Film-forming material

Patent metadata

Field	Value
Publication number	US-9761741-B2
Application number	US-201113990916-A
Country	US
Kind code	B2
Filing date	Dec 1, 2011
Priority date	Dec 2, 2010
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

There is provided a novel material used for solar cells that can contribute to the improvement in maximum output of solar cells. A film-forming material for forming a light-collecting film on a transparent electrode of a solar cell, including an aromatic group-containing organic polymer compound (A), wherein the film-forming material exhibits an index of refraction of 1.5 to 2.0 at a wavelength of 633 nm and a transmittance of 95% or more with respect to light having a wavelength of 400 nm, and a solar cell obtained by coating a cured film made from the film-forming material on a surface of a transparent electrode.

First claim

The invention claimed is:

1. A film-forming material for forming a light-collecting film on a transparent electrode of a solar cell, the film-forming material comprising:
(I) an aromatic group-containing organic polymer compound (A) that is a compound having a fluorene skeleton, having an aromatic cardo structure and a structure of the formula (1), and having a weight average molecular weight of at least 5,000, aromatic cardo structures being linked through a structure containing an ether bond and a thioether bond:

where R 1 to R 10 are independently a hydrogen atom, a C 1-10 alkyl group, a C 1-10 haloalkyl group, a C 1-10 alkoxy group, a halogen atom, a nitro group, a formyl group, a cyano group, an amino group, a carboxyl group, a phosphonyl group, a sulfonyl group, a phenyl group which is optionally substituted with W 8 , a naphthyl group which is optionally substituted with W 8 , a thienyl group which is optionally substituted with W 8 or a furyl group which is optionally substituted with W 8 , provided that one group of R 1 to R 5 forms the —S— group together with one group of R 6 to R 10 ; and
W 8 is a C 1-10 alkyl group, a C 1-10 haloalkyl group, a C 1-10 alkoxy group, a hydroxy group, a halogen atom, a nitro group, a formyl group, a cyano group, a carboxyl group, a phosphonyl group or a sulfonyl group,
wherein the aromatic group-containing organic polymer (A) is a compound obtained by carrying out condensation reaction of at least one compound having an aromatic cardo structure and at least one compound having the structure of the above formula (1),
wherein the compound having a structure of the formula (1) is selected from the group consisting of:

bis(4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-butyl-6-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-isobutyl-6-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-t-butyl-6-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-butyl-5-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-isobutyl-5-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-t-butyl-5-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-methyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-ethyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-propyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-isopropyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-butyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-isobutyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-t-butyl-4-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-butyl-6-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-isobutyl-6-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-t-butyl-6-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-butyl-5-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-isobutyl-5-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-t-butyl-5-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-methyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
bis(2-ethyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-propyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-isopropyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-butyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-isobutyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane,
(2-t-butyl-3-(oxiran)-2-ylmethoxy)phenyl)sulfane, and
bis(4-(oxirane-2-ylmethoxy)-2,3-diamyl-phenyl)sulfane; and
(II) as a component (C) a compound substituted with a blocked isocyanate group;
wherein the film-forming material exhibits an index of refraction of 1.5 to 2.0 at a wavelength of 633 nm and a transmittance of 95% or more with respect to light having a wavelength of 400 nm.

2. The film-forming material according to claim 1 , wherein the organic polymer compound (A) is a compound having at least four benzene rings.

3. The film-forming material according to claim 1 , wherein the film-forming material contains the component (C) at 10 to 100 parts by mass relative to 100 parts by mass of the organic polymer compound (A).

4. The film-forming material according to claim 1 , wherein the film-forming material further contains a solvent (E) and is in a form of varnish.

5. A solar cell obtained by coating a cured film made from the film-forming material according to claim 1 on a surface of a transparent electrode.

Assignees

• Ebara Kazuya
• Imamura Hikaru
• Sakamoto Rikimaru
• Nissan Chemical Ind Ltd

Inventors

• Ebara Kazuya
• Imamura Hikaru
• Sakamoto Rikimaru

Classifications

• C08G18/8061

  masked with compounds having only one group containing active hydrogen · CPC title

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• H01L31/02168 Primary

  Electricity · mapped topic

• C08G18/3851

  containing three nitrogen atoms in the ring · CPC title

• Y02E10/52

  PV systems with concentrators · CPC title