Use of heating steam condensate for producing water-absorbent polymer particles

Patent metadata

Field	Value
Publication number	US-9751958-B2
Application number	US-201013498364-A
Country	US
Kind code	B2
Filing date	Oct 5, 2010
Priority date	Oct 9, 2009
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention relates to a process for producing water-absorbing polymer particles, wherein an aqueous monomer solution is polymerized and the monomer solution is prepared using steam condensate.

First claim

The invention claimed is:

1. A process for producing water-absorbing polymer particles, comprising preparing an aqueous monomer solution or suspension by mixing
a) at least one ethylenically unsaturated monomer bearing an acid group,
b) optionally a neutralizing agent,
c) water at least partly as a steam condensate and the steam condensate comprises less than 1 ppm of dissolved oxygen, and
d) at least one crosslinker,

then inertizing the monomer solution or suspension, polymerizing the inertized monomer solution or suspension, then drying the resulting polymer gel, grinding, and classifying,
wherein the steam condensate is obtained from the condensation of steam in heat exchangers used for drying air in forced air belt dryers in the drying step.

2. The process according to claim 1 , wherein the water c) is steam condensate to an extent of at least 50% by weight.

3. The process according to claim 1 , wherein the oxygen content of the aqueous monomer solution or suspension is lowered below 1 ppm by inertization.

4. The process according to claim 1 , wherein the monomer a) is acrylic acid partly neutralized to an extent of at least 50 mol %.

5. The process according to claim 1 , wherein the monomer a) has been neutralized to an extent of 25 to 85 mol %.

6. The process according to claim 1 , wherein the steam condensate comprises less than 0.5 ppm of dissolved oxygen.

7. The process according to claim 1 , wherein the steam condensate comprises less than 0.1 ppm of dissolved oxygen.

8. The process according to claim 1 , wherein the water c) is steam condensate to an extent of at least 90% by weight.

9. The process according to claim 1 , wherein the water c) is steam condensate to an extent of at least 95% by weight.

Assignees

• Funk Rüdiger
• Schröder Jürgen
• Basf Se

Inventors

• Funk Rüdiger
• Schröder Jürgen

Classifications

• C08F222/1006

  of polyhydric alcohols or polyhydric phenols · CPC title

• C08F2/00

  Processes of polymerisation · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F2/18 Primary

  Suspension polymerisation · CPC title

• A61L15/22

  containing macromolecular materials · CPC title