Process for preparing a conductive composition using a masterbatch

Patent metadata

Field	Value
Publication number	US-9761350-B2
Application number	US-201314372814-A
Country	US
Kind code	B2
Filing date	Jan 18, 2013
Priority date	Jan 20, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A composition can include polystyrene, modified-polystyrene, or a mixture thereof. The polystyrene, modified-polystyrene, or mixture thereof can include carbon nanotubes. The composition can also include a polyolefin. The composition can include at most 1.90% by weight of carbon nanotubes, based on a total weight of the composition. The composition can be prepared by providing a masterbatch including at least 5% by weight of carbon nanotubes based on a total weight of the masterbatch, and a polyolefin and/or styrenic copolymer. The masterbatch can be blended with polystyrene, modified-polystyrene, or a mixture thereof, and with a polyolefin, in amounts such that a conductive composition is obtained. An article can be made of the conductive composition.

First claim

The invention claimed is:

1. A process for preparing a conductive composition comprising:
(a) providing a masterbatch comprising at least 5% by weight of carbon nanotubes based on a total weight of the masterbatch, and a polyolefin and/or styrenic copolymer;
(b) blending the masterbatch of step (a) with a blend of polystyrene, or high-impact polystyrene, or a mixture thereof, and a polyolefin, in amounts such that the conductive composition is obtained, wherein the conductive composition comprises at most 1.90% by weight of carbon nanotubes, based on the total weight of the conductive composition;
wherein the conductive composition has a surface resistivity of at most 10 4 Ohm/sq, measured in accordance with ASTM-D257.

2. The process according to claim 1 , wherein the conductive composition comprises at least 30% by weight of the polystyrene, the high-impact polystyrene, or the mixture thereof, based on the total weight of the conductive composition.

3. The process according to claim 1 , wherein the conductive composition comprises at least 50%, by weight of the polystyrene, the high-impact polystyrene, or the mixture thereof, based on the total weight of the conductive composition.

4. The process according to claim 1 , wherein the conductive composition has a surface resistivity of at most 10 3 Ohm/sq, measured in accordance with ASTM-D257.

5. The process according to claim 1 , wherein the conductive composition comprises at least 0.3% and at most 1.90% by weight of carbon nanotubes relative to the total weight of the conductive composition.

6. The process according to claim 1 , wherein the conductive composition comprises at least 0.5% and at most 1.90% by weight of carbon nanotubes relative to the total weight of the conductive composition.

7. The process according to claim 1 , wherein the polyolefin of step (b) and, if any in step (a), is polyethylene, polypropylene, or a combination thereof.

8. The process according to claim 7 , wherein the polyolefin of step (b) and, if any in step (a), is polyethylene.

9. The process according to claim 7 , wherein the polyolefins are used in both steps (a) and (b), and wherein the polyolefins of step (a) and step (b) are the same.

10. The process according to claim 1 , wherein the conductive composition comprises at least 15% by weight of the polyolefin, based on the total weight of the conductive composition.

11. The process according to claim 1 , wherein the masterbatch comprises the styrenic copolymer, or the styrenic copolymer and the polyolefin; and
wherein the styrenic copolymer is styrene-butadiene-styrene block copolymer (SBS) or styrene-ethylene-butadiene-styrene block copolymer (SEB S).

12. The process according to claim 11 , wherein the content of the styrenic copolymer in the conductive composition ranges between 1 and 25% by weight, based on the total weight of the conductive composition.

13. The process according to claim 11 , wherein the content of the styrenic copolymer in the conductive composition ranges between 2 and 20% by weight, based on the total weight of the conductive composition.

14. The process according to claim 1 , wherein the content of carbon nanotubes in the masterbatch ranges between 5 and 30% by weight, based on the total weight of the masterbatch.

15. The process according to claim 1 , wherein the content of carbon nanotubes in the masterbatch ranges between 8 and 20% by weight, based on the total weight of the masterbatch.

16. An article made of the conductive composition prepared by the process of claim 1 .

17. The process according to claim 1 , wherein the conductive composition comprises at least 15% and at most 60% by weight of the polyolefin; at least 30% by weight of the polystyrene, the high-impact polystyrene, or the mixture thereof; and at least 0.1% and at most 1.90% of the carbon nanotubes; each based on the total weight of the conductive composition.

18. The process according to claim 1 , wherein, in step (b), the polyolefin comprises linear low density polyethylene.

19. The process according to claim 1 , wherein the conductive composition comprises at least two immiscible phases comprising a polystyrene phase and a polyolefin phase.

20. The process according to claim 1 , wherein the composition comprises at least 30% by weight high-impact polystyrene, or at least 30% by weight a mixture of polystyrene and high impact polystyrene.

21. The process according to claim 20 , wherein the composition comprises at least 50% by weight high-impact polystyrene, or at least 50% by weight a mixture of polystyrene and high impact polystyrene.

Assignees

• Total Res & Technology Feluy

Inventors

• Rousseaux Dimitri
• Duc Michel
• Lodefier Philippe
• Lhost Olivier

Classifications

• H01B3/441

  from alkenes · CPC title

• H01B3/442

  from aromatic vinyl compounds · CPC title

• C08K3/04

  Carbon · CPC title

• C08J3/22

  using masterbatch techniques · CPC title

• C08K2201/011

  Nanostructured additives · CPC title