Transparent resin composition for sealing organic electroluminescence element, resin sheet for sealing organic electroluminescence element, and apparatus for displaying image

Patent metadata

Field	Value
Publication number	US-9758690-B2
Application number	US-201514750577-A
Country	US
Kind code	B2
Filing date	Jun 25, 2015
Priority date	Dec 25, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A transparent resin composition for sealing an organic EL element and other things having a sufficient effect of blocking moisture and excellent flexibility is provided. As essential components, a thermoplastic resin, tackifying resin and organometallic compound represented by the following chemical formula are included, having a light transmittance of 85% or more, and having a relationship of AM/Y<162,
A: the acid value excluding the organometallic compound M: the weight average molecular weight of the organometallic compound Y: the weight ratio of the organometallic compound with respect to 100 parts by weight of resin components

wherein the thermoplastic resin contains a hydride of a styrene-based A-B-A type triblock, wherein R1 to R4 represent organic groups including an alkyl group, aryl group, alkoxy group, cycloalkyl group and acyl group, each having a carbon number of 1 or more and 8 or less, M represents a metal atom having 3 valency.

First claim

The invention claimed is:

1. A transparent resin composition, comprising:
a thermoplastic resin;
a tackifying resin; and
an organic metallic compound represented by formula (1),
having a light transmittance of 85% or more through a thickness of 0.1 mm for a light having a wavelength of 550 nm, and
having a relationship of AM/Y <162,
wherein
A is the acid value (mgCH 3 ONa/g) of the resin composition excluding the organic metallic compound of formula (1),
M is the weight average molecular weight of the organic metallic compound of formula (1), and
Y is the weight ratio of the organic metallic compound of formula (1) with respect to 100 parts by weight of resin components, wherein Y is from 3.4 to 10,
wherein the thermoplastic resin contains a hydride of a styrene-based A-B-A triblock polymer,

wherein
R1 to R4 independently represent an organic group selected from the group consisting of an alkyl group, aryl group, alkoxy group, cycloalkyl group and acyl group, each having a carbon number of 1 or more and 8 or less,
M represents a metal atom having 3 valency, and
R1 to R4 may be the same or different organic groups to each other.

2. The transparent resin composition according to claim 1 , wherein the styrene-based A-B-A triblock polymer is at least one selected from the group consisting of a styrene-ethylene-butylene-styrene copolymer, styrene-ethylene-propylene-styrene copolymer, styrene-ethylene-ethylene-propylene-styrene copolymer and styrene-isobutylene-styrene copolymer.

3. The transparent resin composition according to claim 1 , wherein the tackifying resin is at least one selected from the group consisting of a hydride of a C-5 petroleum resin, hydride of a C-9 petroleum resin, and hydride of a petroleum resin obtained through copolymerization of a C-5 petroleum resin with a C-9 petroleum resin.

4. The transparent resin composition according to claim 1 , wherein the AM/Y is 0 or more and 161 or less.

5. A resin sheet, comprising a sealing layer comprising the transparent resin composition according to claim 1 .

6. The transparent resin composition according to claim 1 , wherein the weight average molecular weight of the organic metallic compound is from 274 to 490.

7. The transparent resin composition according to claim 1 , wherein the acid value (A) is from 0 to 2.0 (mgCH 3 ONa/g).

8. The transparent resin composition according to claim 1 , wherein the organic metallic compound of formula (1) is selected from the group consisting of:

Assignees

• Furukawa Electric Co Ltd

Inventors

• Ishiguro Kunihiko
• Mieda Tetsuya
• Saito Keiji
• Aoyama Masami
• Nakamura Toshimitsu
• Mihara Naoaki
• Asanuma Takumi

Classifications

• C09D125/08 Primary

  Copolymers of styrene (C09D129/08, C09D135/06, C09D155/02 take precedence) · CPC title

• H01L51/524

  Electricity · mapped topic

• C08L57/02

  Copolymers of mineral oil hydrocarbons · CPC title

• C08K5/56

  Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond · CPC title

• C09D123/22

  Copolymers of isobutene; Butyl rubber {; Homo- or copolymers of other iso-olefines} · CPC title