Safened herbicidal compositions comprising a pyridine carboxylic acid herbicide

Patent metadata

Field	Value
Publication number	US-9763445-B2
Application number	US-201514854153-A
Country	US
Kind code	B2
Filing date	Sep 15, 2015
Priority date	Sep 15, 2014
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

Disclosed herein are safened herbicidal compositions comprising (a) a pyridine carboxylic acid herbicide or an agriculturally acceptable N-oxide, salt or ester thereof and (b) a quinolinyloxyacetate safener or agriculturally acceptable salt or ester thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylic acid herbicide or an agriculturally acceptable N-oxide, salt or ester thereof and (b) an quinolinyloxyacetate safener or agriculturally acceptable salt or ester thereof.

First claim

What is claimed is:

1. A safened herbicidal composition, comprising:
(a) a pyridine carboxylic acid herbicide defined by Formula (III)

wherein
X is CY, wherein Y is halogen, C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio or C 1 -C 3 haloalkylthio;
R 1 is OR 1′ , wherein R 1′ is hydrogen, C 1 -C 8 alkyl, C 1 -C 6 haloalkyl, or C 7 -C 10 arylalkyl;
R 2 is halogen, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 1 -C 4 alkylthio, C 1 -C 4 haloalkylthio, amino, C 1 -C 4 alkylamino, C 2 -C 4 haloalkylamino, formyl, C 1 -C 3 alkylcarbonyl, C 1 -C 3 haloalkylcarbonyl, or cyano;
R 3 and R 4 are independently hydrogen, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 alkenyl, C 3 -C 6 haloalkenyl, C 3 -C 6 alkynyl, formyl, C 1 -C 3 alkylcarbonyl, C 1 -C 3 haloalkylcarbonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 alkylcarbamyl, or C 1 -C 6 alkylsulfonyl,
R 6 and R 6′ are independently hydrogen, halogen, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, cyclopropyl, halocyclopropyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 haloalkylthio, amino, C 1 -C 4 alkylamino, C 2 -C 4 haloalkylamino, OH, CN, or NO 2 ;
R 7 and R 7′ are independently hydrogen, halogen, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, cyclopropyl, halocyclopropyl, C 2 -C 4 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 haloalkylthio, amino, C 1 -C 4 alkylamino, C 1 -C 4 haloalkylamino, or phenyl; and
R 8 is hydrogen, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 alkenyl, C 3 -C 6 haloalkenyl, C 3 -C 6 alkynyl, formyl, C 1 -C 3 alkylcarbonyl, C 1 -C 3 haloalkylcarbonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 alkylcarbamyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 trialkylsilyl, or phenyl;
or an agriculturally acceptable N-oxide or salt thereof; and

(b) a quinolinyloxyacetate safener, or an agriculturally acceptable salt or ester thereof.

2. The composition of claim 1 , wherein the pyridine carboxylic acid herbicide comprises one of the following:

3. The composition of claim 1 , wherein the pyridine carboxylic acid herbicide comprises

4. The composition of claim 1 , wherein the quinolinyloxyacetate safener comprises cloquintocet or an agriculturally acceptable salt or ester thereof.

5. The composition of claim 1 , wherein the quinolinyloxyacetate safener comprises cloquintocet-mexyl.

6. The composition of claim 1 , wherein the weight ratio of (a) in g ae/ha to (b) in g ai/ha is from 65:1 to 1:5.

7. The composition of claim 1 , further comprising an agriculturally acceptable adjuvant or carrier.

8. The composition of claim 1 , further comprising an additional pesticide.

9. The composition of claim 1 , wherein the active ingredients in the composition consist of (a) and (b).

10. A method of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying to soil or water to control the emergence or growth of vegetation the composition of claim 1 .

11. The method of claim 10 , wherein (a) and (b) are applied post-emergence to the undesirable vegetation.

12. The method of claim 10 , wherein (a) is applied in amount of from 0.1 g ae/ha to 300 g ae/ha.

13. The method of claim 10 , wherein (b) is applied in amount of from 1 g ai/ha to 300 g ai/ha.

14. The method of claim 10 , further comprising applying an additional pesticide.

15. The method of claim 10 , wherein the undesirable vegetation is controlled in wheat, barley, triticale, rye, teff, oats, corn/maize, sorghum , rice, sugarcane, vineyards, orchards, perennial plantation crops, soybeans, cotton, sunflower, oilseed rape/canola, sugarbeets, turf, range and pasture, industrial vegetation management (IVM), rights-of-way, or combinations thereof.

16. The method of claim 10 , wherein the undesirable vegetation includes a broadleaf weed.

17. The method of claim 10 , wherein the undesirable vegetation comprises a herbicide resistant or tolerant weed.

18. The method of claim 10 , wherein the undesirable vegetation includes velvetleaf (ABUTH, Abutilon theophrasti ), pigweed (AMARE, Amaranthus retroflexus ), winter rape (BRSNW, Brassica napus ), shepherd's purse (CAPBP, Capsella bursa pastoris ), cornflower (CENCY, Centaurea cyanus or Cyanus segetum ), lambsquarters (CHEAL, Chenopodium album ), thistle (CIRAR, Cirsium arvense ), nutsedge (CYPES, Cyperus esculentus ), poinsettia (EPHHL, Euphorbia heterophylla ), cleavers (GALAP, Galium aparine ), Helianthus annuus (HELAN, common sunflower), kochia (KCHSC, Kochia scoparia ), prickly lettuce (LACSE, Lactuca serriola ), purple deadnettle (LAMPU, Lamium purpureum ), wild chamomile (MATCH, Matricaria chamomilla ), common poppy (PAPRH, Papaver rhoeas ), wild buckwheat (POLCO, Polygonum convolvulus ), Russian thistle (SASKR, Salsola kali ), giant foxtail (SETFA, Setaria faberi ), green foxtail (SETVI, Setaria viridis ), wild mustard (SINAR, Sinapis arvensis ), common sorghum (SORVU, Sorghum vulgare ), chickweed (STEME, Stellaria media ), bird's-eye speedwell (VERPE, Veronica persica ), wild pansy (VIOTR, Viola tricolor ), or a combination thereof.

19. The method of claim 10 , wherein the active ingredients applied to the vegetation or an area adjacent the vegetation or applied to soil or water to control the emergence or growth of vegetation consist of (a) and (b).

Assignees

• Dow Agrosciences Llc
• Dow Agrosciences Llc

Inventors

• Satchivi Norbert M
• Bangel Bryston L
• Schmitzer Paul R

Classifications

• A01N43/40 Primary

  six-membered rings · CPC title

• A01N43/78

  1,3-Thiazoles; Hydrogenated 1,3-thiazoles · CPC title

• A01N43/54

  1,3-Diazines; Hydrogenated 1,3-diazines · CPC title

• A01N43/42

  condensed with carbocyclic rings · CPC title

• A01N25/32

  Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions · CPC title