Transparent UV-curable adhesive

Patent metadata

Field	Value
Publication number	US-9752064-B2
Application number	US-201615368912-A
Country	US
Kind code	B2
Filing date	Dec 5, 2016
Priority date	Dec 10, 2015
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

A transparent ultraviolet curable adhesive is a solventless composition, based on a total weight of the composition, being composed of 35-65 wt % of a polyurethane (meth)acrylate resin, 30-60 wt % of a (meth)acrylate monomer, 0.1-5 wt % of an acrylate group-containing bisphenol fluorene derivative, 0.3-8 wt % of a photopolymerization initiator and 0.002-0.01 wt % of a vinyl silane coupling agent; and, the adhesive if cured has a refractive index of 1.52-1.56 very close to 1.52 for a glass thereof and has a visible light transmittance of 93-99 VLT (%) so suitable to be adhered to displays, transparent conductive film and touch panels.

First claim

What is claimed is:

1. A transparent ultraviolet curable adhesive for use in adhering to an indium tin oxide (ITO) material in a touch panel, being a solventless composition, when cured having a refractive index of 1.49-1.56 as well as having a visible light transmittance of 93-99 VLT (%), and being composed of the following components of (A)-(E), based on a total weight of the composition:
(A) 35-65 wt % of a polyurethane (meth)acrylate resin having a weight-average molecular weight (Mw) of 10,000-50,000;
(B) 30-60 wt % of a (meth)acrylate monomer;
(C) 0.1-5 wt % of an acrylate group-containing bisphenol fluorene derivative which is one or more selected from the group consisting of 9,9-bis[4-(3-acryloxy-2-hydroxypropyloxy)phenyl]fluorene, 9,9-bis[4-(2-acryloxyethoxy)phenyl]fluorine and 9,9-bis[4-(allyloxy)-3-methylphenyl];
(D) 0.3-8 wt % of a photopolymerization initiator; and
(E) 0.002-0.01 wt % of a vinyl silane coupling agent selected from vinyl trimethoxy silane or/and vinyl triethoxy silane;
wherein the (meth)acrylate monomer is one or more selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, butyl (meth)acrylate, isobutyl (meth)acrylate, cyclohexyl (meth)acrylate, octyl (meth)acrylate, isooctyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, isodecyl (meth)acrylate, lauryl (meth)acrylate, isobornyl (meth)acrylate, (meth)acrylamide, (meth)acryloyl morpholine, dimethyl (meth)acrylamide, diethyl (meth)acrylamide and dimethylaminopropyl acrylamide.

2. The transparent ultraviolet curable adhesive of claim 1 , wherein the polyurethane (meth)acrylate resin having a weight-average molecular weight (Mw) of 25,000-35,000 is obtained by reacting a polyol having more than two hydroxyl groups, a polyisocyanate having more than two isocyanate groups and a hydroxyl group-containing (meth)acrylic monomer.

3. The transparent ultraviolet curable adhesive of claim 1 , wherein the (meth)acrylate monomer is composed of 2-ethylhexyl acrylate, dimethyl acrylamide, and isobornyl acrylate, and, based on a weight of the 2-ethylhexyl acrylate, is composed of 2-ethylhexyl acrylate of 100 wt %, dimethyl acrylamide of 50-80 wt % and isobornyl acrylate of 20-50 wt %.

4. The transparent ultraviolet curable adhesive of claim 2 , wherein the polyurethane (meth)acrylate resin is in an amount of 40-60 wt %.

5. The transparent ultraviolet curable adhesive of claim 2 , wherein the (meth)acrylate monomer is in an amount of 40-55 wt %.

6. The transparent ultraviolet curable adhesive of claim 2 , wherein the photopolymerization initiator is in an amount of 1.0-5.0 wt %.

7. The transparent ultraviolet curable adhesive of claim 2 , wherein the vinyl silane coupling agent is in an amount of 0.006-0.01 wt %.

8. The transparent ultraviolet curable adhesive of claim 2 , wherein the vinyl silane coupling agent is in an amount of 0.0075 wt %.

9. The transparent ultraviolet curable adhesive of claim 3 , wherein the dimethyl acrylamide in the (meth)acrylate monomer is no more than 30 wt %, based on the total weight of the composition.

10. The transparent ultraviolet curable adhesive of claim 3 , wherein the adhesive when cured has a refractive index of 1.52-1.56.

11. The transparent ultraviolet curable adhesive of claim 1 , wherein the acrylate group-containing bisphenol fluorene derivative is in an amount of 0.25-2.5 wt %.

12. The transparent ultraviolet curable adhesive of claim 1 , wherein the acrylate group-containing bisphenol fluorene derivative is in an amount of 2.5 wt %.

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Tsao Chun-Che
• Wang Chih-Feng

Classifications

• C08G18/4825 Primary

  Polyethers containing two hydroxy groups (C08G18/4833 - C08G18/5096 take precedence) · CPC title

• C09J151/08 Primary

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08K5/5425

  containing at least one C=C bond · CPC title

• C09J175/16

  having terminal carbon-to-carbon unsaturated bonds · CPC title

• C08G18/4854

  Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group · CPC title