Process for degassing condensed sulfur from a Claus sulfur recovery system

Patent metadata

Field	Value
Publication number	US-9758376-B2
Application number	US-201514845744-A
Country	US
Kind code	B2
Filing date	Sep 4, 2015
Priority date	Jun 21, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

A process of producing degassed liquid sulfur using process gas containing H 2 S to agitate the liquid sulfur being degassed while in contact with a degassing catalyst. Process gas is less costly and less complicated and quickly accomplishes substantial degassing rendering the liquid sulfur much safer in storage and transportation.

First claim

The invention claimed is:

1. A process for producing liquid sulfur that is degassed of H 2 S, wherein the process comprises:
a) providing a sulfur degassing catalyst and liquid sulfur into a vessel wherein the sulfur degassing catalyst and liquid sulfur define a contact zone;
b) directing condensed products from a Claus plant into the contact zone of the vessel wherein the condensed products include elemental sulfur, dissolved H 2 S and H 2 S x where x≧2;
c) catalyzing the conversion of H 2 S x on the surface of the sulfur degassing catalyst to form H 2 S and elemental sulfur;
d) directing a process gas from the Claus plant and increasing the pressure of the process gas and directing the elevated pressure process gas into the contact zone of the vessel to agitate the sulfur degassing catalyst and liquid sulfur and carry H 2 S that has formed on the surface of the sulfur degassing catalyst away from the sulfur degassing catalyst; wherein the process gas includes H 2 S;
e) exhausting the processes gases along with H 2 S from the contact zone back to the Claus plant for further processing in the Claus plant; and
f) extracting liquid sulfur that is degassed of H 2 S from the contact zone.

2. The process according to claim 1 , wherein the step of providing a sulfur degassing catalyst comprises providing a plurality of high surface area alumina particles constrained to prevent being removed or carried away from the contact zone.

3. The process according to claim 2 , wherein the step of providing a sulfur degassing catalyst further comprises providing a plurality of high surface area alumina particles impregnated with iron oxide.

4. The process according to claim 1 , wherein the step of providing a sulfur degassing catalyst comprises providing one or more low surface area alumina porous ceramic foam supports coated with high surface alumina particles.

5. The process according to claim 4 , wherein the step of providing a sulfur degassing catalyst further comprises providing one or more low surface area alumina porous ceramic foam supports coated with high surface alumina particles that is impregnated with iron oxide.

6. The process according to claim 1 , wherein the process gas directed into the contact zone includes at least 0.5% H 2 S by volume.

7. The process according to claim 1 further including a step of blending process gas drawn from an intermediate step of the Claus plant with the elevated pressure process gas prior to being directed into the contact zone.

8. The process according to claim 1 , the Claus process includes at least three condensers, but only the liquid sulfur from the first two condensers is subject to degassing in the contact zone.

9. The process according to claim 1 further including converting H 2 S to elemental sulfur by reacting on the surface of the catalyst with SO 2 in the process gas by the following reaction: 2H 2 S+SO 2 3/xS x +2H 2 O.

10. A process for producing liquid sulfur that is degassed of H 2 S, wherein the process comprises:
a) providing a Claus plant for desulfurizing H 2 S containing gases, wherein the Claus plant includes a number of components including a burner for converting some H 2 S to SO 2 along with elevated pressure process gas, a reaction furnace for converting at least some H 2 S and SO 2 to elemental sulfur, a first condenser for condensing the sulfur from the process gas exiting the reaction furnace, at least one additional catalytic reactor for converting a portion of the H 2 S in the process gas from the first condenser to elemental sulfur, a second condenser for condensing the sulfur in the gases exiting the one additional catalytic reactor;
b) providing a sulfur degassing catalyst and liquid sulfur into a vessel wherein the sulfur degassing catalyst and liquid sulfur define a contact zone;
c) directing condensed products from at least one condenser of the Claus plant to the vessel, wherein the condensed products include elemental sulfur, dissolved H 2 S and H 2 S x where x≧2;
d) catalyzing the conversion of H 2 S x on the surface of the sulfur degassing catalyst in the contact zone to form H 2 S and elemental sulfur;
e) directing process gas from the Claus plant and increasing the pressure of the process gas and directing the elevated pressure process gas into the contact zone of the vessel to agitate the sulfur degassing catalyst and liquid sulfur and carry H 2 S that has formed on the surface of the sulfur degassing catalyst away from the sulfur degassing catalyst; wherein the process gas includes H 2 S;
f) exhausting the processes gas along with H 2 S from the contact zone back to the Claus plant for further processing in the Claus plant; and
g) extracting liquid sulfur that is degassed of H 2 S from the contact zone.

11. The process according to claim 10 , wherein the step of providing a sulfur degassing catalyst comprises providing a plurality of high surface area alumina particles constrained to prevent being removed or carried away from the contact zone.

12. The process according to claim 11 , wherein the step of providing a sulfur degassing catalyst further comprises providing a plurality of high surface area alumina particles impregnated with iron oxide.

13. The process according to claim 10 , wherein the step of providing a sulfur degassing catalyst comprises providing one or more low surface area alumina porous ceramic foam supports coated with high surface alumina particles.

14. The process according to claim 13 , wherein the step of providing a sulfur degassing catalyst further comprises providing one or more low surface area alumina porous ceramic foam supports coated with high surface alumina particles that is impregnated with iron oxide.

15. The process according to claim 10 , wherein the process gas directed into the contact zone includes at least 0.5% H 2 S by volume.

16. The process according to claim 10 further including a step of blending process gas drawn from an intermediate step of the Claus plant with the elevated pressure process gas prior to being directed into the contact zone.

17. The process according to claim 10 , the Claus process includes at least three condensers, but only the liquid sulfur from the first two condensers is subjected to degassing in the contact zone.

18. The process according to claim 10 further including converting H 2 S to elemental sulfur by reacting on the surface of the catalyst with SO 2 in the process gas by the following reaction: 2H 2 S+SO 2 3/x S x +2H 2 O.

Assignees

• Phillips 66 Co

Inventors

• Keller Alfred E

Classifications

• B01D5/0051

  Regulation processes; Control systems, e.g. valves · CPC title

• C01B17/0456 Primary

  the hydrogen sulfide-containing gas being a Claus process tail gas · CPC title

• B01D19/0052

  in rotating vessels, vessels containing movable parts or in which centrifugal movement is caused (B01D19/0026 takes precedence) · CPC title

• B01D5/0012

  Vertical tubes · CPC title

• C01B17/0447

  Separation of the obtained sulfur · CPC title