Organic electroluminescence element and material for organic electroluminescence element

Patent metadata

Field	Value
Publication number	US-9761811-B2
Application number	US-201314404255-A
Country	US
Kind code	B2
Filing date	May 15, 2013
Priority date	Jun 28, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

Provided are a novel organic electroluminescent device material and an organic electroluminescent device using the same. The organic electroluminescent device material includes a compound represented by the following formula (1). The organic electroluminescent device of the present invention includes a substrate, an anode, an organic layer, and a cathode, the anode, the organic layer, and the cathode being laminated on the substrate, in which the organic layer contains the organic electroluminescent device material. The organic electroluminescent device material is suitable as a host material for a light-emitting layer containing a phosphorescent light-emitting dopant. In the formula, L represents an aromatic group including at least one aromatic heterocyclic group, and Ar 1 to Ar 4 each represent an aromatic group.

First claim

The invention claimed is:

1. An organic electroluminescent device material, comprising a compound represented by the general formula (1):

in the general formula (1):
L represents a divalent aromatic group selected from an aromatic hydrocarbon group represented by the formula (2) or (3) and having 6 to 50 carbon atoms, and an aromatic heterocyclic group represented by the formula (2), (3), or (4) and having 3 to 50 carbon atoms, and n represents an integer of from 1 to 6, provided that when n represents 1, L represents the aromatic heterocyclic group, and when n represents 2 or more, L may be different at each occurrence and at least one L represents the aromatic heterocyclic group;
in each of the formula (2) and the formula (3), X's each independently represent methine, substituted methine, a carbon atom, or nitrogen, provided that two of X's each represent a carbon atom;
in the formula (4), Y represents NR, oxygen, or sulfur, R represents an aromatic hydrocarbon group having 6 to 50 carbon atoms or an aromatic heterocyclic group having 3 to 50 carbon atoms, and Z's each independently represent methine, substituted methine, a carbon atom, or nitrogen, provided that two of Z's each represent a carbon atom;
substituents in a case where X's or Z's represent substituted methine each independently represent an alkyl group having 1 to 30 carbon atoms, a cycloalkyl group having 3 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an alkynyl group having 2 to 30 carbon atoms, an aromatic hydrocarbon group having 6 to 50 carbon atoms, or an aromatic heterocyclic group having 3 to 50 carbon atoms;
W's each independently represent hydrogen, an alkyl group having 1 to 30 carbon atoms, a cycloalkyl group having 3 to 30 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an alkynyl group having 2 to 30 carbon atoms, an aromatic hydrocarbon group having 6 to 50 carbon atoms, or an aromatic heterocyclic group having 3 to 50 carbon atoms; and
Ar 1 to Ar 4 each independently represent an aromatic hydrocarbon group having 6 to 50 carbon atoms or an aromatic heterocyclic group having 3 to 50 carbon atoms.

2. An organic electroluminescent device material according to claim 1 , wherein in the general formula (1), L represents a divalent aromatic group represented by the formula (2) or (4).

3. An organic electroluminescent device material according to claim 1 , wherein:
in the general formula (1), L represents a divalent aromatic group represented by the formula (2) or (4);
at least one of X's in the formula (2) represents nitrogen; and
six of Z's in the formula (4) each represent methine and two of Z's in the formula (4) each represent a carbon atom.

4. An organic electroluminescent device material according to claim 1 , wherein the compound comprises a compound represented by the general formula (5):

in the general formula (5), L and Ar 1 to Ar 4 have the same meanings as in the general formula (1).

5. An organic electroluminescent device material according to claim 1 , wherein the compound comprises a compound represented by the general formula (6):

in the general formula (6), L has the same meaning as in the general formula (1).

6. An organic electroluminescent device, comprising:
a substrate;
an anode;
at least one organic layer; and
a cathode,
the anode, the at least one organic layer, and the cathode being laminated on the substrate,
wherein the at least one organic layer comprises an organic layer containing the organic electroluminescent device material according to claim 1 .

7. An organic electroluminescent device according to claim 6 , wherein the organic layer containing the organic electroluminescent device material comprises at least one layer selected from the group consisting of a light-emitting layer, an electron-transporting layer, a hole-transporting layer, an electron-blocking layer, and a hole-blocking layer.

8. An organic electroluminescent device according to claim 7 , wherein the organic layer containing the organic electroluminescent device material is a light-emitting layer containing a phosphorescent light-emitting dopant.

9. An organic electroluminescent device, comprising:
a substrate;
an anode;
at least one organic layer; and
a cathode,
the anode, the at least one organic layer, and the cathode being laminated on the substrate,
wherein the at least one organic layer comprises an organic layer containing the organic electroluminescent device material according to claim 4 .

Assignees

• Nippon Steel & Sumikin Chem Co

Inventors

• Suda Mitsuru

Classifications

• C09K2211/104

  with other heteroatoms · CPC title

• C07F7/0816 Primary

  said ring comprising Si as a ring atom · CPC title

• C09B69/008

  Dyes containing a substituent, which contains a silicium atom · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• H01L51/0073

  Electricity · mapped topic