Luminescent converter for a phosphor-enhanced light source

Patent metadata

Field	Value
Publication number	US-9754776-B2
Application number	US-201013262873-A
Country	US
Kind code	B2
Filing date	Mar 31, 2010
Priority date	Apr 6, 2009
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The invention relates to a luminescent converter ( 10, 12 ) for a phosphor-enhanced light source ( 100, 102, 104 ). The luminescent converter comprises a first luminescent material ( 20 ) configured for absorbing at least a part of excitation light (hv 0 ) emitted by a light emitter ( 40, 42 ) of the phosphor-enhanced light source, and for converting at least a part of the absorbed excitation light into first emission light (hv 1 ) comprising a longer wavelength compared to the excitation light. The luminescent converter further comprising a second luminescent material ( 30 ) comprising organic luminescent material ( 30 ) and configured for absorbing at least a part of the first emission light emitted by the first luminescent material, and for converting at least a part of the absorbed first emission light into second emission light (hv 2 ) having a longer wavelength compared to the first emission light.
An effect of the luminescent converter according to the invention is that the two-step light conversion according to the invention generates a relatively small Stokes shift of the light emitted by the organic luminescent material. The inventors have found that by reducing the Stokes shift of the organic luminescent material, the width of the spectrum of the second emission light is limited to reduce an infrared part in the emission spectrum. As such, the efficiency is improved.

First claim

The invention claimed is:

1. A luminescent converter for a phosphor-enhanced light source, the luminescent converter comprising:
a first luminescent material configured for absorbing at least a part of excitation light emitted by a light emitter of the phosphor-enhanced light source, and for converting at least a part of the absorbed excitation light into first emission light comprising a longer wavelength compared to the excitation light, and
a second luminescent material comprising organic luminescent material that is configured for absorbing at least a part of the first emission light emitted by the first luminescent material, and for converting at least a part of the absorbed first emission light into second emission light having a longer wavelength compared to the first emission light, wherein the wavelength difference between the first emission light and the second emission light is less than 100 nanometers, wherein the first luminescent material and the second luminescent material constitute layers of luminescent material in a stack of luminescent materials.

2. Luminescent converter as claimed in claim 1 , wherein the first luminescent material comprises an inorganic luminescent material.

3. Luminescent converter as claimed in claim 1 , wherein a protective layer is applied on the second luminescent material for protecting the second luminescent material.

4. Luminescent converter as claimed in claim 1 , wherein the luminescent converter comprises a mixture of luminescent materials, the mixture of luminescent materials comprising both the first luminescent material and the second luminescent material.

5. Luminescent converter as claimed in claim 1 , wherein the luminescent converter is located at a distance from the light emitter constituting a remote phosphor arrangement.

6. Luminescent converter as claimed in claim 1 , wherein the second luminescent material comprises:
perylene derivatives comprising Lumogen F materials comprising 083 emitting Yellow light, 170 emitting Yellow light, 240 emitting Orange light, 305 emitting Red light, 850 emitting Green light, difluoro-boraindacene derivatives, Fluorescein dyes, fluerene derivatives, coumarin dyes, xanthene dyes, pyrromethene-BF2 complexes, Stilbene derivatives, Rodamine dyes, perylene carboximide dyes, or luminescent polymers comprising polyphenylenevinilene or polyphenyl derivatives.

7. Phosphor-enhanced light source comprising a light emitter emitting excitation light and comprising the luminescent converter according to claim 1 .

8. Phosphor-enhanced light source as claimed in claim 7 , wherein the light emitter comprises a solid-state light emitter.

9. Phosphor-enhanced light source as claimed in claim 7 , wherein the light emitter comprises a discharge in a discharge lamp.

10. Phosphor-enhanced light source as claimed in claim 6 , wherein the light emitter is configured for emitting excitation light comprising the primary color Blue.

11. Phosphor-enhanced light source as claimed in claim 9 , the discharge lamp comprising a discharge vessel enclosing, in a gastight manner, a discharge space comprising a gas filling and comprising discharge means for maintaining a discharge in the discharge space, in operation, for emitting the excitation light, wherein the second luminescent material is applied at a side of a wall of the discharge vessel facing away from the discharge.

12. Phosphor-enhanced light source as claimed in claim 9 , the discharge lamp comprising a discharge vessel enclosing, in a gastight manner, a discharge space comprising a gas filling and comprising discharge means for maintaining a discharge in the discharge space, in operation, for emitting the excitation light, the discharge lamp further comprising an outer bulb surrounding the discharge vessel, wherein the second luminescent material is arranged on a wall of the outer bulb.

13. Phosphor-enhanced light source as claimed in claim 12 , wherein the second luminescent material is arranged on a side of the wall of the outer bulb facing the discharge vessel.

14. A luminescent converter for a phosphor-enhanced light source, the luminescent converter comprising:
a first luminescent material configured for absorbing at least a part of excitation light emitted by a light emitter of the phosphor-enhanced light source, and for converting at least a part of the absorbed excitation light into first emission light comprising a longer wavelength compared to the excitation light, and
a second luminescent material comprising organic luminescent material that is configured for absorbing at least a part of the first emission light emitted by the first luminescent material, and for converting at least a part of the absorbed first emission light into second emission light having a longer wavelength compared to the first emission light, wherein the wavelength difference between the first emission light and the second emission light is less than 100 nanometers,
wherein a Stokes shift of said organic luminescent material for said converting of the at least a part of the absorbed first emission light is less than 100 nm.

15. Luminescent converter as claimed in claim 14 , wherein the second emission light is red light.

16. A luminescent converter for a phosphor-enhanced light source, the luminescent converter comprising a first luminescent material configured for absorbing at least a part of excitation light emitted by a light emitter of the phosphor-enhanced light source, and for converting at least a part of the absorbed excitation light into first emission light comprising a longer wavelength compared to the excitation light, and a second luminescent material comprising organic luminescent material that is configured for absorbing at least a part of the first emission light emitted by the first luminescent material, and for converting at least a part of the absorbed first emission light into second emission light having a longer wavelength compared to the first emission light, wherein the wavelength difference between the first emission light and the second emission light is less than 100 nanometers, wherein the second emission light is red light.

Assignees

• Staats Cornelia Titia
• Van Dijk Gerardus Arnoldus Rita
• Wegh Rene Theodorus
• Van De Spijker Willibrordus Hubertus Martinus Maria
• Peeters Martinus Petrus Joseph
• Philips Lighting Holding Bv

Inventors

• Staats Cornelia Titia
• Van Dijk Gerardus Arnoldus Rita
• Wegh Rene Theodorus
• Van De Spijker Willibrordus Hubertus Martinus Maria
• Peeters Martinus Petrus Joseph

Classifications

• H01J61/48

  Separate coatings of different luminous materials · CPC title

• H01J61/44 Primary

  Devices characterised by the luminescent material · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• C09K11/77748

  Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides · CPC title

• H01L33/504

  Electricity · mapped topic