Molding resin composition including chlorinated vinyl chloride-based resin, and molded article thereof

Patent metadata

Field	Value
Publication number	US-9758633-B2
Application number	US-201615292666-A
Country	US
Kind code	B2
Filing date	Oct 13, 2016
Priority date	Sep 27, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The present invention aims to provide a chlorinated vinyl chloride-based resin composition with excellent thermal stability and a molded body thereof. The present invention relates to a resin composition for molding, including a chlorinated vinyl chloride-based resin, a thermal stabilizer, and a polyalcohol and/or a partial ester of a polyalcohol. The chlorinated vinyl chloride-based resin has a chlorine content of 65% by weight or more and less than 72% by weight. The chlorinated vinyl chloride-based resin has, based on the total number of moles of a structural unit (a) —CCl 2 —, a structural unit (b) —CHCl—, and a structural unit (c) —CH 2 —, a proportion of the structural unit (a) of 17.5 mol % or less, a proportion of the structural unit (b) of 46.0 mol % or more, and a proportion of the structural unit (c) of 37.0 mol % or less. The thermal stabilizer contains at least one of a compound represented by the formula Ca 1-x Zn x (OH) 2 where x satisfies the inequality 0<x<1 and a compound represented by the formula Ca 1-y Zn y O where y satisfies the inequality 0<y<1.

First claim

The invention claimed is:

1. A resin composition for molding, comprising:
a chlorinated vinyl chloride-based resin;
a thermal stabilizer; and
a polyalcohol and/or a partial ester of a polyalcohol,
the chlorinated vinyl chloride-based resin having a chlorine content of 65% by weight or more and less than 72% by weight,
the chlorinated vinyl chloride-based resin having, based on the total number of moles of a structural unit (a) —CCl 2 —, a structural unit (b) —CHCl—, and a structural unit (c) —CH 2 —, a proportion of the structural unit (a) of 17.5 mol % or less, a proportion of the structural unit (b) of 46.0 mol % or more, and a proportion of the structural unit (c) of 37.0 mol % or less,
the thermal stabilizer containing at least one of a compound represented by the formula Ca 1-x Zn x (OH) 2 where x satisfies the inequality 0<x<1 and a compound represented by the formula Ca 1-y Zn y O where y satisfies the inequality 0<y<1,
the resin composition containing the thermal stabilizer in an amount of 0.4 to 10 parts by weight based on 100 parts by weight of the chlorinated vinyl chloride-based resin,
the chlorinated vinyl chloride-based resin having a UV absorbance at 216 nm of 0.8 or less, measured by recording spectrophotometer at a concentration of 800 ppm, and
a time required for the amount of dehydrochlorination from the chlorinated vinyl chloride-based resin at 190° C. to reach 7000 ppm is 90 seconds or longer.

2. The resin composition for molding according to claim 1 ,
wherein the chlorinated vinyl chloride-based resin has a chlorine content of 65% by weight or more and less than 69% by weight.

3. The resin composition for molding according to claim 1 ,
wherein the chlorinated vinyl chloride-based resin has a chlorine content of 69% by weight or more and less than 72% by weight.

4. The resin composition for molding according to claim 1 ,
wherein the chlorinated vinyl chloride-based resin has, based on the total number of moles of the structural unit (a) —CCl 2 —, the structural unit (b) —CHCl—, and the structural unit (c) —CH 2 —, a proportion of the structural unit (b) of 58.0 mol % or more and a proportion of the structural unit (c) of 35.8 mol % or less.

5. The resin composition for molding according to claim 1 ,
wherein the resin composition is free of β-diketone.

6. The resin composition for molding according to claim 1 ,
wherein the resin composition for molding contains the polyalcohol and/or the partial ester of a polyalcohol in a total amount within the range of 0.05 to 3 parts by weight based on 100 parts by weight of the chlorinated vinyl chloride-based resin.

7. The resin composition for molding according to claim 1 , further comprising a stabilizing aid.

8. The resin composition for molding according to claim 7 ,
wherein the stabilizing aid comprises at least one of sodium adipate and hydrotalcite.

9. The resin composition for molding according to claim 7 ,
wherein the stabilizing aid comprises an organic acid salt.

10. The resin composition for molding according to claim 7 ,
wherein the stabilizing aid comprises a higher fatty acid salt.

11. A molded body molded from the resin composition for molding according to claim 1 .

Assignees

• Sekisui Chemical Co Ltd
• Tokuyama Sekisui Co Ltd

Inventors

• Matsumura Kenichi
• Seiki Atsushi
• MASHINO Norikazu
• YOSHIYAMA Kei
• Kawano Atsushi

Classifications

• C08L27/24

  halogenated · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08K2003/2296

  of zinc · CPC title

• C08K2003/2206

  of calcium, strontium or barium · CPC title

• C08K5/103

  with polyalcohols · CPC title