim 1 ,
wherein the proportion of germanium dioxide is between 0.05 and 2 weight percent.

4. The scrubbing solution as claimed in claim 1 ,
wherein the absorbent further comprises a secondary, tertiary or sterically hindered amine, and/or a plurality of amino acid salts.

5. The scrubbing solution as claimed in claim 1 ,
wherein the scrubbing solution is in the form of an aqueous solution.

6. A method for accelerating the absorption of carbon dioxide, comprising:
contacting a gas comprising carbon dioxide with a carbon dioxide scrubbing solution consisting essentially of an absorbent comprising amines, or ethanolamines, or amino acid salts, or potash, or a combination, and also germanium dioxide, with absorption of carbon dioxide,
wherein the carbon dioxide is physically dissolved in the scrubbing solution and chemically absorbed by the absorbent, and
wherein the germanium dioxide is catalytically active for at least one reaction step of the chemical absorption of carbon dioxide.

7. The method as claimed in claim 6 ,
wherein the germanium dioxide is adjusted in the scrubbing liquid to a proportion of 0.01 to 10 weight percent.

8. The method as claimed in claim 7 ,
wherein the proportion of germanium dioxide is adjusted between 0.05 and 2 weight percent.

9. The method as claimed in claim 6 ,
wherein the absorbent comprises secondary, tertiary or sterically hindered amines.

10. The method as claimed in claim 6 ,
wherein the gas which is treated as comprising carbon dioxide is the flue gas of a fossil fuel steam power plant, of a gas turbine plant or of a combined gas and steam turbine plant.

11. A composition of matter comprising:
a carbon dioxide scrubbing solution, the solution further comprising:
a liquid phase comprising a liquid bulk and a boundary layer on the liquid bulk when the scrubbing solution adjoins a gas phase comprising carbon dioxide;
the liquid phase further comprising a solution comprising a carbon dioxide absorbent and germanium dioxide; and
wherein the germanium dioxide is at a concentration effective to be catalytically active in at least one reaction step of chemical absorption of carbon dioxide in the boundary layer.

12. The composition of claim 11 , further comprising:
the liquid phase comprises an aqueous solution; and
the germanium dioxide is at a concentration effective to catalyze a carbamate-water reaction, forming bicarbonate, in the boundary layer.

13. The composition of claim 12 , wherein the germanium dioxide is at a concentration effective to catalyze the bicarbonate formation in the boundary layer and not in the liquid bulk.

14. The composition of claim 11 , further comprising:
the liquid phase comprising an aqueous solution; and
the germanium dioxide at a concentration of 0.01 to 10 weight percent and effective to catalyze a fast carbamate-water reaction in the boundary layer.

15. The composition of claim 11 , wherein the carbon dioxide absorbent comprises an amino acid salt.

16. The composition of claim 11 , wherein the carbon dioxide absorbent comprises a secondary amino acid salt, and wherein the germanium dioxide is at a concentration effective to be catalytically active in forming a protonated amino acid salt in the boundary layer.

Assignees

• Siemens Ag

Inventors

• Fischer Bjorn
• Joh Ralph
• Kinzl Markus
• Kuettel Diego Andres
• Schneider Rudiger

Classifications

• B01D2258/0283

  Flue gases · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D53/78

  with gas-liquid contact · CPC title

• B01D2252/602

  Activators, promoting agents, catalytic agents or enzymes · CPC title

• B01D2252/204

  Amines · CPC title