Optical computing devices comprising rotatable broadband angle-selective filters

Patent metadata

Field	Value
Publication number	US-9746584-B2
Application number	US-201515316871-A
Country	US
Kind code	B2
Filing date	Apr 15, 2015
Priority date	Apr 15, 2015
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

An optical computing device comprising a plurality of electromagnetic radiation sources, each at a unique angular displacement about an optical train and each at at least one unique electromagnetic radiation wavelength; an integrated computational element (ICE) located in the optical train before or after a sample located in the optical train to generate modified electromagnetic radiation in the optical train; a broadband angle-selective filter (BASF) located in the optical train that is rotatable about an axis to a plurality of unique orientations to transmit the electromagnetic radiation and/or the modified electromagnetic radiation in the optical train at a target incident angle corresponding to one of the plurality of electromagnetic radiation sources to generate angle selected-modified electromagnetic radiation (ASMR); and a detector to receive the ASMR and to generate an output signal corresponding to a characteristic of the sample.

First claim

The invention claimed is:

1. An optical computing device comprising:
a plurality of electromagnetic radiation sources, each at a unique angular displacement about an optical train and each at at least one unique electromagnetic radiation wavelength;
an integrated computational element (ICE) located in the optical train before or after a sample located in the optical train to generate modified electromagnetic radiation in the optical train;
a broadband angle-selective filter (BASF) located in the optical train that is rotatable about an axis to a plurality of unique orientations to transmit the electromagnetic radiation and/or the modified electromagnetic radiation in the optical train at a target incident angle corresponding to one of the plurality of electromagnetic radiation sources to generate angle selected-modified electromagnetic radiation (ASMR); and
a detector to receive the ASMR and to generate an output signal corresponding to a characteristic of the sample.

2. The optical computing device of claim 1 , wherein the ICE is located either (A) after the sample so that the electromagnetic radiation first optically interacts with the sample to generate optically interacted radiation in the optical train, and then the optically interacted radiation optically interacts with the ICE to generate the modified electromagnetic radiation in the optical train, or (B) before the sample so that the electromagnetic radiation first optically interacts with the ICE to generate optically interacted radiation in the optical train, and then the optically interacted radiation optically interacts with the sample to generate the modified electromagnetic radiation in the optical train, and
wherein the BASF is located in the optical train to transit the electromagnetic radiation, the optically interacted radiation, and/or the modified electromagnetic radiation in the optical train at the target incident angle.

3. The optical computing device of claim 2 , wherein the detector is in the optical train to receive a plurality of ASMR from a plurality of unique orientations of the rotatable BASF.

4. The optical computing device of claim 2 , wherein the sample is contained in a flow path to permit optical interaction with the electromagnetic radiation or the optically interacted radiation therewith.

5. The optical computing device of claim 2 , wherein the plurality of electromagnetic radiation sources are selected from the group consisting of narrow band sources, broadband sources, and any combination thereof.

6. The optical computing device of claim 2 , wherein the BASF is a multi-layer film stack deposited on the ICE.

7. The optical computing device of claim 2 , wherein a sample window is arranged adjacent to the sample in the optical train.

8. The optical computing device of claim 7 , wherein the BASF is a multi-layer film stack deposited onto a component selected from the group consisting of the ICE, the sampling window, and any combination thereof.

9. The optical computing device of claim 2 , wherein the BASF is composed of photonic crystal layers.

10. The optical computing device of claim 9 , wherein the photonic crystal layers are selected from the group consisting of a silicon-based compound, a tantalum-based compound, a Group III-V semiconductor compound, a Group IVB metal compound, a dielectric, a thin film deposition compound, and any combination thereof.

11. A method comprising:
providing a plurality of electromagnetic radiation sources, each at a unique angular displacement about an optical train and each at least one unique electromagnetic radiation wavelength;
optically interacting the electromagnetic radiation with a sample located in the optical train and an integrated computational element (ICE) located in the optical train before or after the sample to generate modified electromagnetic radiation in the optical train;
transmitting the electromagnetic radiation and/or the modified electromagnetic radiation through a broadband angle-selective filter (BASF) located in the optical train, wherein the BASF is rotatable about an axis to a plurality of unique orientations in the optical train at a target incident angle corresponding to one of the plurality of electromagnetic radiation sources, thereby generating angle selected-modified electromagnetic radiation (ASMR);
receiving the ASMR with a detector; and
generating an output signal corresponding to a characteristic of the sample.

12. The method of claim 11 , wherein the ICE is located either (A) after the sample so that the electromagnetic radiation first optically interacts with the sample to generate optically interacted radiation in the optical train, and then the optically interacted radiation optically interacts with the ICE to generate the modified electromagnetic radiation in the optical train, or (B) before the sample so that the electromagnetic radiation first optically interacts with the ICE to generate optically interacted radiation in the optical train, and then the optically interacted radiation optically interacts with the sample to generate the modified electromagnetic radiation in the optical train, and
wherein the BASF is located in the optical train to transit the electromagnetic radiation, the optically interacted radiation, and/or the modified electromagnetic radiation in the optical train at the target incident angle.

13. The method of claim 12 , further comprising receiving a plurality of ASMR with the detector from a plurality of unique orientations of the rotatable BASF.

14. The method of claim 12 , further comprising containing the sample in a flow path that permits optical interaction with the electromagnetic radiation or the optically interacted radiation therewith.

15. The method of claim 12 , wherein the plurality of electromagnetic radiation sources are selected from the group consisting of narrow band sources, broadband sources, and any combination thereof.

16. The method of claim 12 , wherein the BASF is a multi-layer film stack deposited on the ICE.

17. The method of claim 12 , wherein a sample window is arranged adjacent to the sample in the optical train.

18. The method of claim 17 , wherein the BASF is a multi-layer film stack deposited onto a component selected from the group consisting of the ICE, the sampling window, and any combination thereof.

19. The method of claim 12 , wherein the BASF is composed of photonic crystal layers.

20. A system comprising:
a sample arranged in an optical train; and
an optical computing device arranged in the optical train to optically interact with the sample, the optical computing device comprising:
a plurality of electromagnetic radiation sources, each at a unique angular displacement about an optical train and each at at least one unique electromagnetic radiation wavelength;
an integrated computational element (ICE) located in the optical train before or after a sample located in the optical train to generate modified electromagnetic radiation in the optical train;
a broadband angle-selective filter (BASF) located in the optical train that is rotatable about an axis to a plurality of unique orientations to transmit the electromagnetic radiation and/or the modified electromagnetic radiation in the optical train at a target incident angle corresponding to one of the plurality of electromagnetic radiation sources to generate angle selected-modified electromagnetic radiation (ASMR); and
a detector to receive the ASMR and to generate an output signal corresponding to a characteristic of the sample.

Assignees

• Halliburton Energy Services Inc

Inventors

• Price James M
• Perkins David L

Classifications

• G01N21/31 Primary

  Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry {(G01N21/72 takes precedence)} · CPC title

• G01N21/27

  using photo-electric detection (G01N21/31 takes precedence){; circuits for computing concentration (logarithmic circuits G06G7/24; photometric circuits in general G01J)} · CPC title

• E21B47/00

  Survey of boreholes or wells (monitoring pressure or flow of drilling fluid E21B21/08) · CPC title

• E21B47/135

  using light waves, e.g. infrared or ultraviolet waves · CPC title

• G01N21/17 Primary

  Systems in which incident light is modified in accordance with the properties of the material investigated (where the material investigated is optically excited causing a change in wavelength of the incident light G01N21/63) · CPC title