Hydrogen separation membrane, and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-9751051-B2
Application number	US-201314651596-A
Country	US
Kind code	B2
Filing date	Oct 31, 2013
Priority date	Dec 11, 2012
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention relates to a hydrogen separation membrane and to a method for manufacturing same, which is provided for restraining the diffusion of and for imparting excellent bonding characteristics between a porous support and a palladium-based metal separation membrane. The hydrogen separation membrane according to the present invention comprises: a porous support of a metal material or a ceramic material; a buffer layer formed as a plurality of columns by using a ceramic material on the porous support; and a palladium-based metal separation membrane formed on the buffer layer for separating hydrogen. In said case, the buffer layer includes an oxide-based ceramic material of either MO y (M is Ti, Zr), wherein which the composition of oxygen is 1<y<2, or Al 2 O z , wherein which the composition of oxygen is 2<z<3, and may be formed as a plurality of layers.

First claim

The invention claimed is:

1. A hydrogen separation membrane comprising:
a porous support made of a metal or ceramic material;
a buffer layer made of a ceramic material, and formed in the form of a plurality of columns on the porous support, wherein the buffer layer is formed of a plurality of layers; and
a palladium-based metal separation membrane formed on the buffer layer and capable of separating hydrogen,
wherein the buffer layer has neighboring layers formed of different ceramic materials, the buffer layer comprises:
a first buffer layer formed on the porous support, and formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<1.8, or 2<z<2.8; and
a second buffer layer formed on the first buffer layer, and formed of an oxide-based ceramic material comprising one selected from the group consisting of Ti, Zr, Al, Si, Ce, La, Sr, Cr, V, Nb, Ga, Ta, W, and Mo.

2. The hydrogen separation membrane of claim 1 , wherein the buffer layer is in the form of the plurality of columns having a diameter of 10 to 200nm.

3. The hydrogen separation membrane of claim 2 , wherein the plurality of columns of the buffer layer are formed separately, or formed in the form of a plurality of clusters.

4. The hydrogen separation membrane of claim 1 , wherein the buffer layer comprises:
a third buffer layer formed on the second buffer layer, and formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<1.8, or 2<z<2.8.

5. A method for manufacturing a hydrogen separation membrane, comprising:
preparing a porous support made of a metal or ceramic material;
forming a buffer layer in the form of a plurality of columns on the porous support, wherein the buffer layer is made of a ceramic material, and formed of a plurality of layers; and
forming a palladium-based metal separation membrane, which is able to separate hydrogen, on the buffer layer,
wherein the buffer layer has neighboring layers formed of different ceramic materials,
the forming of the buffer layer comprises:
forming a first buffer layer on the porous support wherein the first buffer layer is formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<2, or 2<z<3;
forming a second buffer layer on the first buffer layer wherein the second buffer layer is formed of an oxide-based ceramic material comprising one selected from the group consisting of Ti, Zr, Al, Si, Ce, La, Sr, Cr, V, Nb, Ga, Ta, W, and Mo; and
forming a third buffer layer on the second buffer layer wherein the third buffer layer is formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<2, or 2<z<3.

6. The method of claim 5 , wherein, in the forming of the buffer layer, the buffer layer is formed at a vacuum condition by means of a sputtering process using a target as MO 2 (M is Ti or Zr) or Al 2 O 3 .

7. The method of claim 5 , wherein, in the forming of the buffer layer, the buffer layer is formed by supplying oxygen gas to an M metal plate or powder used as a source and oxidizing the M metal plate or powder by a reaction of evaporated M with the oxygen gas to grow on the porous support in the form of columns.

8. The method of claim 5 , wherein, in the forming of the metal separation membrane, the palladium-based metal separation membrane is formed on the buffer layer using a physical vapor deposition method.

9. A hydrogen separation membrane comprising:
a porous support made of a metal or ceramic material;
a buffer layer made of a ceramic material, and formed in the form of a plurality of columns on the porous support, wherein the buffer layer is formed of a plurality of layers; and
a palladium-based metal separation membrane formed on the buffer layer and capable of separating hydrogen,
wherein the buffer layer has neighboring layers formed of different ceramic materials,
the buffer layer comprises:
a first buffer layer formed on the porous support, and formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<2, or 2<z<3;
a second buffer layer formed on the first buffer layer, and formed of an oxide-based ceramic material comprising one selected from the group consisting of Ti, Zr, Al, Si, Ce, La, Sr, Cr, V, Nb, Ga, Ta, W, and Mo; and
a third buffer layer formed on the second buffer layer, and formed of one oxide-based ceramic material selected from the group consisting of TiO y , ZrO y , and Al 2 O z where the composition of oxygen is 1<y<2, or 2<z<3.

10. The hydrogen separation membrane of claim 9 , wherein the buffer layer is in the form of the plurality of columns having a diameter of 10 to 200 nm.

11. The hydrogen separation membrane of claim 9 , wherein the plurality of columns of the buffer layer are formed separately, or formed in the form of a plurality of clusters.

12. The hydrogen separation membrane of claim 9 , wherein the composition of oxygen is 1.5<y <1.8, or 2<z<2.8.

13. The hydrogen separation membrane of claim 1 , wherein the composition of oxygen is 1.5<y <1.8, or 2<z<2.8.

14. The method for manufacturing a hydrogen separation membrane of claim 5 , wherein the composition of oxygen is 1.5<y<1.8, or 2<z<2.8.

Assignees

• Korea Energy Research Inst

Inventors

• Park Jongsoo
• Ryi Shinkun
• Lee Chunboo
• Lee Sungwook

Classifications

• C23C8/10

  Oxidising · CPC title

• B01D71/024

  Oxides · CPC title

• B01D2257/108

  Hydrogen · CPC title

• B01D53/228 Primary

  characterised by specific membranes · CPC title

• C23C14/34

  Sputtering · CPC title