Polyarylene sulfide for oil and gas flowlines

Patent metadata

Field	Value
Publication number	US-9758674-B2
Application number	US-201313804481-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Apr 13, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

Flowlines for use in oil and gas applications are described. The flowlines include a barrier layer that includes polyarylene sulfide composition that exhibits high strength and flexibility characteristics. Methods for forming the flowlines are also described. Formation methods include dynamic vulcanization of a polyarylene sulfide composition that includes an impact modifier dispersed throughout the polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier throughout the composition. The flowlines can include production fluid flowlines, supporting fluid flowlines, bundled flowlines, etc. and can be utilized as risers, pipelines, jumpers, and the like.

First claim

What is claimed is:

1. A flowline for an oil and/or gas production application, the flowline having a tubular shape and defining a bore for carrying a fluid, wherein the flowline contains a layer that comprises a polyarylene sulfide composition, the polyarylene sulfide composition of the flowline being formed by melt processing (i) a linear polyarylene sulfide containing less than about 1 mol. % of cross-linking units based on the total monomer units of the polyarylene sulfide, (ii) from 20 wt. % to 35 wt. % of an epoxy-functionalized impact modifier, and (iii) from 1.0 wt. % to 1.75 wt. % of a polyfunctional crosslinking agent that includes a dicarboxylic acid, wherein the crosslinking agent is supplied following distribution of the impact modifier with the polyarylene sulfide, and wherein the melt processing forms a crosslinked epoxy-functionalized impact modifier that is a reaction product of epoxy-functionalized monomer units and a polyfunctional crosslinking agent, wherein the composition exhibits a tensile elongation at break of 70% or more as determined in accordance with ISO Test No. 527 at a temperature of 23° C. and at a speed of 50 mm/min.

2. The flowline of claim 1 , wherein the polyarylene sulfide composition has
an elongation at yield of greater than about 4.5% as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min; and/or
a tensile modulus of less than about 3000 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min.

3. The flowline of claim 1 , wherein the flowline is a riser, a bundled flowline, a support fluid flowline, or a pipe-in-pipe.

4. The flowline of claim 1 , further comprising a fitting, connector, anchor mooring, buoy, or yoke, attached to the flowline, the fitting, connector, anchor, mooring, buoy, or yoke comprising the polyarylene sulfide composition.

5. The flowline of claim 1 , wherein the polyarylene sulfide is not functionalized.

6. The flowline of claim 1 , further comprising one or more additives.

7. The flowline of claim 1 , wherein the oil and/or gas production application is an offshore production application or an onshore production application.

8. The flowline of claim 1 , wherein the polyarylene sulfide composition is free of plasticizers.

9. The flowline of claim 1 , wherein the polyarylene sulfide composition has an elongation at yield of greater than about 7% as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min and/or a tensile modulus of less than about 2300 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min.

10. The flowline of claim 1 , wherein the polyarylene sulfide composition has a deflection temperature under load of greater than about 90° C. as measured according to ISO Test No. 75 at 1.8 MPa.

11. The flowline of claim 1 , wherein the polyarylene sulfide composition has a notched Charpy impact strength of greater than about 3 kJ/m 2 as measured according to ISO Test No. 179-1 at a temperature of 23° C. and/or a loss in Charpy notched impact strength as determined according to ISO Test No, 179-1 at 23° C. of less than about 17% following exposure of about 500 hours to a strong acid solution at a temperature of about 80° C.

12. The flowline of claim 1 , wherein the polyarylene sulfide composition has a notched Charpy impact strength of greater than about 8 kJ/m 2 as measured according to ISO Test No. 179-1 at a temperature of 23° C. and/or a loss in Charpy notched impact strength as determined according to ISO Test No. 179-1 at 23° C. of less than about 25% following exposure of about 500 hours to a strong acid solution at a temperature of about 80° C.

13. The flowline of claim 1 , wherein the polyarylene sulfide composition has a tensile break stress of greater than about 30 MPa as measured according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min and/or a tensile break strain of greater than about 25% as measured according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min.

14. The flowline of claim 1 , wherein the polyarylene sulfide composition has a halogen content of less than about 1000 ppm.

15. The flowline of claim 1 , wherein the polyarylene sulfide composition meets the V-0 flammability standard at a thickness of 0.2 millimeters.

16. The flowline of claim 1 , wherein the polyarylene sulfide composition exhibits a permeation resistance to a fuel or a fuel source of less than about 3 g-mm/m 2 -day as determined according to SAE Testing Method No. J2665.

17. The flowline of claim 1 , wherein the epoxy-functionalized impact modifier includes methacrylic monomer units.

18. The flowline of claim 17 , the epoxy-functionalized impact modifier further includes α-olefin monomer units.

19. The flowline of claim 1 , wherein the dicarboxylic acid includes terephthalic acid.

20. The flowline of claim 1 , wherein the epoxy-functionalized monomer units include epoxy-functionalized methacrylic monomer units.

21. The flowline of claim 1 , wherein polyarylene sulfides constitute from about 20% wt. % to about 78.6 wt. % by weight of the composition.

22. The flowline of claim 1 , wherein the polyarylene sulfide is functionalized.

23. The flowline of claim 22 , wherein the functionalized polyarylene sulfide is a reaction product of a polyarylene sulfide and a disulfide compound having a reactive functionality.

24. The flowline of claim 1 , wherein the flowline contains multiple layers, at least one of which contains the polyarylene sulfide composition.

25. The flowline of claim 24 , wherein the flowline contains an inner carcass that supports and adjacent barrier layer.

26. The flowline of claim 25 , wherein the barrier layer contains the polyarylene sulfide composition.

27. The flowline of claim 25 , wherein the flowline further contains an outer layer, the outer layer containing the polyarylene sulfide composition.

28. The flowline of claim 1 , wherein the flowline contains a single layer.

29. A system that comprises the flowline of claim 1 in combination with a fluid.

30. The system of claim 29 , wherein the fluid is an injection fluid.

31. The system of claim 29 , wherein the fluid is a production fluid.

32. The flowline of claim 1 , wherein the composition exhibits a tensile elongation at break of about 80 or more.

Assignees

• Ticona Llc

Inventors

• Luo Rong
• Zhao Xinyu

Classifications

• F27B14/00

  Crucible or pot furnaces · CPC title

• F16L9/133

  the walls consisting of two layers · CPC title

• Y10T428/1352

  Polymer or resin containing [i.e., natural or synthetic] · CPC title

• C08L81/04 Primary

  Polysulfides · CPC title

• F16L9/147

  comprising only layers of metal and plastics with or without reinforcement · CPC title