Enhanced Q high dielectric constant material for microwave applications

Patent metadata

Field	Value
Publication number	US-9755293-B2
Application number	US-201414561182-A
Country	US
Kind code	B2
Filing date	Dec 4, 2014
Priority date	Dec 5, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

Enhanced Q high dielectric constant material for microwave applications. In some embodiments, a composition can include a material with a formula Ba 4+x Sm (2/3)(14−x+0.5y) Ti 18−y Al y O 54 , with the quantity y being in a range 0<y<2, and the quantity x being in a range 0<x<2−y. Such a material can have a dielectric constant value greater than 60 and a Qf value greater than 10,000 at a frequency (f) at or less than 1 GHz. In some embodiments, a material having such properties can be implemented as a ceramic device and be utilized as a dielectric microwave resonator. Such a microwave resonator can be utilized as, for example, a narrowband radio-frequency (RF) filter.

First claim

What is claimed is:

1. A composition comprising a material with a formula Ba 4+x Sm (2/3)(14−x+0.5y) Ti 18−y Al y O 54 , the quantity y being in a range 0<y<2, the quantity x being in a range 0<x<2−y.

2. The composition of claim 1 wherein the quantity x is in a range 0<x<1−0.5y corresponding to barium content being in a range of 0% to 50%.

3. The composition of claim 1 wherein the quantity y is approximately 0.5 and the quantity x is in a range from approximately 0.01 to approximately 1.0.

4. The composition of claim 1 wherein the quantity y is approximately 1.0 and the quantity x is in a range from approximately 0.01 to approximately 0.5.

5. The composition of claim 1 wherein the quantity y is approximately 1.4 and the quantity x is in a range from approximately 0.01 to approximately 0.3.

6. The composition of claim 1 wherein at least some of the Sm is substituted by another lanthanide.

7. The composition of claim 6 wherein the other lanthanide includes La, Ce, Pr, Nd or Gd.

8. The composition of claim 6 wherein the other lanthanide substitutes up to approximately 50 atomic percent of the Sm.

9. The composition of claim 8 wherein the other lanthanide is La or Nd.

10. The composition of claim 1 wherein at least some of the Ba is substituted by Sr.

11. The composition of claim 1 further comprising a minor additive including manganese oxide, manganese carbonate, cerium oxide, copper oxide, germanium oxide, silica or gallium oxide.

12. The composition of claim 1 further comprising a high Q second phase material.

13. A dielectric resonator comprising a ceramic device configured as a microwave resonator, the ceramic device including a material with a formula Ba 4+x Sm (2/3)(14−x+0.5y) Ti 18−y Al y O 54 , the quantity y being in a range 0<y<2, the quantity x being in a range 0<x<2−y.

14. The dielectric resonator of claim 13 wherein the material has a dielectric constant value that is greater than 60 for frequencies less than or equal to 1 GHz.

15. The dielectric resonator of claim 14 wherein the dielectric constant value is in a frequency range that is greater than or equal to 700 MHz and less than or equal to 1 GHz.

16. The dielectric resonator of claim 14 wherein the material has a Qf value that is greater than 10,000, the quantity Q being a quality factor, the quantity f being a frequency expressed in GHz.

17. A method for fabricating a tungsten bronze material, the method comprising:
in a material having rhombic (A1) sites, pentagonal (A2) sites, and titanium (Ti) in octahedral sites, substituting aluminum (Al) for at least some of the titanium (Ti) in the respective octahedral sites to provide a dielectric constant value greater than 60 and a Qf value greater than 10,000 at a frequency (f), with the quantity Q being a quality factor, and the quantity f being a frequency expressed in GHz and less than 1 GHz; and
adjusting contents of the A1 sites and the A2 sites to compensate for charge imbalance resulting from the aluminum substitution of titanium.

18. The method of claim 17 wherein the tungsten bronze material is represented by a formula [A2] 4 [A1] 10 Ti 18−y Al y O 54 .

19. The method of claim 18 wherein substantially all of the A2 sites are occupied by barium (Ba) and at least some of the A1 sites are occupied by samarium (Sm), such that the adjusting includes adding x formula unit of Ba and (⅔)x formula unit of Sm to the A1 sites.

20. The method of claim 19 further comprising substituting at least some of the samarium with another lanthanide (Ln) to provide a temperature coefficient of resonant frequency (τ f ) that is less negative.

Assignees

• Skyworks Solutions Inc

Inventors

• Hill Michael David

Classifications

• C04B2235/3213

  Strontium oxides or oxide-forming salts thereof · CPC title

• C04B35/468

  based on barium titanates · CPC title

• C04B2235/76

  Crystal structural characteristics, e.g. symmetry · CPC title

• C04B2235/3224

  Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide · CPC title

• C04B2235/3227

  Lanthanum oxide or oxide-forming salts thereof · CPC title