Ethylene/alpha-olefin interpolymer composition

Patent metadata

Field	Value
Publication number	US-9752021-B2
Application number	US-201414762898-A
Country	US
Kind code	B2
Filing date	Mar 13, 2014
Priority date	Mar 28, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The instant invention provides an ethylene/alpha-olefin interpolymer composition suitable for blown film applications, and blown films made therefrom. The ethylene/alpha-olefin interpolymer composition suitable for blown film applications according to the present invention comprises greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.910 to 0.918 g/cm 3 , a melt index I 2 in the range of from 0.5 to 1.1 g/10 minutes, a melt flow ratio I 10 /I 2 in the range of from 8 to 10, a melt strength in the range of from 3 to 6 cN, a highest temperature fraction in the range of from 11 to 14 percent determined by CEF, a highest peak temperature fraction by CEF in range of from 96 to 100° C., and a lowest temperature fraction from CEF in the range of from 2 to 5 percent, and a DSC heat curve having three melting peaks with a highest temperature melting peak in the range of from 120 to 124° C., a crystallinity in the range of from 40 to 50 percent.

First claim

We claim:

1. A blown film comprising an ethylene/alpha-olefin interpolymer composition comprising greater than 80 percent by weight of units derived from ethylene and 20 percent or less by weight of units derived from one or more alpha olefin co-monomers, wherein said ethylene/alpha-olefin interpolymer has a density in the range of from 0.910 to 0.916 g/cm 3 , a melt index I 2 in the range of from 0.5 to 1.1 g/10 minutes, a melt flow ratio I 10 /I 2 in the range of from 8 to 10, a melt strength in the range of from 3 to 6 cN, a highest temperature fraction in the range of from 8 to 15 percent determined by CEF, a highest peak temperature fraction by CEF in the range of from 96 to 100° C., and a lowest temperature fraction from CEF in the range of from 2 to 5 percent, and a DSC heat curve having three melting peaks with a highest temperature melting peak in the range of from 120 to 124° C., and a crystallinity in the range of from 40 to 50 percent.

2. The blown film of claim 1 , wherein said blown film is characterized by having a Total Haze in the range of less than 20%; wherein said film has a 1 mil thickness, and said polyolefin composition further comprises one or more antiblock agents and one or more slip agents, and wherein said film is produced via a blown film process which has at least a 10 percent production rate increase over another ethylene based polymer having one or more properties outside of the required property ranges of the ethylene/alpha-olefin interpolymer composition.

3. The blown film of claim 2 , wherein said another ethylene based polymer composition having a melt index outside of the required melt index range of the ethylene/alpha-olefin interpolymer composition.

4. The blown film of claim 1 , wherein said blown film is characterized by having a Total Haze in the range of less than 20%; wherein said film has a 1 mil thickness and wherein said film is produced via a blown film process which has at least a 10 percent production rate increase over another ethylene based polymer having one or more properties outside of the required property ranges of the ethylene/alpha-olefin interpolymer composition.

5. The blown film of claim 1 comprising the ethylene/alpha-olefin interpolymer composition and one or more LDPEs or one or more LLDPEs.

6. An article comprising one or more layers, wherein at least one of said layers comprises the blown film of claim 1 .

7. The article of claim 6 , wherein the blown film comprises the ethylene/alpha-olefin interpolymer composition and one or more LDPEs or one or more LLDPEs.

8. The blown film of claim 1 , characterized by an oxygen transmission rate in the range of from 600 to 800 cc-mil/100 sq. in-day-atm), measured at 23° C. and 0% relative humidity.

9. The blown film of claim 1 , characterized by a moisture vapor transmission rate in the range of 1.1 to 1.4 gm-mil/100 sq.in-day at 38° C., 100% RH.

10. The blown film of claim 1 , wherein the ethylene/alpha-olefin interpolymer composition has a melt index I 2 in the range of from 0.5 to 0.8 g/10 minutes.

11. The blown film of claim 1 , wherein the ethylene/alpha-olefin interpolymer composition has a molecular weight distribution (Mw/Mn) of 3 to 5.

12. The blown film of claim 1 , wherein the ethylene/alpha-olefin interpolymer composition has a melt flow ratio I 10 /I 2 of 8.2 to 10.

13. The blown film of claim 1 , wherein the ethylene/alpha-olefin interpolymer composition has a melt strength of 4 to 5 cN.

14. The blown film of claim 1 , wherein the ethylene/alpha-olefin interpolymer composition is catalyzed using at least two catalysts and one or more co-catalysts.

15. The blown film of claim 14 , wherein the at least two catalysts comprise a Ziegler-Natta catalyst and a catalyst comprising an s-indacenyl silanaminato complex of titanium.

16. The blown film of claim 15 , wherein the at least two catalysts comprise titanium [N-(1,1-dimethylethyl)-1,1-dimethyl-1-[(1,2,3,3a,8a-η)-1,5,6,7-tetrahydro-2-methyl-s-indacen-1-yl]silanaminato(2-)- K N][(1,2,3,4-η)-1,3-pentadiene] (CAT-B).

17. The blown film of claim 14 , wherein the ethylene/alpha-olefin interpolymer composition is produced by solution phase polymerization using a dual reactor system.

Assignees

• Dow Global Technologies Llc

Inventors

• Demirors Mehmet
• Karjala Teresa P
• Mckenna Julie W
• Ginger Douglas S

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08L2207/066

  LDPE (radical process) · CPC title