Catalyst for the oxidation of CO and HC at low temperatures

Patent metadata

Field	Value
Publication number	US-9757712-B2
Application number	US-201415029853-A
Country	US
Kind code	B2
Filing date	Oct 22, 2014
Priority date	Oct 22, 2013
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The present invention relates to a catalyst for the removal of carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines on a supporting body, which bears platinum and/or palladium on one or more refractory carrier materials and also contains cerium oxide and which, after reductive treatment at 250° C. and after CO adsorption, is characterized by certain peaks in Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), and also relates to the use thereof for removing carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines.

First claim

The invention claimed is:

1. A catalyst for removing carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines on a supporting body, comprising
(i) platinum, or platinum and palladium, on one or more refractory carrier material; and
(ii) cerium oxide present in an amount of 50 to 150 g/L relative to the volume of the supporting body,
wherein, after reductive treatment at 250° C. and after CO adsorption, the catalyst shows peaks at wavenumbers 2906 cm −1 (5 cm −1 ), 2879 cm −1 (±5 cm −1 ), and 2847 cm −1 (±5 cm −1 ) in Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS), and
wherein a ratio of peak heights at wavenumber 2879 cm −1 to wavenumber 2906 cm −1 is greater than 0.4, and a ratio of peak heights at wavenumber 2847 cm −1 to wavenumber 2906 cm −1 is also greater than 0.4.

2. The catalyst according to claim 1 , wherein the quantity of platinum, or platinum and palladium, is 0.5 to 10% by weight relative to component (i).

3. The catalyst according to claim 1 , wherein the quantity of platinum, or platinum and palladium, is 1 to 5% by weight relative to component (i).

4. The catalyst according to claim 1 , wherein the catalyst comprises platinum and palladium, and the weight ratio of Pt:Pd is 1:1 to 20:1.

5. The catalyst according to claim 1 , wherein aluminum oxide, silicon oxide, magnesium oxide, titanium oxide, cerium oxide, zeolite, or mixtures or mixed oxides thereof are used as refractory carrier materials of component (i).

6. A method for removing carbon monoxide and hydrocarbon from the exhaust gas of lean-operated internal combustion engines, comprising passing the exhaust gas over a catalyst according to claim 1 .

Assignees

• Umicore Ag & Co Kg

Inventors

• Hoyer Ruediger
• Wen Fei
• Mueller Elena

Classifications

• B01J2523/31

  Aluminium · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• B01J23/44 Primary

  Palladium · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J2523/824

  Palladium · CPC title