Lithium ion battery electrodes including graphenic carbon particles

Patent metadata

Field	Value
Publication number	US-9761903-B2
Application number	US-201414530007-A
Country	US
Kind code	B2
Filing date	Oct 31, 2014
Priority date	Sep 30, 2011
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

Lithium ion battery electrodes including graphenic carbon particles are disclosed. Lithium ion batteries containing such electrodes are also disclosed. The graphenic carbon particles may be used in cathodes of such batteries by depositing a graphenic carbon particle-containing coating of a conductive substrate such as a metal foil The use of graphenic carbon particles in the cathodes results in improved performance of the lithium ion batteries.

First claim

We claim:

1. A lithium ion battery electrode material provided as a coating on a substrate, the coating comprising:
from 80 to 99.5 weight percent of a lithium-containing active material;
10 weight percent or less of thermally produced graphenic carbon particles; and
a binder, wherein the coating has an electrical resistivity of less than 240 ohms/square.

2. The lithium ion battery electrode material coating of claim 1 , wherein the thermally produced graphenic carbon particles comprise from 0.5 to 10 weight percent, and the binder comprises from 0.5 to 10 weight percent.

3. The lithium ion battery electrode material coating of claim 1 , wherein the lithium-containing active material comprises from 87 to 99 weight percent, and the thermally produced graphenic carbon particles comprise from 1 to 8 weight percent.

4. The lithium ion battery electrode material coating of claim 1 , wherein the lithium-containing active material comprises lithium iron phosphate, lithium cobalt oxide, lithium nickel cobalt aluminate, lithium manganate, lithium nickel cobalt manganate or a combination thereof.

5. The lithium ion battery electrode material coating of claim 1 , wherein the thermally produced graphenic carbon particles have aspect ratios of greater than 3:1 and are produced in a thermal zone having a temperature of greater than 3,500° C.

6. The lithium ion battery electrode material coating of claim 1 , wherein the thermally produced graphenic carbon particles have average thicknesses of from 0.3 to 6 nanometers.

7. The lithium ion battery electrode material coating of claim 1 , wherein the thermally produced graphenic carbon particles have BET specific surface area of greater than 70 square meters per gram.

8. The lithium ion battery electrode material coating of claim 1 , wherein the binder comprises a polymer selected from PVDF, acrylics or a combination thereof.

9. The lithium ion battery electrode material coating of claim 1 , further comprising a dispersant.

10. The lithium ion battery electrode material coating of claim 1 , wherein the substrate is conductive.

11. The lithium ion battery electrode material coating of claim 1 , wherein the coating has a thickness of from 10 to 500 microns.

12. The lithium ion battery electrode material coating of claim 1 , wherein the coating has a thickness of from 20 to 200 microns.

13. The lithium ion battery electrode material coating of claim 1 , wherein the coating has an electrical resistivity of less than 100 ohms/square.

14. A lithium ion battery cathode material provided as a coating on a substrate, the coating comprising:
from 80 to 99.5 weight percent of a lithium-containing active material;
10 weight percent or less of graphenic carbon particles; and
a binder, wherein the coating has an electrical resistivity of less than 200 ohms/square.

15. A lithium ion battery comprising:
an anode;
a cathode;
a separator between the anode and the cathode; and
an electrolyte in contact with the anode and the cathode,
wherein the cathode comprises a coating on a substrate and the coating comprises from 80 to 99.5 weight percent of a lithium-containing active material, 10 weight percent or less of thermally produced graphenic carbon particles, and a binder wherein the coating has a thickness of from 10 to 500 microns.

16. The lithium ion battery of claim 15 , wherein the substrate comprises a metal foil.

17. A lithium ion battery electrode material provided as a coating on a substrate, the coating comprising:
from 80 to 99.5 weight percent of a lithium-containing active material;
10 weight percent or less of thermally produced graphenic carbon particles;
a binder; and
a dispersant.

Assignees

• Ppg Ind Ohio Inc

Inventors

• Hellring Stuart D
• Daughenbaugh Randy E
• Vanier Noel R
• Hung Cheng-Hung
• Burgman John W

Classifications

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/623

  fluorinated polymers · CPC title