Method for producing foamed molded bodies

Patent metadata

Field	Value
Publication number	US-9758613-B2
Application number	US-201314397513-A
Country	US
Kind code	B2
Filing date	Apr 26, 2013
Priority date	Apr 30, 2012
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The invention relates to a method for producing foamed molded bodies comprising the steps of
A) providing a mold, and B) introducing a foam-forming reaction mixture into the mold under variable pressure of injection,

wherein the method is characterized in that

the foam-forming reaction mixture has a fiber time of ≧20 s to ≦60 s.

First claim

The invention claimed is:

1. A method for producing foamed molded bodies comprising the steps of
A) providing a mold, and
B) introducing a foam-forming reaction mixture from a mixing head into the mold under variable pressure of injection, wherein the foam-forming reaction mixture exits the mixing head at a speed which decreases over time from an initial exit speed to a decreased exit speed, wherein the initial exit speed and the decreased exit speed are each in the range of >1 m/s to <5 m/s,
and
wherein the foam-forming reaction mixture has a fiber time at 20° C. of ≧20 s to ≦60 s
wherein the foam-forming reaction mixture comprises an emulsion, and wherein the emulsion contains the following constituents:
(I) an isocyanate-reactive composition A containing a polyol mixture A1 of at least three polyols A1a, A1 and A1e as continuous phase
and
(II) at least one physical blowing agent T as disperse phase,
wherein:
(i) A1a is a polyether polyol having a hydroxyl number of 15 mg KOH/g to 550 mg KOH/g and having a functionality of 1.5 to 6.0, obtained by addition reaction of an epoxide onto one or more starter compounds selected from the group consisting of carbohydrates and di- or higher-functional alcohols;
(ii) A1b is a polyether polyol having a hydroxyl number of 100 mg KOH/g to 550 mg KOH/g and having a functionality of 1.5 to 5.0, obtained by addition reaction of an epoxide onto an aromatic amine; and
(iii) A1e is a polyester polyether polyol having a hydroxyl number of 100 mg KOH/g to 450 mg KOH/g and having a functionality of 1.5 to 3.5, obtained by addition reaction of an epoxide onto the esterification product of an aromatic dicarboxylic acid derivative and a di- or more highly functional alcohol.

2. The method as claimed in claim 1 , wherein the foam-forming reaction mixture is introduced into the mold at a temporally variable rate.

3. The method as claimed in claim 1 , wherein the ratio of the time in which the foam-forming reaction mixture is introduced into the mold at a temporally variable rate to the cream time of the foam-forming reaction mixture is in the range from 0.1 to 10.

4. The method as claimed in claim 1 , wherein the temporal variation of the introduction rate and/or injection pressure of the foam-forming reaction mixture is effected by varying the power output of a pump motor acting on the reaction mixture.

5. The method as claimed in claim 1 , wherein the foam-forming reaction mixture is obtained from the reaction of a first reaction component comprising said emulsion and a second reaction component and the a first reaction component comprising said emulsion and a second reaction component are each introduced via nozzles into a mixing chamber in said mixing head.

6. The process as claimed in claim 1 , wherein the foam-forming reaction mixture has a fiber time of ≧25 s to ≦55 s.

7. The method as claimed in 1 , wherein the injection pressure is reduced over time in step B).

8. The method as claimed in claim 1 , wherein the injection pressure in step B) is varied by at least 15 bar/s.

9. The method as claimed in claim 1 , wherein the mold in cross section comprises a horizontally disposed floor volume and also vertically disposed volumes in communication with the floor volume.

10. The method as claimed in claim 1 , wherein the mold comprises a pipework line on the outside and a pipework line disposed therein on the inside and the foam-forming reaction mixture is introduced between the inside and outside pipework lines.

11. The method as claimed in claim 1 , wherein the mold comprises two spaced-apart areal elements and the foam-forming reaction mixture is introduced between these areal elements.

12. The method as claimed in claim 1 , wherein the foam-forming reaction mixture is introduced by the mixing head having a mixing chamber and wherein furthermore the outflow cross section of the mixing chamber is varied during the introducing.

13. The method as claimed in claim 1 , wherein the at least one physical blowing agent T is at least one member selected from the group consisting of hydrocarbons, halogenated ethers and perfluorinated hydrocarbons having from 1 to 8 carbon atoms each.

14. A foamed molded body obtainable by a method as claimed in claim 1 .

15. A refrigerator, a freezer or a fridge-freezer combination comprising a foamed molded body as claimed in claim 14 .

16. The method as claimed in claim 2 , wherein the time during which the foam-forming reaction mixture is introduced into the mold at a temporally variable rate is ≧1 s to ≦20 s.

17. The method according to claim 3 , wherein the ratio of the time in which the foam-forming reaction mixture is introduced into the mold at a temporally variable rate to the cream time of the foam-forming reaction mixture is in the range from 0.5 to 5.

18. The method as claimed in claim 4 , wherein the power output of the pump motor is effected by varying the rotary speed of the motor using a frequency converter.

19. The method as claimed in claim 5 , wherein the foam-forming reaction mixture is selected so as to obtain a rigid polyurethane foam.

20. The process as claimed in claim 6 , wherein the foam-forming reaction mixture has a fiber time of ≧30 s to ≦50 s.

21. The method as claimed in 7 , wherein the injection pressure is reduced over time in step B) in a very substantially linear manner.

22. The method as claimed in claim 8 , wherein the injection pressure in step B) is varied by at least 20 bar/s.

23. The refrigerator, freezer or fridge-freezer combination as claimed in claim 15 , wherein the provided mold is a housing component of the refrigerator, of the freezer or of the fridge-freezer combination.

Assignees

• Covestro Deutschland Ag

Inventors

• Albers Reinhard
• Wirtz Hans-Guido
• Loof Michael
• Pielasch Andreas

Classifications

• B29C44/18 Primary

  Filling preformed cavities {(B29C44/1204 takes precedence)} · CPC title

• C08J9/14

  organic · CPC title

• B05B1/3026

  Gate valves; Sliding valves; Cocks (B05B1/326 takes precedence) · CPC title

• C08J2205/10

  Rigid foams · CPC title

• B29C44/42

  using pressure difference, e.g. by injection or by vacuum · CPC title