Small pore size nonwoven mat with hydrophilic/acid resistant filler used in lead acid batteries and applications therefor

Patent metadata

Field	Value
Publication number	US-9755205-B2
Application number	US-201514642361-A
Country	US
Kind code	B2
Filing date	Mar 9, 2015
Priority date	Mar 9, 2015
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

According to one embodiment, a nonwoven fiber mat includes between 10% and 50% by weight of a plurality of first glass fibers having an average diameter of less than 5 μm and between 50% and 90% by weight of a plurality of second glass fibers having an average diameter of greater than 6 μm. The nonwoven fiber mat also includes an acid resistant binder that binds the first and second glass fibers together. The nonwoven fiber mat has an average pore size of between 1 and 100 μm and exhibits an air permeability of below 100 cubic feet per minute per square foot (cfm/ft 2 ) as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737.

First claim

What is claimed is:

1. A nonwoven fiber reinforcement mat configured for reinforcing an electrode or supporting a separator of a lead-acid battery comprising:
a plurality of first glass fibers having an average diameter of less than 5 μm;
a plurality of second glass fibers having an average diameter of greater than 6 μm; and
an acid resistant binder composition that binds the plurality of first glass fibers and second glass fibers together, wherein:
the nonwoven fiber reinforcement mat includes between about 10% and about 50% by weight of the plurality of first glass fibers and between about 50% and 90% by weight of the plurality of second glass fibers; and
the nonwoven fiber reinforcement mat has an average pore size of between 1 μm and 100 μm and exhibits an air permeability of below 100 cubic feet per minute per square foot (cfm/ft 2 ) as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737;
wherein the nonwoven fiber reinforcement mat has a Cobb 60 degree that is less than about 1.

2. The nonwoven fiber reinforcement mat of claim 1 , wherein the nonwoven fiber reinforcement mat has an average pore size of between 1 and 10 μm.

3. The nonwoven fiber reinforcement mat of claim 1 , wherein the nonwoven fiber reinforcement mat exhibits an air permeability of below 10 cfm/ft 2 as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737.

4. The nonwoven fiber reinforcement mat of claim 3 , wherein the nonwoven fiber reinforcement mat exhibits an air permeability of below 1 cfm/ft 2 as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737.

5. The nonwoven fiber reinforcement mat of claim 1 , wherein the nonwoven fiber reinforcement mat includes between 0.1% and about 20% by weight of a powder or granular filler, wherein the powder or granular filler is hydrophilic and acid resistant and has a surface area of greater than 10 m 2 /g such that the powder or granular filler decreases the pore size and air permeability of the nonwoven fiber reinforcement mat.

6. The nonwoven fiber reinforcement mat of claim 5 , wherein the powder or granular filler comprises synthetic precipitated silica.

7. The nonwoven fiber reinforcement mat of claim 1 , wherein the plurality of first glass fibers have an average fiber diameter of about 0.7 μm.

8. The nonwoven fiber reinforcement mat of claim 1 , wherein nonwoven fiber reinforcement mat exhibits:
an average wick height of between about 1 cm and about 5 cm after exposure to sulfuric acid having 40 wt. % H2SO4 or a specific gravity of 1.28 for 10 minutes conducted according to method ISO8787, and
a total normalized tensile strength of greater than 4 lbf/in.

9. A lead-acid battery comprising:
a positive electrode;
a negative electrode; and
a nonwoven fiber reinforcement mat configured for reinforcing the positive or negative electrode or supporting a separator, the nonwoven fiber reinforcement mat including:
a plurality of first glass fibers having an average fiber diameter of less than 5 μm;
a plurality of second glass fibers having an average fiber diameter of greater than 6 μm; and
an acid resistant binder composition that binds the plurality of first glass fibers and second glass fibers together, wherein:
the nonwoven fiber reinforcement mat includes between about 10% and about 50% by weight of the plurality of first glass fibers and between about 50% and 90% by weight of the plurality of second glass fibers; and
the nonwoven fiber reinforcement mat has an average pore size of between 1 μm and 100 μm and exhibits an air permeability of below 100 cubic feet per minute per square foot (cfm/ft 2 ) as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737;
wherein the nonwoven fiber reinforcement mat has a Cobb 60 degree that is less than or equal to the weight of the nonwoven fiber reinforcement mat.

10. The lead acid battery of claim 9 , wherein the nonwoven fiber reinforcement mat has an average pore size of between 1 and 10 μm.

11. The lead acid battery of claim 9 , wherein the nonwoven fiber reinforcement mat exhibits an air permeability of below 10 cfm/ft 2 as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737.

12. The lead acid battery of claim 11 , wherein the nonwoven fiber reinforcement mat exhibits an air permeability of below 1 cfm/ft 2 as measured by the Frazier test at 125 Pa according to ASTM Standard Method D737.

13. The lead acid battery of claim 9 , wherein the nonwoven fiber reinforcement mat includes between 0.1% and about 20% by weight of a powder or granular filler, wherein the powder or granular filler is hydrophilic and acid resistant and has a surface area of greater than 10 m 2 /g such that the powder or granular filler decreases the pore size and air permeability of the nonwoven fiber reinforcement mat.

14. The lead acid battery of claim 13 , wherein the powder or granular filler comprises synthetic precipitated silica.

15. The lead acid battery of claim 9 , wherein nonwoven fiber reinforcement mat exhibits:
an average wick height of between about 1 cm and about 5 cm after exposure to sulfuric acid having 40 wt. % H2SO4 or a specific gravity of 1.28 for 10 minutes conducted according to method ISO8787, and
a tensile strength of greater than 4 lbf/in.

Assignees

• Johns Manville

Inventors

• Guo Zhihua
• Sharma Gautam
• Nandi Souvik
• Asrar Jawed
• Dietz Iii Albert G

Classifications

• H01M10/06 Primary

  Lead-acid accumulators (semi-lead accumulators H01M10/20) · CPC title

• H01M50/437

  Glass · CPC title

• H01M2/1613 Primary

  Electricity · mapped topic

• H01M2/145

  Electricity · mapped topic

• H01M2/1646

  Electricity · mapped topic