Electrode active material, electrode including the same, and lithium battery including the electrode

Patent metadata

Field	Value
Publication number	US-9755230-B2
Application number	US-201414467338-A
Country	US
Kind code	B2
Filing date	Aug 25, 2014
Priority date	Aug 30, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

An electrode active material including an ordered mesoporous metal oxide; and at least one conductive carbon material disposed in a pore of the ordered mesoporous metal oxide. Also, an electrode including the electrode active material, and a lithium battery including the electrode.

First claim

What is claimed is:

1. An electrode active material, comprising:
an ordered mesoporous metal oxide; and
at least one conductive carbon material disposed in a pore of the mesoporous metal oxide,
wherein the ordered mesoporous metal oxide is a manganese oxide represented by Formula 1:
Mn x O y   Formula 1

wherein 1≦x≦3, 1≦y≦4, 2≦x+y≦7, and 0<y/x<2.

2. The electrode active material of claim 1 , wherein the ordered mesoporous metal oxide comprises pores having pore diameters within about ±30% of each other.

3. The electrode active material of claim 1 , wherein the conductive carbon material consists of carbon.

4. The electrode active material of claim 3 , wherein the conductive carbon material is at least one of graphene, carbon nanotube, carbon black, graphite nanofiber, fullerene, and graphite.

5. The electrode active material of claim 1 , wherein the conductive carbon material is embedded in the ordered mesoporous metal oxide, and wherein the conductive carbon material penetrates through the ordered mesoporous metal oxide.

6. The electrode active material of claim 1 , wherein pores of the ordered mesoporous metal oxide are connected to each other to form a channel.

7. The electrode active material of claim 1 , wherein the ordered mesoporous metal oxide comprises at least one of Mn 3 O 4 and MnO 2 .

8. The electrode active material of claim 1 , wherein the amount of the conductive carbon material is in a range of about 1 parts by weight to about 10 parts by weight, based on 100 parts by weight of the electrode active material.

9. The electrode active material of claim 1 wherein the ordered mesoporous metal oxide is an ordered mesoporous manganese oxide,
wherein the conductive carbon material is a carbon nanotube or graphene, and
wherein the carbon nanotube or graphene is embedded in the ordered mesoporous manganese oxide.

10. The electrode active material of claim 1 , wherein an average diameter of mesopores of the ordered mesoporous metal oxide is in a range of about 1 nanometer to about 50 nanometers.

11. The electrode active material of claim 1 , wherein, in an X-ray diffraction pattern of the electrode active material, a peak with respect to a (210) plane appears at a Bragg (2θ) angle in a range of about 0.5° to about 1.5°, when using Cu K-alpha radiation.

12. The electrode active material of claim 1 , wherein a specific surface area of the electrode active material is in a range of about 50 m 2 /g to about 250 m 2 /g, and
wherein a volume of mesopores of the mesoporous metal oxide is in a range of about 0.1 cm 3 /g to about 2 cm 3 /g.

13. The electrode active material of claim 1 , wherein, when the electrode active material is analyzed by nitrogen adsorption analysis, a double hysteresis is not observed.

14. An electrode comprising the electrode active material of claim 1 .

15. A lithium battery comprising the electrode of claim 12 .

16. The lithium battery of claim 15 , wherein the electrode is a negative electrode.

17. An electrode active material, comprising:
an ordered mesoporous metal oxide; and
at least one conductive carbon material disposed in a pore of the mesoporous metal oxide,
wherein the ordered mesoporous metal oxide is an ordered mesoporous manganese oxide.

18. The electrode active material of claim 17 , wherein the conductive carbon material is at least one of a carbon nanotube or graphene.

19. The electrode active material of claim 18 , wherein the carbon nanotube or graphene is embedded in the ordered mesoporous manganese oxide.

20. An electrode comprising the electrode active material of claim 17 .

21. A lithium battery comprising the electrode of claim 20 .

Assignees

• Samsung Electronics Co Ltd

Inventors

• Shon Jeongkuk
• Choi Jaeman
• Ku Junhwan
• Kwon Kuntae
• Kwon Moonseok
• Song Minsang
• Hwang Seungsik
• Kim Jiman
• Park Gwiok

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/366

  as layered products · CPC title