Method and device for catalytic methanation of synthesis gas

Patent metadata

Field	Value
Publication number	US-9758440-B2
Application number	US-201314907726-A
Country	US
Kind code	B2
Filing date	Jul 26, 2013
Priority date	Jul 26, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The method for catalytic methanation of synthesis gas includes the following steps: 1) feeding the synthesis gas into the bottom of a reactor of an upward concurrent flow transporting bed so as to adequately mix and preheat with methanation catalyst entering the bottom of the reactor until the activation temperature of the catalyst is reached and then the methanation reaction begins; and 2) after the methanation reaction, immediately passing the product gas and the catalyst grains outputted from the transporting bed into a gas-solid separator to perform a rapid separation so as to obtain the product gas.

First claim

What is claimed is:

1. A method for catalytic methanation of synthesis gas, the method comprising the steps of:
1) the synthesis gas is fed into bottom of an upward concurrent flow transporting bed reactor, the synthesis gas is fully mixed and preheated with methanation catalyst particles entering into the bottom of the upward concurrent flow transporting bed reactor, and then the mixture undergo methanation reaction after the temperature reaches the activation temperature of the catalyst, wherein outlet temperature of the upward concurrent flow transporting bed reactor is from 400° C. to 700° C., operation pressure is from 0.1 to 6.0 MPa and gas superficial speed is from 1 to 10 m/s;
2) after the methanation reaction is completed, product gas and the catalyst particles output from the transporting bed reactor directly enter into a gas-solid separator in order to quickly separate the product gas and the catalyst particles to obtain the product gas.

2. The method for catalytic methanation of synthesis gas according to claim 1 , wherein the catalyst particles obtained by the separation in step 2) enter into a loop seal and exchange heat in a heat exchanger of the loop seal and then circulate to the transporting bed reactor.

3. The method for catalytic methanation of synthesis gas according to claim 1 , wherein heat-exchange tube bundles are embedded inside or a cooling water jacket is installed outside the upward concurrent flow transport bed to remove the exothermic heat of methanation in step 1).

4. The method for catalytic methanation of synthesis gas according to claim 1 , wherein the product gas in step 2) produces overheated steam as sub-product after heat exchange via a heat exchanger.

Assignees

• Inst Process Eng Cas
• China Kingsun Mat Tech Co Ltd

Inventors

• Xu Guangwen
• Liu Jiao
• Cui Dianmiao
• Yu Jian

Classifications

• C10L3/08 Primary

  Production of synthetic natural gas · CPC title

• C07C1/042

  Temperature controlling devices; Heat exchangers · CPC title

• B01J2208/00203

  Coils · CPC title

• Y02P20/124

  Cross-Sectional Technologies · mapped topic

• B01J8/0055

  using cyclones · CPC title