Binder and lithium ion battery using the same

Patent metadata

Field	Value
Publication number	US-9761881-B2
Application number	US-201615092572-A
Country	US
Kind code	B2
Filing date	Apr 6, 2016
Priority date	Apr 7, 2015
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The present application discloses a binder for a lithium ion battery, which comprises a polymer obtained through emulsion polymerization of a monomer in the presence of a reactive emulsifying agent. The binder is used in fabrication of a lithium ion electrode plate, whereby a thin film formed on the surface of an electrode membrane and fine channels formed in the electrode membrane with the use of a conventional emulsifying agent during the electrode membrane-forming process are eliminated, and the lithium ion conductivity of the electrode membrane is improved. Meanwhile, with the use of the reactive emulsifying agent, the bonding effect of the binder and the stability of the electrode membrane are improved, thereby greatly improving the charging rate and cycle life of the lithium ion battery.

First claim

The invention claimed is:

1. A binder for a lithium ion battery, comprising a polymer, wherein the polymer is obtained through emulsion polymerization of a monomer in the presence of a reactive emulsifying agent;
the monomer comprises at least one compound having a chemical structure of Formula I:

wherein R 11 is hydrogen or R 11 is selected from an alkyl group having 1 to 20 carbon atoms; R 12 is hydrogen or R 12 is selected from an alkyl group having 1 to 20 carbon atoms; R 13 is hydrogen or R 13 is selected from an alkyl group having 1 to 20 carbon atoms; and R 14 is hydrogen or R 14 is selected from an alkyl group having 1 to 20 carbon atoms;
the reactive emulsifying agent is selected from a compound with a chemical structure comprising a moiety of Formula IV:

wherein R 41 is hydrogen or R 41 is selected from an alkyl group having 1 to 20 carbon atoms; and R 42 is hydrogen or R 42 is selected from an alkyl group having 1 to 20 carbon atoms.

2. The binder for a lithium ion battery according to claim 1 , wherein R 41 and R 42 are all hydrogen.

3. The binder for a lithium ion battery according to claim 1 , wherein the reactive emulsifying agent is selected from at least one of a maleate and a derivative thereof, wherein the maleate and the derivative thereof are selected from at least one of a compound with a chemical structure of Formula IX:

where R 91 is hydrogen or R 91 is selected from an alkyl group having 1 to 20 carbon atoms; R 92 is hydrogen or R 92 is selected from an alkyl group having 1 to 10 carbon atoms; R 93 is hydrogen or R 93 is selected from an alkyl group having 1 to 10 carbon atoms; and M + is selected from at least one of Li + , Na + , K + , Rb + , Cs + , and NH 4 + .

4. The binder for a lithium ion battery according to claim 1 , wherein the weight ratio of the reactive emulsifying agent to the monomer is 1-3:100.

5. The binder for a lithium ion battery according to claim 1 , wherein the polymer has a glass transition temperature from 0° C. to 50° C.

6. The binder for a lithium ion battery according to claim 1 , wherein the polymer has a weight average molecular weight from 300 kDa to 1,500 kDa.

7. The binder for a lithium ion battery according to claim 1 , wherein the binder has a solid content from 25 wt % to 50 wt %.

8. An electrode plate, comprising at least one of the binders according to claim 1 .

9. A lithium ion battery, comprising at least one of the binders according to claim 1 .

Assignees

• Ningde Amperex Technology Ltd
• Dongguan Amperex Tech Ltd

Inventors

• Shen Hongguang
• Luo Fuping
• Gao Chao
• Zheng Qiang
• Wang Shengwei

Classifications

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• C08F2/26

  anionic · CPC title

• C08F222/165

  the ester chains containing seven or more carbon atoms · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title