Carrier treatment to improve catalytic performance of an ethylene oxide catalyst

Patent metadata

Field	Value
Publication number	US-9758498-B2
Application number	US-201514811309-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	May 16, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A method for lowering the sodium content of different carriers which may have different physical properties as well as varying degrees of sodium is provided. The method, which lowers the sodium content from the surface, subsurface as well as the binding layer of the carrier, includes contacting a carrier with water. A rinse solution is recovered from the contacting. The rinse solution includes leached sodium from the carrier. The sodium content in the rinse solution is then determined. The contacting, recovering and determining are repeated until a steady state in the sodium content is achieved.

First claim

What is claimed is:

1. A process for producing a silver-based ethylene oxide catalyst, said process comprising:
selecting a carrier;
contacting said carrier with water;
recovering a rinse solution from the contacting of the carrier with said water, said rinse solution comprises leached sodium from said carrier;
determining sodium content in the rinse solution, wherein said contacting, recovering and determining are repeated until a steady state in sodium content in the rinse solution is achieved;
depositing a catalytic effective amount of silver on said carrier; and
depositing a promoting amount of at least one promoter prior to, coincidentally with, or subsequent to the deposition of the catalytic effective amount of silver.

2. The process of claim 1 , wherein the sodium content in the rinse solution is determined by measuring electrical conductivity of the rinse solution.

3. The process of claim 1 , wherein said at least one promoter is comprises an alkali metal, a Group IIA alkaline earth metal, a transition metal, a rare earth metal, sulfur, boron, phosphorus, or a halogen.

4. The process of claim 1 , wherein said at least one promoter comprises a combination of cesium lithium, and rhenium.

5. The process of claim 1 , wherein said at least one promoter comprises at least potassium.

6. The process of claim 4 , wherein said at least one promoter further comprises sulfur, tungsten or a combination of sulfur and tungsten.

7. The process of claim 1 , wherein said contacting, recovering and determining is performed in a batch mode and said steady state is achieved when analysis of the sodium content of at least three successive rinse solutions vary in a value within ±0.5%.

8. The process of claim 2 , wherein said contacting, recovering and determining is performed in a batch mode and said steady state is achieved when the electrical conductivity of at least three determinations is within a value of ±0.5%.

9. The process of claim 1 , wherein said contacting, recovering and determining is performed in a batch mode batch mode, said batch mode comprises circulating said water around said carrier.

10. The process of claim 1 , wherein said contacting, recovering and determining is performed in a continuous mode and said steady state is achieved when a slope of a change of electrical conductivity of the rinsing solution is lower than 0.2μ Siemens/hour.

11. The process of claim 10 , wherein said continuous mode comprises trickling said water through a column containing a bed of said carrier at a flow rate to continuously wet the bed of said carrier.

12. A method for the vapor phase conversion of ethylene to ethylene oxide in the presence of oxygen, said method comprising:
providing a catalyst; and
reacting a reaction mixture comprising ethylene and oxygen in the presence of said catalyst, wherein said providing said catalyst comprises:
selecting a carrier;
contacting said carrier with water;
recovering a rinse solution from the contacting of the carrier with said water, said rinse solution comprises leached sodium from said carrier;
determining sodium content in the rinse solution, wherein said contacting, recovering and determining are repeated until a steady state in the sodium content is achieved;
depositing a catalytic effective amount of silver on said carrier; and
depositing a promoting amount of at least one promoter prior to, coincidentally with, or subsequent to the deposition of the catalytic effective amount of silver.

13. The method of claim 12 , wherein the sodium content in the rinse solution is determined by measuring electrical conductivity of the rinse solution.

14. The method of claim 12 , wherein said at least one promoter is comprises an alkali metal, a Group IIA alkaline earth metal, a transition metal, a rare earth metal, sulfur, phosphorus, boron, or a halogen.

15. The method of claim 12 , wherein said at least one promoter comprises a combination of cesium, lithium, and rhenium.

16. The method of claim 15 , wherein said at least one promoter further comprises sulfur, tungsten or a combination of sulfur and tungsten.

17. The method of claim 12 , wherein said contacting, recovering and determining is performed in a batch mode and said steady state is achieved when analysis of the sodium content of at least three successive rinse solutions vary in a value within ±0.5%.

18. The method of claim 13 , wherein said contacting, recovering and determining is performed in a batch mode and said steady state is achieved when the electrical conductivity of at least three determinations is within a value of ±0.5%.

19. The method of claim 12 , wherein said contacting, recovering and determining is performed in a batch mode batch mode, said batch mode comprises circulating said water around said carrier.

20. The method of claim 12 , wherein said contacting, recovering and determining is performed in a continuous mode and said steady state is achieved when a slope of a change of electrical conductivity of the rinsing solution is lower than 0.2μ Siemens/hour.

21. The method of claim 20 , wherein said continuous mode comprises trickling said water through a column containing of bed of said carrier at a flow rate to wet the bed of said carrier.

Assignees

• Scient Design Co

Inventors

• Rizkalla Nabil
• Rokicki Andrzej

Classifications

• B01J23/50

  Silver · CPC title

• B01J23/66

  Silver or gold · CPC title

• C07D301/10 Primary

  with catalysts containing silver or gold · CPC title

• B01J21/04

  Alumina · CPC title

• B01J37/0201

  Impregnation · CPC title