Mixtures of olefin-ester copolymer with polyolefin as viscosity modifier

Patent metadata

Field	Value
Publication number	US-9758743-B2
Application number	US-201314376851-A
Country	US
Kind code	B2
Filing date	Feb 14, 2013
Priority date	Feb 17, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A lubricant composition of an oil of lubricating viscosity; an esterified copolymer with a backbone comprising units derived from (i) an α-olefin monomer of at least about 6 carbon atoms and (ii) an ethylenically unsaturated carboxylic acid in a mole ratio of 1:3 to 3:1; and a polymer comprising olefin monomer units of 3 to 5 carbon atoms, wherein at least 50 percent by weight of such units contain fewer than 6 carbon atoms and wherein less than 5 percent by weight of such units are ethylene monomer units; exhibits good power transfer efficiency and elastohydrodynamic film thickness.

First claim

The invention claimed is:

1. A lubricant composition comprising
(a) about 16 to about 84.5 percent by weight of an oil of lubricating viscosity having a kinematic viscosity at 100° C. of less than about 15 mm 2 /s which comprises a poly-α-olefin; and
(b) about 12 to about 44 percent by weight of an esterified copolymer having a weight average molecular weight of about 5,000 to about 30,000, with a backbone comprising units derived from (i) an α-olefin monomer of at least about 10 to about 14 carbon atoms and (ii) maleic anhydride or derivative thereof, wherein the mole ratio of (i) α-olefin monomer to (ii) maleic anhydride or derivative thereof is about 0.8:1 to about 1.1:1, said copolymer further containing nitrogen functionality derived from reaction of said copolymer with an amine which comprises an imidazolidinone, said copolymer containing about 0.075 to about 0.25 weight percent nitrogen; and
(c) about 0.3 to about 25 percent by weight of a polyisobutene having a kinematic viscosity at 100° C. of at least about 1000 mm 2 /s and a weight average molecular weight of about 1,000 to about 3,000;
wherein the polymers (b) and (c) are present in a weight ratio (b):(c) of about 6:4 to about 9:1 and wherein the total amount of polymer (b) plus (c) is about 25 to about 50 percent by weight of the lubricant composition.

2. The lubricant composition of claim 1 wherein the backbone of copolymer (b) further comprises units of a vinyl aromatic monomer.

3. The lubricant of claim 1 further comprising at least one of a detergent, a dispersant, an antioxidant, an additional viscosity improver, an antiwear agent, an anti-scuffing agent, an extreme-pressure agent, a corrosion inhibitor, a foam inhibitor, a pour point depressant, or a friction modifier.

4. The lubricant of claim 1 wherein the lubricant contains 0.01 to 1 weight percent sulfur and 0.005 to 0.1 weight percent phosphorus.

5. A method for lubricating a mechanical device, comprising supplying thereto the lubricant of claim 1 .

6. The method of claim 5 wherein the mechanical device comprises a hypoid gear.

7. The method of claim 5 wherein the mechanical device comprises a component of a driveline system of a vehicle.

8. The lubricant composition of claim 1 wherein the oil of lubricating viscosity consists essentially of a poly-α-olefin.

Assignees

• Lubrizol Corp

Inventors

• Knapton Daniel J
• Barton William R S
• Wessler Brett
• Baker Mark R

Classifications

• C10M2205/024

  Propene · CPC title

• C10N2030/58

  Elastohydrodynamic lubrication, e.g. for high compressibility layers · CPC title

• C10M2219/046

  Overbased sulfonic acid salts · CPC title

• C10N2040/26

  Two-strokes {or two-cycle engines} · CPC title

• C10N2040/045

  for continuous variable transmission [CVT] · CPC title