SOx concentration detection device

Patent metadata

Field	Value
Publication number	US-9753005-B2
Application number	US-201314760528-A
Country	US
Kind code	B2
Filing date	Dec 26, 2013
Priority date	Jan 15, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

To provide an SOx concentration detection device that can detect the SOx concentration in exhaust gas without using a dedicated sensor. As shown in FIG. 4 , the current value that flows when a voltage in the limiting current region is applied stays at a constant value (limiting current value) regardless of the elapsed time. On the other hand, the current value that flows when a voltage in the overcurrent region is applied decreases with the lapse of time and approaches the limiting current value 30 seconds after the start of application of the voltage. In this embodiment, the current value difference is defined as “SO 2 reduction current,” and the SO 2 concentration around the sensor is detected from an integrated value of the SO 2 reduction current.

First claim

The invention claimed is:

1. An SOx concentration detection device comprising:
an electronic control unit electrically connected, on an input side, to a plurality of engine control sensors and electrically connected, on an output side, to a plurality of actuators, the electronic control unit for executing predetermined programs based on input information from the plurality of engine control sensors; and
a limiting current-type sensor including a solid electrolyte and a pair of electrodes, the solid electrolyte having oxide ion conductivity, and the pair of electrodes being provided on opposite sides of the solid electrolyte,
the limiting current-type sensor configured to generate a limiting current corresponding to a concentration of a specific component in exhaust gas from an internal combustion engine when a predetermined voltage is applied between the pair of electrodes;
the electronic control unit programmed to:
apply a reference voltage and an SOx detecting voltage between the pair of electrode when an exhaust gas air-fuel ratio of the internal combustion engine is on rich side of stoichiometry, the reference voltage being a voltage in a limiting current region that includes the predetermined voltage, and the SOx detecting voltage being a voltage in a voltage region higher than the limiting current region,
acquire an SOx detecting output that is output from the limiting current-type sensor when the SOx detecting voltage is applied, and acquire a reference output that is output from the limiting current-type sensor when the reference voltage is applied, and
detect a SOx concentration in the exhaust gas from the internal combustion engine using histories of the SOx detecting output and the reference output that are generated before an output difference between the SOx detecting output and the reference output falls to or below a set value.

2. The SOx concentration detection device according to claim 1 ,
wherein the pair of electrodes include a detection electrode,
the detection electrode is provided on an exhaust gas contacting surface of the solid electrolyte, and
the detection electrode contains 0.1 to 5.0 wt % of at least one metal that is selected from a group that consists of alkaline-earth metals and rare-earth metals.

3. The SOx concentration detection device according to claim 1 ,
wherein the electronic control unit is further programmed to control the exhaust gas air-fuel ratio to the richer side of stoichiometry and heat the sensor to a predetermined temperature at which sulfur components that have been adsorbed on the pair of electrodes can be desorbed when the output difference falls to or below the set value.

Assignees

• Toyota Motor Co Ltd

Inventors

• Kato Tetsuya
• Teranishi Shinya
• Aoki Keiichiro
• Wakao Kazuhiro

Classifications

• G01N33/0042

  SO2 or SO3 · CPC title

• G01N27/4074 Primary

  for detection of gases other than oxygen · CPC title

• Y02A50/20

  Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters · CPC title