Methods of removing a wellbore isolation device using galvanic corrosion of a metal alloy in solid solution

Patent metadata

Field	Value
Publication number	US-9759035-B2
Application number	US-201414199820-A
Country	US
Kind code	B2
Filing date	Mar 6, 2014
Priority date	Jun 8, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

At least a portion of a wellbore isolation device consists essentially of: a metal alloy, wherein the metal alloy: (A) comprises magnesium at a concentration of at least 50% by volume of the metal alloy; and (B) at least partially dissolves in the presence of an electrolyte. A method of removing the wellbore isolation device comprises: contacting or allowing the wellbore isolation device to come in contact with an electrolyte; and allowing at least a portion of the metal alloy to dissolve.

First claim

What is claimed is:

1. A method of removing a wellbore isolation device comprising:
contacting or allowing the wellbore isolation device to come in contact with an electrolyte, wherein at least a portion of the wellbore isolation device consists essentially of a metal alloy, wherein the ingredients making up the metal alloy are in solid solution consisting of a single homogenous phase, wherein the metal alloy:
(A) comprises magnesium at a concentration of at least 50% by volume of the metal alloy;
(B) is alloyed with nickel; and
(C) at least partially dissolves in the presence of the electrolyte; and

allowing at least a portion of the metal alloy to dissolve.

2. The method according to claim 1 , wherein the isolation device is capable of restricting or preventing fluid flow between a first wellbore interval and a second wellbore interval.

3. The method according to claim 1 , wherein isolation device is a ball and a seat, a plug, a bridge plug, a wiper plug, or a packer.

4. The method according to claim 1 , wherein the metal alloy is the mandrel of a packer or plug, a spacer ring, a slip, a wedge, a retainer ring, an extrusion limiter or backup shoe, a mule shoe, a ball, a flapper, a ball seat, a sleeve, or any other downhole tool or component of a downhole tool used for zonal isolation.

5. The method according to claim 1 , wherein the magnesium is at a concentration in the range of about 70% to about 98% by volume of the metal alloy.

6. The method according to claim 1 , wherein the metal alloy comprises at least one other ingredient in addition to the magnesium, and wherein the at least one other ingredient is selected from one or more metals, one or more non-metals, or combinations thereof.

7. The method according to claim 6 , wherein the one or more metals is selected from the group consisting of lithium, beryllium, calcium, aluminum, tin, bismuth, scandium, chromium, manganese, thorium, nickel, copper, zinc, yttrium, zirconium, praseodymium, silver, cadmium, terbium, neodymium, gadolinium, erbium, oxides of any of the foregoing, and any combinations thereof.

8. The method according to claim 6 , wherein the one or more non-metals is selected from the group consisting of graphite, carbon, silicon, boron nitride, and combinations thereof.

9. The method according to claim 6 , wherein the isolation device is capable of withstanding a specific pressure differential.

10. The method according to claim 6 , wherein the metal alloy has a desired density, and wherein the at least one other ingredient is selected such that the metal alloy has the desired density.

11. The method according to claim 6 , wherein the metal alloy has a desired standard state reduction potential, and wherein the at least one other ingredient is selected and for more than one other ingredient, the ingredient's relative concentrations or ratios are selected to provide the desired standard state reduction potential.

12. The method according to claim 6 , wherein at least the portion of the metal alloy dissolves in a desired amount of time.

13. The method according to claim 12 , wherein the at least one other ingredient is selected such that the metal alloy has a desired rate of dissolution and dissolves in the desired amount of time.

14. The method according to claim 12 , wherein the pH of the electrolyte is selected such that at least the portion of the metal alloy dissolves in the desired amount of time.

15. The method according to claim 1 , wherein the electrolyte is selected from the group consisting of solutions of an acid, a base, a salt, and combinations thereof.

16. The method according to claim 1 , further comprising introducing the electrolyte into the wellbore.

17. The method according to claim 1 , further comprising the step of placing the isolation device into a portion of the wellbore, wherein the step of placing is performed prior to the step of contacting or allowing the isolation device to come in contact with the electrolyte.

18. The method of claim 1 , wherein the metal alloy is not coated.

19. At least a portion of a wellbore isolation device consists essentially of:
a metal alloy, wherein the ingredients making up the metal alloy are in solid solution consisting of a single homogenous phase, wherein the metal alloy is not coated, and wherein the metal alloy:
(A) comprises magnesium at a concentration of at least 50% by volume of the metal alloy;
(B) is alloyed with nickel;
(C) at least partially dissolves in the presence of an electrolyte; and
(D) has been heat treated at a temperature in the range of 300° F. to 500° F. for 1 to 24 hours.

Assignees

• Halliburton Energy Services Inc

Inventors

• Fripp Michael L
• Walton Zachary W
• Murphree Zachary R

Classifications

• E21B34/063

  Valve or closure with destructible element, e.g. frangible disc (E21B34/103 takes precedence) · CPC title

• E21B33/12

  Packers; Plugs (used for cementing E21B33/134, E21B33/16) · CPC title

• E21B2200/06

  Sleeve valves · CPC title

• E21B34/14

  operated by movement of tools, e.g. sleeve valves operated by pistons or wire line tools {(E21B34/066 takes precedence)} · CPC title

• E21B33/1208 Primary

  characterised by the construction of the sealing or packing means (E21B33/1277 takes precedence) · CPC title