Electrolyte solutions including a phosphoranimine compound, and energy storage devices including same

Patent metadata

Field	Value
Publication number	US-9761910-B2
Application number	US-201514720493-A
Country	US
Kind code	B2
Filing date	May 22, 2015
Priority date	May 23, 2014
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

An electrolyte solution comprising at least one phosphoranimine compound and a metal salt. The at least one phosphoranimine compound comprises a compound of the chemical structure

where X is an organosilyl group or a tert-butyl group and each of R 1 , R 2 , and R 3 is independently selected from the group consisting of an alkyl group, an aryl group, an alkoxy group, or an aryloxy group. An energy storage device including the electrolyte solution is also disclosed.

First claim

What is claimed is:

1. An electrolyte solution comprising:
at least one phosphoranimine compound of the chemical structure

 where X is an organosilyl group or a tert-butyl group and each of R 1 , R 2 , and R 3 is independently selected from the group consisting of an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, a substituted alkoxy group, an aryloxy group, or a substituted aryloxy group, and
a metal salt.

2. The electrolyte solution of claim 1 , wherein each of R 1 , R 2 , and R 3 is different.

3. The electrolyte solution of claim 1 , wherein at least two of R 1 , R 2 , and R 3 are different.

4. The electrolyte solution of claim 1 , wherein X is a trimethylsilyl group.

5. The electrolyte solution of claim 1 , wherein X is the tert-butyl group.

6. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound is a liquid at a temperature from about 20° C. to about 25° C.

7. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound exhibits a viscosity of from about 1 centipoise at room temperature to about 30 centipoise at room temperature.

8. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound comprises at least one of

9. The electrolyte solution of claim 1 , wherein at least one of R 1 , R 2 , or R 3 comprises a halogenated alkyl group, a halogenated aryl group, a halogenated alkoxy group, or a halogenated aryloxy group.

10. The electrolyte solution of claim 1 , wherein at least one of R 1 , R 2 , or R 3 comprises a cationic pendant group.

11. The electrolyte solution of claim 1 , wherein the metal salt comprises a salt of an alkali metal or a salt of an alkaline earth metal.

12. The electrolyte solution of claim 1 , wherein the metal salt comprises a lithium salt, a sodium salt, a magnesium salt, or combinations thereof.

13. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound comprises from about 0.1% by weight to less than about 15% by weight of the electrolyte solution.

14. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound comprises from greater than or equal to about 15% by weight to less than about 50% by weight of the electrolyte solution.

15. The electrolyte solution of claim 1 , wherein the at least one phosphoranimine compound comprises greater than or equal to about 50% by weight of the electrolyte solution.

16. The electrolyte solution of claim 1 , further comprising at least one organic solvent.

17. An energy storage device, comprising:
a positive electrode, a negative electrode separated from the positive electrode, and an electrolyte solution in contact with the positive electrode and the negative electrode, the electrolyte solution comprising:
at least one phosphoranimine compound of the chemical structure

 where X is an organosilyl group or a tert-butyl group and each of R 1 , R 2 , and R 3 is independently selected from the group consisting of an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, a substituted alkoxy group, an aryloxy group, or a substituted aryloxy group.

18. The energy storage device of claim 17 , wherein the electrolyte solution further comprises a salt of an alkali metal or a salt of an alkaline earth metal.

19. The energy storage device of claim 17 , wherein the electrolyte solution further comprises a lithium salt, a sodium salt, a magnesium salt, or combinations thereof.

20. The energy storage device of claim 17 , further comprising a separator between the positive electrode and the negative electrode.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Klaehn John R
• Dufek Eric J
• Rollins Harry W
• Harrup Mason K
• Gering Kevin L

Classifications

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M10/0569 Primary

  characterised by the solvents · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title