Corrosion inhibitors

Patent metadata

Field	Value
Publication number	US-9752236-B2
Application number	US-201113992674-A
Country	US
Kind code	B2
Filing date	Dec 8, 2011
Priority date	Dec 8, 2010
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention provides the use of a sulfosuccinate as a corrosion inhibitor. In particular, the sulfosuccinate may be used to inhibit the corrosion of a metal component that is, or will be, in contact with an aqueous fluid, in order to prevent or reduce corrosion of the metal component. The sulfosuccinate may be used to inhibit corrosion of a metal component in an industrial aqueous system, such as a hydrocarbon plant; a chemical plant; a water plant; or a paper manufacturing plant, and in particular in an oilfield system or a downstream oil-related system.

First claim

The invention claimed is:

1. A method of preventing or reducing corrosion of a metal component that is in contact with, or will be in contact with, an aqueous fluid, wherein the method comprises:
applying a sulfosuccinate to a metal component or adding the sulfosuccinate to an aqueous fluid that is in contact with, or will be in contact with, the metal component
wherein the sulfosuccinate is a reaction product of maleic anhydride and a compound selected from the group consisting of: a fatty alkanolamide, a fatty alkoxylated alkanolamide, a fatty alcohol, a fatty alkoxylated alcohol, an alkoxylated terpene group, and an alkyl polyglucoside, followed by reaction with a bisulfite;
wherein the fatty group of the compound is a C8-30 unbranched alkyl or alkenyl group.

2. The method of claim 1 wherein the sulfosuccinate is of formula (I) or formula (II):

wherein
M is a monovalent or divalent cation; and
R is:
(i) a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group; or
(ii-a) R′—(O—C 2 H 4 ) x —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group or a C8-C30 terpene group, and x is an integer from 1 to 50; or
(ii-b) R′—(O—C 3 H 6 ) x —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group or a C8-C30 terpene group, and x is an integer from 1 to 50; or
(ii-c) R′—(O—C 4 H 8 ) x —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group or a C8-C30 terpene group, and x is an integer from 1 to 50; or
(ii-d) R′—(O—C y H 2y ) x′ (O—C 2 H 4 ) x″ —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group or a C8-C30 terpene group, y is 3 or 4, x′ is an integer from 1 to 50, and x″ is an integer from 1 to 50; or
(ii-e) R′—(O—C 2 H 4 ) x″ (O—C y H 2y ) x ′—, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group or a C8-C30 terpene group, y is 3 or 4, x′ is an integer from 1 to 50, and x″ is an integer from 1 to 50; or
(iii) R′—(═O)—NH—R a —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group, and R a is a C1-C6 alkyl or C2-C6 alkoxyalkyl, or
(iv) R′—(O—CH 2 —CH 2 ) x —C(═O)—NH—R a —, where R′ is a hydrocarbon group which is a C8-30 unbranched alkyl or alkenyl group, and R a is a C1-C6 alkyl or C2-C6 alkoxyalkyl, and x is an integer from 1 to 50;
or the (or each) sulfosuccinate is made up of units of formula (III) and/or (IV):

wherein
R is a C8 to 30 alkyl group;
R 1 , R 2 , R 3 and R 4 are independently selected from the group consisting of hydrogen and —CH 2 CH(OH)CH 2 —R 12 , with the proviso that R 1 , R 2 , R 3 and R 4 are not all hydrogen;
R 5 , R 6 , R 7 R 8 , R 9 and R 11 are independently selected from the group consisting of hydrogen and —CH 2 CH(OH)CH 2 —R 12 ,
and R 10 is selected from the group consisting of hydrogen, —CH 2 CH(OH)CH 2 —R 12 , and

with the proviso that R 5 , R 6 , R 7 R 8 , R 9 , R 10 and R 11 are not all hydrogen,
R 12 is

and M is a monovalent or divalent cation, and wherein the overall degree of polymerisation of the sulfosuccinate product is from 1 to 10.

3. The method of claim 2 , wherein the sulfosuccinate is of formula (I) or (II) and wherein x, x′ and x″ are each independently from 1 to 20.

4. The method of claim 2 , wherein the sulfosuccinate is of formula (I) or (II) and wherein R a is ethyl, isopropyl or ethoxyethane.

5. The method of claim 2 , wherein the sulfosuccinate is made up of units of formula (III) and/or (IV) and the degree of polymerisation is from 1 to 5.

6. The method of claim 2 wherein the sulfosuccinate is of formula (I) or (II) and wherein the hydrocarbon group is an unbranched C10 to C22 alkyl or alkenyl group or a C8 to C22 terpene group, or wherein the sulfosuccinate is made up of units of formula (III) and/or (IV) and R is a C12 to C22 alkyl group.

7. The method of claim 2 wherein the cation M is selected from the group consisting of: alkali metal ions, ammonium ions, and alkanolammonium ions.

8. The method of claim 2 wherein the sulfosuccinate is of formula (I).

9. The method of claim 1 wherein the sulfosuccinate has a molecular weight of greater than 700 Da.

10. The method of claim 1 wherein the sulfosuccinate has a molecular weight of from 300 to 1600 Da.

11. The method of claim 1 wherein the sulfosuccinate has an HLB value of from 0 to 7.

12. The method of claim 1 wherein the metal component is in an industrial aqueous system and wherein the metal component contacts the aqueous fluid within the industrial aqueous system.

13. The method of claim 12 wherein the industrial aqueous system is selected from the group consisting of an aqueous system in a hydrocarbon plant; a chemical plant; a water plant; and a paper manufacturing plant.

14. The method of claim 13 wherein the industrial aqueous system is an oilfield system or a downstream oil-related system.

15. The method of claim 14 wherein the industrial aqueous system is an oilfield production system or an oilfield distribution system or an oil refining system.

16. The method of claim 1 wherein the aqueous fluid is acidic.

17. The method of claim 1 wherein the metal component comprises a material selected from the group consisting of: ferrous material, copper, aluminium, and combinations thereof.

18. The method of claim 17 wherein the metal component comprises steel.

19. The method of claim 1 wherein the sulfosuccinate is used together with one or more component selected from the group consisting of: corrosion inhibitors that are not sulfosuccinates; surfactants; solvents; antifoam agents; demulsifiers; scale inhibitors; dispersants and biocides.

20. The method of claim 1 wherein the amount of sulfosuccinate used is from 1 ppm to 1000 ppm.

21. A method of inhibiting corrosion of a metal component of an industrial aqueous system that is in contact with, or will be in contact with, an aqueous fluid, wherein the metal component contacts the aqueous fluid within the industrial aqueous system, the method comprises:
applying a sulfosuccinate to a metal component of an industrial aqueous system or adding the sulfosuccinate to an aqueous fluid that is in contact with, or will be in contact with, the metal component of the industrial aqueous system,
wherein the sulfosuccinate is a reaction product of maleic anhydride and a compound selected from the group consisting of: a fatty alkanolamide, a fatty alkoxylated alkanolamide, a fatty alcohol, a fatty alkoxylated alcohol, an alkoxylated terpene group, and an alkyl polyglucoside, followed by reaction with a bisulfite;
wherein the fatty group of the compound is a C8-30 unbranched alkyl or alkenyl group.

22. The method of claim 21 wherein the industrial aqueous system is selected from the group consisting of an aqueous system in a hydrocarbon plant; a chemical plant; a water plant; and a paper manufacturing plant.

23. The method of claim 22 wherein the industrial aqueous system is an oilfield system or a downstrea

Assignees

• Fellows Alan
• Hatchman Kevan
• Jones Chris
• Rhodia Operations

Inventors

• Fellows Alan
• Hatchman Kevan
• Jones Chris

Classifications

• C23F11/163 Primary

  Sulfonic acids · CPC title

• C09K8/54 Primary

  Compositions for in situ inhibition of corrosion in boreholes or wells · CPC title

• C23F11/04

  in markedly acid liquids · CPC title

• C23F11/10

  using organic inhibitors · CPC title