Insecticidal compounds

Patent metadata

Field	Value
Publication number	US-9750246-B2
Application number	US-201415106489-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 23, 2013
Publication date	Sep 5, 2017
Grant date	Sep 5, 2017

Abstract

The present invention relates to novel bisamide derivatives of formula (I) having insecticidal activity, to processes and intermediates for preparing them, to insecticidal, acaricidal, nematicidal or molluscicidal compositions comprising them and to methods of using them to combat and control insect, acarine, nematode or mollusc pests

wherein X 0 , X 1 , X 2 , Y 1 , Y 2 , R 1 , R 2 , G 1 and G 2 , and Q are as described in formula 1 or salts and n-Oxides thereof.

First claim

The invention claimed is:

1. A compound of formula (I)

wherein
X 0 is bromo, chloro or hydrogen;
X 1 is methoxy;
X 2 is hydrogen;
Y 1 and Y 2 are independently chloro, bromo, iodo, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy, and C 1 -C 4 haloalkoxy;
R 1 and R 2 are independent of one another hydrogen, C 1 -C 8 alkyl, C 2 -C 8 alkenyl, C 2 -C 8 alkynyl, C 1 -C 8 alkylcarbonyl, C 1 -C 8 alkoxycarbonyl, hydroxyl, C 1 -C 8 -alkyloxy, and aminocarbonyl-C 1 -C 4 alkylene;
G 1 and G 2 are independent of each other oxygen or sulfur;
Q is a group selected from Q2, Q3, Q4 and Q5, where
Q2 is a group of formula (IIb)

where W 2 is selected from, hydrogen, halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy or C 1 -C 4 haloalkoxy,
Q3 is a group of formula (IIc)

where W 3 is selected from, hydrogen, halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy or C 1 -C 4 haloalkoxy,
Q4 is a group of formula (IId)

where W 4 is selected, hydrogen, halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy or C 1 -C 4 haloalkoxy,
Q5 is a group of formula (IIe)

where W 5 is selected from hydrogen, halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C4 alkoxy or C 1 -C 4 haloalkoxy.

2. A compound of formula (I) according to claim 1 wherein Y 1 and Y 2 are selected from Cl, Br, I, methyl, ethyl, methoxy, difluoromethoxy, and trifluoromethoxy,
X 0 is hydrogen or Br or Cl
R 1 is selected from hydrogen or C 1 -C 2 alkyl;
R 2 is selected from hydrogen, C 1 -C 2 alkyl;
and
G 1 and G 2 are both oxygen.

3. A compound of formula (III)

wherein X 0 , Y 1 , Y 2 , X 1 , X 2 , R 1 , and R 2 are as defined in formula (I) of claim 1 .

4. A method of controlling insects, acarines, nematodes or molluscs which comprises applying to a pest, to a locus of a pest, or to a plant susceptible to attack by a pest an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) as defined in claim 1 .

5. An insecticidal, acaricidal, nematicidal or molluscicidal composition comprising an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula (I) as defined in claim 1 together with an agrochemically acceptable diluent or carrier.

6. A composition according to claim 5 which further comprises one or more additional insecticidal, acaricidal, nematicidal or molluscicidal compounds.

7. A method of protecting useful plants from insects, acarines, nematodes or molluscs, comprising applying to said plants, to the locus thereof, or to plant propagation material thereof, an insecticidally, acaricidally, nematicidally or molluscicidally effective amount of a compound of formula I in claim 1 .

Assignees

• Syngenta Participations Ag

Inventors

• Edmunds Andrew
• STOLLER ANDRé
• Pitterna Thomas

Classifications

• A01N37/46

  N-acyl derivatives · CPC title

• A01N43/40

  six-membered rings · CPC title

• C07D213/89

  with hetero atoms directly attached to the ring nitrogen atom · CPC title

• C07D213/81

  Amides; Imides · CPC title

• C07C255/57 Primary

  containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton · CPC title