System and methodology for determining properties of a substance

Patent metadata

Field	Value
Publication number	US-9746410-B2
Application number	US-201414762258-A
Country	US
Kind code	B2
Filing date	Feb 5, 2014
Priority date	Feb 8, 2013
Publication date	Aug 29, 2017
Grant date	Aug 29, 2017

Abstract

A method for characterizing properties of a porous sample that employs a test apparatus including a sample cell and associated pressure sensor having a configuration that measures pressure of the isolated sample cell. The porous sample is divided into a number of pieces, which are loaded into the sample cell. The test apparatus is configured to perform a sequence of test operations whereby the loaded isolated sample cell is filled with test fluid under pressure and the pressure sensor is used to generate and store pressure data over time. A data processing system processes the pressure data in conjunction with a computational model that includes a set of pressure curves with a number of curve-related variables and associated values in order to identify a matching pressure curve, and processes the variable values for the matching pressure curve in order to derive bulk properties of the porous sample.

First claim

What is claimed is:

1. A method for characterizing properties of a porous sample, comprising:
a) providing a test apparatus including a sample cell and associated first pressure sensor, wherein the sample cell has a configuration where the sample cell is filled with test fluid under pressure and isolated from other parts of the test apparatus, and wherein the first pressure sensor has a configuration that measures pressure of the sample cell when the sample cell is isolated from other parts of the test apparatus;
b) dividing the porous sample into a number of pieces having controlled shapes with sizes corresponding to thickness of the controlled shapes and selected surfaces of the pieces are sealed with an impermeable material for characterization of directional permeability and increasing signal-to-noise ratio by decreasing dead volume;
c) loading pieces of the porous sample resulting from b) into the sample cell of the test apparatus;
d) subsequent to c), configuring the test apparatus to perform a sequence of test operations whereby the loaded sample cell is filled with test fluid under pressure and isolated from other parts of the test apparatus and the first pressure sensor is used to measure and store pressure data that represents pressures measured by the pressure sensor over time;
e) using a data processing system to process the pressure data generated and stored in d) in conjunction with a computational model that includes a set of pressure curves with a number of curve-related variables and associated values in order to identify a matching pressure curve; and
f) using the data processing system to process the values of the curve-related variables for the matching pressure curve identified in e) in order to derive bulk properties of the porous sample.

2. A method according to claim 1 , wherein the porous sample comprises a porous rock sample.

3. A method according to claim 1 , wherein the test apparatus further includes:
an intake valve fluidly coupled to a source of test fluid;
a reference cell fluidly coupled to the source of test fluid via the intake valve;
an isolation valve fluidly coupled between the reference cell and the sample cell;
an exhaust port;
an exhaust valve fluidly coupled between the sample cell and the exhaust port; and
a second pressure sensor associated with the reference cell for measuring pressure within the reference cell.

4. A method according to claim 3 , wherein:
the intake valve, the isolation valve, and the exhaust valve are electronically-controlled;
the data processing system interfaces to the intake valve, the isolation valve, and the exhaust valve via electronic signals communicated therebetween in order to control operation of the intake valve, the isolation valve, and the exhaust valve; and
the data processing system interfaces to the first and second pressure sensors via electronic signals communicated therebetween in order to generate and store first and second pressure data representing the pressures measured by the first and second pressure sensors, respectively, over time.

5. A method according to claim 1 , wherein the bulk properties of the porous sample derived in f) are selected from the group consisting of bulk volume, bulk density, porosity, permeability, grain volume, grain density, and effective density-based porosity.

6. A method according to claim 1 , wherein the computational model is based on an analytical decay function that includes three parameters α, β and τ, where the parameter α is a storage coefficient that defines the ratio of pore volume to dead volume in the sample under test, the parameter β relates to the final pressure in the sample cell when pressure inside and outside of the pore volume of the sample under test has stabilized, and parameter τ is a relaxation time.

7. A method according to claim 6 , wherein the bulk properties of the porous sample derived in f) are selected from the group consisting of bulk volume based on value of the parameter β for the matching pressure curve, porosity based on value of the parameter α for the matching pressure curve, permeability based on the parameter τ for the matching pressure curve, grain volume based on the bulk volume and the porosity, bulk density based on bulk volume, grain density based on grain volume, and effective density-based porosity based on bulk and grain density.

8. A method according to claim 1 , wherein the processing of e) derives corrected pressure values based on the pressure data generated and stored in d) and matches the corrected pressure values to the set of pressure curves derived from the computational model in order to identify a matching pressure curve.

9. A method according to claim 1 , wherein the pieces resulting from b) and loaded into the sample cell in c) are fragments of uncontrolled shape with sizes corresponding to the radius of such fragments.

10. A method according to claim 1 , wherein the pieces of controlled shape are slices of a core sample with varying thickness.

11. A method according to claim 6 , wherein using the data processing system to process the pressure data generated and stored in d) in conjunction with the computational model in order to identify value of the parameter τ for the matching pressure curve and to determine if the pieces resulting from b) require reduction in size based on the value of the parameter τ for the matching pressure curve.

12. A method according to claim 11 , wherein the data processing system compares the time period of the pressure data as measured by the pressure sensor with the parameter τ for the matching pressure curve to determine if the pieces resulting from b) require reduction in size.

13. A method according to claim 12 , wherein the data processing system determines that the pieces resulting from b) require reduction in size in the event that the time period of the pressure data as measured by the pressure sensor is smaller than the parameter τ for the matching pressure curve.

14. A method according to claim 13 , further comprising:
in the event that the data processing system determines that the pieces resulting from b) require reduction in size, repeating b) in order to reduce maximum size of the pieces that result from b).

15. A method according to claim 1 , further comprising:
g) partitioning the pieces of the porous sample resulting from b) into size-groups of different sizes;
h) performing a sequence of operations for each given size-group of sample pieces resulting from g), wherein the sequence of operations of h) includes
h1) loading one or more pieces of the given size-group into the sample cell of the test apparatus,
h2) subsequent to h1), configuring the test apparatus to perform a sequence of test operations whereby the loaded sample cell is filled with test fluid under pressure and isolated from other parts of the test apparatus and the first pressure sensor is used to measure and store pressure data that represents pressures measured by the first pressure sensor over time,
h3) using the data processing system to process the pressure data generated and stored in h2) in conjunction with the computational model in order to identify a matching pressure curve, and
h4) using the data processing system to process the values of the curve-related variables for the matching pressure curve identified in h3) in order to derive properties of a given size-group of pieces.

16. A method according to claim 15 , wherein the processing of h3) derives corrected pressure values based on the pressure data generated and stored in h2) and matches the corrected pressure values to the set

Assignees

• Schlumberger Technology Corp

Inventors

• Chertov Maxim Andreevich
• Suarez-Rivera Roberto
• Willberg Dean M
• Green Sidney J

Classifications

• G01N15/0806

  Details, e.g. sample holders, mounting samples for testing · CPC title

• G01N33/24

  Earth materials (G01N33/42 takes precedence) · CPC title

• G01N7/00 Primary

  Analysing materials by measuring the pressure or volume of a gas or vapour · CPC title

• G01N15/0826

  and measuring fluid flow rate, i.e. permeation rate or pressure change · CPC title

• G01N15/088

  Investigating volume, surface area, size or distribution of pores; Porosimetry · CPC title