Additive for electrolyte of lithium battery, electrolyte including the same, and lithium battery using the electrolyte

Patent metadata

Field	Value
Publication number	US-9748606-B2
Application number	US-201514705306-A
Country	US
Kind code	B2
Filing date	May 6, 2015
Priority date	Aug 25, 2014
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

Provided are an additive for an electrolyte of a lithium battery; an electrolyte having the same; and a lithium battery using the electrolyte. The additive for an electrolyte of a lithium battery includes a triazine triphosphonate compound.

First claim

What is claimed is:

1. A lithium battery electrolyte, comprising:
a non-aqueous organic solvent;
a lithium salt; and
an additive, the additive including a triazine triphosphonate compound.

2. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is a 1,3,5-triazine-2,4,6-triphosphonate compound.

3. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is represented by Formula 1 below:

wherein:
X 1 , X 2 , X 3 , X 4 , X 5 , and X 6 are each independently hydrogen, a halogen atom, a substituted or unsubstituted C 1 -C 30 alkyl group, a substituted or unsubstituted C 1 -C 30 alkoxy group, a substituted or unsubstituted C 2 -C 20 alkenyl group, a substituted or unsubstituted C 2 -C 20 alkynyl group, a substituted or unsubstituted C 6 -C 20 aryl group, a substituted or unsubstituted C 6 -C 20 aryloxy group, a substituted or unsubstituted C 7 -C 20 arylalkyl group, a substituted or unsubstituted C 2 -C 20 heteroaryl group, a substituted or unsubstituted C 2 -C 20 heteroaryloxy group, a substituted or unsubstituted C 2 -C 20 heteroarylalkyl group, a substituted or unsubstituted C 4 -C 20 cyclic group, a substituted or unsubstituted C 4 -C 20 cyclic alkyl group, a substituted or unsubstituted C 2 -C 20 heterocyclic group, a substituted or unsubstituted C 2 -C 20 heterocyclic alkyl group, a cyano group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a nitro group, a phosphonate group, a silyl group, a carboxyl group or a salt thereof, a sulfonyl group, a sulfamoyl group, a sulfonic acid group or a salt thereof, or a phosphoric acid group or a salt thereof.

4. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is a silylated triazine triphosphonate compound.

5. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is a silylated 1,3,5-triazine-2,4,6-triphosphonate compound.

6. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is represented by Formula 2 below:

wherein:
R 1 to R 18 are each independently hydrogen, a halogen atom, a substituted or unsubstituted C 1 -C 30 alkyl group, a substituted or unsubstituted C 1 -C 30 alkoxy group, a substituted or unsubstituted C 2 -C 20 alkenyl group, a substituted or unsubstituted C 2 -C 20 alkynyl group, a substituted or unsubstituted C 6 -C 20 aryl group, a substituted or unsubstituted C 6 -C 20 aryloxy group, a substituted or unsubstituted C 7 -C 20 arylalkyl group, a substituted or unsubstituted C 2 -C 20 heteroaryl group, a substituted or unsubstituted C 2 -C 20 heteroaryloxy group, a substituted or unsubstituted C 2 -C 20 heteroarylalkyl group, a substituted or unsubstituted C 4 -C 20 cyclic group, a substituted or unsubstituted C 4 -C 20 cyclic alkyl group, a substituted or unsubstituted C 2 -C 20 heterocyclic group, a substituted or unsubstituted C 2 -C 20 heterocyclic alkyl group, a cyano group, a hydroxyl group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a nitro group, a thiol group, a carboxyl group or a salt thereof, a sulfonyl group, a sulfamoyl group, a sulfonic acid group or a salt thereof, or a phosphoric acid group or a salt thereof.

7. The electrolyte as claimed in claim 6 , wherein, in Formula 2, R 1 to R 18 are each independently substituted or unsubstituted C 1 -C 30 alkyl groups.

8. The electrolyte as claimed in claim 6 , wherein, in Formula 2, R 1 to R 18 are each independently a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a tert-butyl group, a trifluoromethyl group, or a tetrafluoroethyl group.

9. The electrolyte as claimed in claim 1 , wherein the triazine triphosphonate compound is represented by Formula 3 below:

10. The electrolyte as claimed in claim 1 , wherein the amount of the additive is in a range of about 0.001 wt % to about 10 wt % based on the total weight of the electrolyte.

11. The electrolyte as claimed in claim 1 , wherein the amount of the additive is in a range of about 0.01 wt % to about 5 wt % based on the total weight of the electrolyte.

12. The electrolyte as claimed in claim 1 , wherein the non-aqueous organic solvent includes one or more of a carbonate-based solvent, an ester-based solvent, an ether-based solvent, a ketone-based solvent, an alcohol-based solvent, or an aprotic solvent.

13. The electrolyte as claimed in claim 1 , wherein the non-aqueous organic solvent includes one or more of dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate (DPC), methyl propyl carbonate (MPC), ethyl propyl carbonate (EPC), methyl ethyl carbonate (MEC), ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), fluoroethylene carbonate (FEC), vinylene carbonate (VC), acetonitrile, succinonitrile (SN), dimethyl sulfoxide, dimethyl formamide, dimethyl acetamide, γ-butyrolactone, tetrahydrofuran, or ethyl propionate (EP).

14. The electrolyte as claimed in claim 1 , wherein the lithium salt includes one or more of LiPF 6 , LiBF 4 , LiSbF 6 , LiAsF 6 , LiC4F 9 SO 3 , LiClO 4 , LiALO 2 , LiAlCl 4 , LiN(C x F 2x+1 SO 2 )(C y F 2y+1 SO 2 ) where x and y are each independently an integer of 1 to 10, LiCl, LiI, LiB(C 2 O 4 ) 2 (lithium bis(oxalato)borate), or a combination thereof.

15. The electrolyte as claimed in claim 1 , wherein the concentration of the lithium salt is in a range of about 0.1 M to about 2.0 M.

16. A lithium battery, comprising:
a positive electrode;
a negative electrode; and
the electrolyte as claimed in claim 1 .

Assignees

• Samsung Sdi Co Ltd

Inventors

• Shatunov Pavel Alexandrovich
• Kim Sanghoon
• Lee Harim
• Khasanov Makhmut
• Cho Inhaeng
• Shin Woocheol

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M2300/0037

  Mixture of solvents · CPC title

• C07F9/65216

  Chemistry & Metallurgy · mapped topic